Heads or Tails? Sandwich-Type Metallocomplexes of
Hexakis(2,3-di-O-methyl)-alpha-cyclodextrin

J 2020

Heads or Tails? Sandwich-Type Metallocomplexes of Hexakis(2,3-di-O-methyl)-alpha-cyclodextrin

JURČEK, Ondřej; Rahesh PUTTREDDY; Filip TOPIĆ; Pia Yasmine JURČEK; Pezhman ZARABADI POOR et. al.

Základní údaje

Originální název

Heads or Tails? Sandwich-Type Metallocomplexes of Hexakis(2,3-di-O-methyl)-alpha-cyclodextrin

Autoři

JURČEK, Ondřej (203 Česká republika, garant, domácí); Rahesh PUTTREDDY (356 Indie); Filip TOPIĆ (191 Chorvatsko); Pia Yasmine JURČEK (246 Finsko, domácí); Pezhman ZARABADI POOR (364 Írán, domácí); Hendrik V. SCHRÖDER (276 Německo); Radek MAREK (203 Česká republika, domácí) a Kari RISSANEN (246 Finsko)

Vydání

Crystal Growth Design, American Chemical Society, 2020, 1528-7483

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

DOI: 10.1021/acs.cgd.0c00532

Impakt faktor

Impact factor: 4.076

Kód RIV

RIV/00216224:14740/20:00114124

Organizační jednotka

Středoevropský technologický institut

DOI

http://dx.doi.org/10.1021/acs.cgd.0c00532

UT WoS

000538515500071

EID Scopus

2-s2.0-85087197608

Klíčová slova česky

cykodextrin;krystalová struktura;RTG difrakce;metalokomplex

Klíčová slova anglicky

cyclodextrin;crystal structure;X-ray diffraction;metallocomplex

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 3. 3. 2021 14:06, Mgr. Pavla Foltynová, Ph.D.

Anotace

V originále

Native and synthetically modified cyclodextrins (CDs) are useful building blocks in construction of large coordination complexes and porous materials with various applications. Sandwich-type complexes (STCs) are one of the important groups in this area. Usually, coordination of secondary hydroxyls or the “head” portal of native CD molecules to a notional multinuclear ring of metal cations leads to formation of head-to-head STCs. Our study introduces a new CD-ligand, hexakis(2,3-di-O-methyl)-alpha-cyclodextrin, which enables formation of intriguing head-to-head, but also novel tail-to-tail STCs. Homometallic silver-based head-to-head STCs, AgPF6-STC and AgClO4-STC, were obtained by coordination of ligand methoxy groups to six Ag+, while bulky counter-anions are located on the outside but also filling the inner space of infinite linear channels formed. In contrast, unique homometallic tail-to-tail RbF-STC was prepared by complexation of primary hydroxyls, “tails”, to twelve Rb+ tightly interconnected by twelve F- creating complex structure with accessible pores for potential gas adsorptions.

Návaznosti

EF18_070/0009846, projekt VaV

Název: MSCAfellow2@MUNI

GA18-05421S, projekt VaV

Název: Rozvoj paramagnetické NMR spektroskopie pro supramolekulární systémy (Akronym: SUPRAMAG)

Investor: Grantová agentura ČR, Rozvoj paramagnetické NMR spektroskopie pro supramolekulární systémy

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

5SA15055, interní kód MU

Název: Metal-Organic Materials for Pharmaceutical Applications (Akronym: MOPHARM)

Investor: Jihomoravský kraj, Metal-Organic Materials for Pharmaceutical Applications

5SA15060, interní kód MU

Název: Advanced carbon@MOF composites for gas storage and separation (Akronym: COMPSTORE)

Investor: Jihomoravský kraj, Advanced carbon@MOF composites for gas storage and separation

Citovat

JURČEK, Ondřej; Rahesh PUTTREDDY; Filip TOPIĆ; Pia Yasmine JURČEK; Pezhman ZARABADI POOR; Hendrik V. SCHRÖDER; Radek MAREK a Kari RISSANEN. Heads or Tails? Sandwich-Type Metallocomplexes of Hexakis(2,3-di-O-methyl)-alpha-cyclodextrin. Crystal Growth Design. American Chemical Society, 2020, roč. 20, č. 6, s. 4193-4199. ISSN 1528-7483. Dostupné z: https://dx.doi.org/10.1021/acs.cgd.0c00532.

@article{1651498,
   author = {Jurček, Ondřej and Puttreddy, Rahesh and Topić, Filip and Jurček, Pia Yasmine and Zarabadi Poor, Pezhman and Schröder, Hendrik V. and Marek, Radek and Rissanen, Kari},
   article_number = {6},
   doi = {http://dx.doi.org/10.1021/acs.cgd.0c00532},
   keywords = {cyclodextrin;crystal structure;X-ray diffraction;metallocomplex},
   language = {eng},
   issn = {1528-7483},
   journal = {Crystal Growth Design},
   title = {Heads or Tails? Sandwich-Type Metallocomplexes of Hexakis(2,3-di-O-methyl)-alpha-cyclodextrin},
   url = {http://dx.doi.org/10.1021/acs.cgd.0c00532},
   volume = {20},
   year = {2020}
}

TY  - JOUR
ID  - 1651498
AU  - Jurček, Ondřej - Puttreddy, Rahesh - Topić, Filip - Jurček, Pia Yasmine - Zarabadi Poor, Pezhman - Schröder, Hendrik V. - Marek, Radek - Rissanen, Kari
PY  - 2020
TI  - Heads or Tails? Sandwich-Type Metallocomplexes of Hexakis(2,3-di-O-methyl)-alpha-cyclodextrin
JF  - Crystal Growth Design
VL  - 20
IS  - 6
SP  - 4193-4199
EP  - 4193-4199
PB  - American Chemical Society
SN  - 15287483
KW  - cyclodextrin;crystal structure;X-ray diffraction;metallocomplex
UR  - http://dx.doi.org/10.1021/acs.cgd.0c00532
L2  - http://dx.doi.org/10.1021/acs.cgd.0c00532
N2  - Native and synthetically modified cyclodextrins (CDs) are useful building blocks in construction of large coordination complexes and porous materials with various applications. Sandwich-type complexes (STCs) are one of the important groups in this area. Usually, coordination of secondary hydroxyls or the “head” portal of native CD molecules to a notional multinuclear ring of metal cations leads to formation of head-to-head STCs. Our study introduces a new CD-ligand, hexakis(2,3-di-O-methyl)-alpha-cyclodextrin, which enables formation of intriguing head-to-head, but also novel tail-to-tail STCs. Homometallic silver-based head-to-head STCs, AgPF6-STC and AgClO4-STC, were obtained by coordination of ligand methoxy groups to six Ag+, while bulky counter-anions are located on the outside but also filling the inner space of infinite linear channels formed. In contrast, unique homometallic tail-to-tail RbF-STC was prepared by complexation of primary hydroxyls, “tails”, to twelve Rb+ tightly interconnected by twelve F- creating complex structure with accessible pores for potential gas adsorptions.
ER  -

JURČEK, Ondřej; Rahesh PUTTREDDY; Filip TOPI$\backslash$'C; Pia Yasmine JURČEK; Pezhman ZARABADI POOR; Hendrik V. SCHRÖDER; Radek MAREK a Kari RISSANEN. Heads or Tails? Sandwich-Type Metallocomplexes of Hexakis(2,3-di-O-methyl)-alpha-cyclodextrin. \textit{Crystal Growth Design}. American Chemical Society, 2020, roč.~20, č.~6, s.~4193-4199. ISSN~1528-7483. Dostupné z: https://dx.doi.org/10.1021/acs.cgd.0c00532.

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