Preparation of thorium dioxide nanofibers by electrospinning

J 2020

Preparation of thorium dioxide nanofibers by electrospinning

KUNDRÁT, Vojtěch, Zdeněk MORAVEC a Jiří PINKAS

Základní údaje

Originální název

Preparation of thorium dioxide nanofibers by electrospinning

Autoři

KUNDRÁT, Vojtěch (203 Česká republika, domácí), Zdeněk MORAVEC (203 Česká republika, domácí) a Jiří PINKAS (203 Česká republika, garant, domácí)

Vydání

Journal of Nuclear Materials, Amsterdam, Elsevier, 2020, 0022-3115

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.936

Kód RIV

RIV/00216224:14310/20:00116139

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.jnucmat.2020.152153

UT WoS

000535457700013

Klíčová slova anglicky

Electrospinning; Thorium dioxide; Thoria; Nanofibers; Polyvinylpyrrolidone; Polyvinyl alcohol

Štítky

CF CRYO, CF SAXS, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 2. 11. 2020 09:35, Mgr. Marie Šípková, DiS.

Anotace

V originále

For the first time, we report the preparation of thorium dioxide with nanofibrous morphology by the electrospinning method. Two approaches were employed with different electrospun solution compositions and inorganic precursors. Thorium nitrate with polyvinyl alcohol (PVA) as a supporting polymer was successfully electrospun from an aqueous solution resulting in green composite fibers that were calcined at 773 K to pure ThO2 nanofibers of diameter 76 +/- 25 nm. Another precursor solution was based on organic solvents and thorium acetylacetonate complex with polyvinylpyrrolidone (PVP). Green fibers were calcined at 673 K to porous nanofibers of ThO2 with an average diameter of 34 +/- 18 nm and surface area of 85 m(2) g(-1). The prepared materials were characterized by TGA-DSC, SEM, TEM, PXRD, and BET methods. (C) 2020 Elsevier B.V. All rights reserved.

Návaznosti

LM2018127, projekt VaV

Název: Česká infrastruktura pro integrativní strukturní biologii (Akronym: CIISB)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Czech Infrastructure for Integrative Structural Biology

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

Citovat

KUNDRÁT, Vojtěch, Zdeněk MORAVEC a Jiří PINKAS. Preparation of thorium dioxide nanofibers by electrospinning. Journal of Nuclear Materials. Amsterdam: Elsevier, 2020, roč. 534, JUN 2020, s. 1-8. ISSN 0022-3115. Dostupné z: https://dx.doi.org/10.1016/j.jnucmat.2020.152153.

@article{1673197,
   author = {Kundrát, Vojtěch and Moravec, Zdeněk and Pinkas, Jiří},
   article_location = {Amsterdam},
   article_number = {JUN 2020},
   doi = {http://dx.doi.org/10.1016/j.jnucmat.2020.152153},
   keywords = {Electrospinning; Thorium dioxide; Thoria; Nanofibers; Polyvinylpyrrolidone; Polyvinyl alcohol},
   language = {eng},
   issn = {0022-3115},
   journal = {Journal of Nuclear Materials},
   title = {Preparation of thorium dioxide nanofibers by electrospinning},
   url = {http://dx.doi.org/10.1016/j.jnucmat.2020.152153},
   volume = {534},
   year = {2020}
}

TY  - JOUR
ID  - 1673197
AU  - Kundrát, Vojtěch - Moravec, Zdeněk - Pinkas, Jiří
PY  - 2020
TI  - Preparation of thorium dioxide nanofibers by electrospinning
JF  - Journal of Nuclear Materials
VL  - 534
IS  - JUN 2020
SP  - 1-8
EP  - 1-8
PB  - Elsevier
SN  - 00223115
KW  - Electrospinning
KW  - Thorium dioxide
KW  - Thoria
KW  - Nanofibers
KW  - Polyvinylpyrrolidone
KW  - Polyvinyl alcohol
UR  - http://dx.doi.org/10.1016/j.jnucmat.2020.152153
L2  - http://dx.doi.org/10.1016/j.jnucmat.2020.152153
N2  - For the first time, we report the preparation of thorium dioxide with nanofibrous morphology by the electrospinning method. Two approaches were employed with different electrospun solution compositions and inorganic precursors. Thorium nitrate with polyvinyl alcohol (PVA) as a supporting polymer was successfully electrospun from an aqueous solution resulting in green composite fibers that were calcined at 773 K to pure ThO2 nanofibers of diameter 76 +/- 25 nm. Another precursor solution was based on organic solvents and thorium acetylacetonate complex with polyvinylpyrrolidone (PVP). Green fibers were calcined at 673 K to porous nanofibers of ThO2 with an average diameter of 34 +/- 18 nm and surface area of 85 m(2) g(-1). The prepared materials were characterized by TGA-DSC, SEM, TEM, PXRD, and BET methods. (C) 2020 Elsevier B.V. All rights reserved.
ER  -

KUNDRÁT, Vojtěch, Zdeněk MORAVEC a Jiří PINKAS. Preparation of thorium dioxide nanofibers by electrospinning. \textit{Journal of Nuclear Materials}. Amsterdam: Elsevier, 2020, roč.~534, JUN 2020, s.~1-8. ISSN~0022-3115. Dostupné z: https://dx.doi.org/10.1016/j.jnucmat.2020.152153.

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