Deposition Penetration Depth and Sticking Probability in Plasma
Polymerization of Cyclopropylamine

J 2021

Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine

MICHLÍČEK, Miroslav, Lucie BLAHOVÁ, Eva DVOŘÁKOVÁ, David NEČAS, Lenka ZAJÍČKOVÁ et. al.

Základní údaje

Originální název

Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine

Autoři

MICHLÍČEK, Miroslav (203 Česká republika, domácí), Lucie BLAHOVÁ (203 Česká republika, domácí), Eva DVOŘÁKOVÁ (203 Česká republika, domácí), David NEČAS (203 Česká republika) a Lenka ZAJÍČKOVÁ (203 Česká republika, garant, domácí)

Vydání

Applied Surface Science, Amsterdam, Elsevier Science, 2021, 0169-4332

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10305 Fluids and plasma physics

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 7.392

Kód RIV

RIV/00216224:14310/21:00118778

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.apsusc.2020.147979

UT WoS

000598377000006

Klíčová slova anglicky

plasma polymerization; 3D structured substrates; bioactive functional coating; penetration depth; sticking probability

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 6. 3. 2024 14:54, Mgr. Marie Šípková, DiS.

Anotace

V originále

Understanding the role of substrate geometry is vital for a successful optimization of low-pressure plasma polymerization on non-planar substrates used in bioapplications, such as porous materials or well plates. We investigated the altered transport of film-forming species and properties of the coatings for a cyclopropylamine and argon discharge using a combined analysis of the plasma polymer deposition on flat Si pieces, culture wells, microtrenches, a macrocavity, porous hydroxyapatite scaffolds and electrospun polycaprolactone nanofibrous mats. The aspect ratio of the well structures impacted mainly the deposition rate, whereas the film chemistry was affected only moderately. A large deposition penetration depth into the porous media indicated a relatively low sticking probability of film-forming species. A detailed analysis of microtrench step coverage and macrocavity deposition disproved the model of film-forming species with a single overall sticking probability. At least two populations with two different sticking probabilities were required to fit the experimental data. A majority of the film-forming species (76%) has a large sticking probability of 0.20±0.01, while still a significant part (24%) has a relatively small sticking probability of 0.0015±0.0002. The presented methodology is widely applicable for understanding the details of plasma-surface interaction and successful applications of plasma polymerization onto complex substrates.

Návaznosti

GA18-12774S, projekt VaV

Název: Plazmové polymery připravené na nanovlákenných membránách pro inženýrství cévní tkáně

Investor: Grantová agentura ČR, Plazmové polymery připravené na nanovlákenných membránách pro inženýrství cévní tkáně

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

90110, velká výzkumná infrastruktura

Název: CzechNanoLab

Citovat

MICHLÍČEK, Miroslav, Lucie BLAHOVÁ, Eva DVOŘÁKOVÁ, David NEČAS a Lenka ZAJÍČKOVÁ. Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine. Applied Surface Science. Amsterdam: Elsevier Science, 2021, roč. 540, February 2021, s. 1-10. ISSN 0169-4332. Dostupné z: https://dx.doi.org/10.1016/j.apsusc.2020.147979.

@article{1689016,
   author = {Michlíček, Miroslav and Blahová, Lucie and Dvořáková, Eva and Nečas, David and Zajíčková, Lenka},
   article_location = {Amsterdam},
   article_number = {February 2021},
   doi = {http://dx.doi.org/10.1016/j.apsusc.2020.147979},
   keywords = {plasma polymerization; 3D structured substrates; bioactive functional coating; penetration depth; sticking probability},
   language = {eng},
   issn = {0169-4332},
   journal = {Applied Surface Science},
   note = {doc. Zajíčková - dle rozhodnutí ředitelů 5.3.2024},
   title = {Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine},
   url = {https://www.sciencedirect.com/science/article/pii/S0169433220327367},
   volume = {540},
   year = {2021}
}

TY  - JOUR
ID  - 1689016
AU  - Michlíček, Miroslav - Blahová, Lucie - Dvořáková, Eva - Nečas, David - Zajíčková, Lenka
PY  - 2021
TI  - Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine
JF  - Applied Surface Science
VL  - 540
IS  - February 2021
SP  - 1-10
EP  - 1-10
PB  - Elsevier Science
SN  - 01694332
N1  - doc. Zajíčková - dle rozhodnutí ředitelů 5.3.2024
KW  - plasma polymerization
KW  - 3D structured substrates
KW  - bioactive functional coating
KW  - penetration depth
KW  - sticking probability
UR  - https://www.sciencedirect.com/science/article/pii/S0169433220327367
L2  - https://www.sciencedirect.com/science/article/pii/S0169433220327367
N2  - Understanding the role of substrate geometry is vital for a successful optimization of low-pressure plasma polymerization on non-planar substrates used in bioapplications, such as porous materials or well plates. We investigated the altered transport of film-forming species and properties of the coatings for a cyclopropylamine and argon discharge using a combined analysis of the plasma polymer deposition on flat Si pieces, culture wells, microtrenches, a macrocavity, porous hydroxyapatite scaffolds and electrospun polycaprolactone nanofibrous mats. The aspect ratio of the well structures impacted mainly the deposition rate, whereas the film chemistry was affected only moderately. A large deposition penetration depth into the porous media indicated a relatively low sticking probability of film-forming species. A detailed analysis of microtrench step coverage and macrocavity deposition disproved the model of film-forming species with a single overall sticking probability. At least two populations with two different sticking probabilities were required to fit the experimental data. A majority of the film-forming species (76%) has a large sticking probability of 0.20±0.01, while still a significant part (24%) has a relatively small sticking probability of 0.0015±0.0002. The presented methodology is widely applicable for understanding the details of plasma-surface interaction and successful applications of plasma polymerization onto complex substrates.
ER  -

MICHLÍČEK, Miroslav, Lucie BLAHOVÁ, Eva DVOŘÁKOVÁ, David NEČAS a Lenka ZAJÍČKOVÁ. Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine. \textit{Applied Surface Science}. Amsterdam: Elsevier Science, 2021, roč.~540, February 2021, s.~1-10. ISSN~0169-4332. Dostupné z: https://dx.doi.org/10.1016/j.apsusc.2020.147979.

Podrobný výpis o publikaci