Kinetics, Isotherm, and Thermodynamic Studies of the Adsorption
Mechanism of PFOS and PFOA Using Inactivated and Chemically
Activated Maize Tassel

J 2020

Kinetics, Isotherm, and Thermodynamic Studies of the Adsorption Mechanism of PFOS and PFOA Using Inactivated and Chemically Activated Maize Tassel

OMO-OKORO, Patricia N., Christopher J. CURTIS, Pavlína KACER, Lisa Emily MELYMUK, Opeyemi A. OYEWO et. al.

Základní údaje

Originální název

Kinetics, Isotherm, and Thermodynamic Studies of the Adsorption Mechanism of PFOS and PFOA Using Inactivated and Chemically Activated Maize Tassel

Autoři

OMO-OKORO, Patricia N. (710 Jižní Afrika), Christopher J. CURTIS (710 Jižní Afrika), Pavlína KACER (203 Česká republika, domácí), Lisa Emily MELYMUK (124 Kanada, garant, domácí), Opeyemi A. OYEWO (710 Jižní Afrika) a Jonathan O. OKONKWO (710 Jižní Afrika)

Vydání

Water, Air and Soil Pollution, Dordrecht, Springer, 2020, 0049-6979

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10503 Water resources

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.520

Kód RIV

RIV/00216224:14310/20:00117360

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1007/s11270-020-04852-z

UT WoS

000570922700002

Klíčová slova anglicky

PFOS; PFOA; Maize tassel; Activated-maize tassel; Adsorption kinetics; Adsorption isotherm

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 29. 4. 2021 18:00, Mgr. Marie Šípková, DiS.

Anotace

V originále

The extreme persistence, bioaccumulative, and toxicity tendencies of per- and polyfluoroalkyl substances (PFAS) have contributed to the ever-increasing quest for effective and low-cost technologies for removing PFAS from aqueous solutions. Therefore, in the present study, maize tassel (MT) was activated using phosphoric acid. The chemically activated maize tassel (CAMT) was thereafter applied as an adsorbent for removing perfluorooctanoate (PFOA) and perfluorooctanesulfonate (PFOS) from aqueous media in comparison with the inactivated MT. The adsorption behaviors of PFOS and PFOA onto MT and CAMT were investigated via adsorption experiments. It was found that the isothermal data fit better with the Freundlich isotherm model than with the Langmuir isotherm model. Maximum adsorption capacities of 1552.5 mg g(-1) (3.10 mmol g(-1)) and 380.32 mg g(-1) (0.92 mmol g(-1)) were recorded for PFOS and PFOA, respectively, using CAMT, when the Freundlich model was applied. Equilibrium was attained within 60 min using both MT and CAMT. The pseudo-second-order kinetics model suited the kinetics data better. It was observed from the thermodynamic studies that the adsorption mechanism of PFOS and PFOA on MT and CAMT is spontaneous and feasible. All the values for the Gibb's free energy change (Delta G(0), kJ mol(-1)) obtained in the present study were below -20 kJ mol(-1). The adsorption of PFOS and PFOA using CAMT is exothermic in nature (enthalpy, Delta H-0 was negative) whereas the adsorption of PFOS and PFOA using MT is endothermic. The PFOS and PFOA adsorption processes using both MT and CAMT were greatly influenced by electrostatic and hydrophobic interactions.

Návaznosti

EF16_013/0001761, projekt VaV

Název: RECETOX RI

LM2015051, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX RI)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Výzkumná infrastruktura RECETOX

734522, interní kód MU

Název: Synergising International Research Studies into the Environmental Fate and Behaviour of Toxic Organic Chemicals in the Waste Stream (Akronym: INTERWASTE)

Investor: Evropská unie, Synergising International Research Studies into the Environmental Fate and Behaviour of Toxic Organic Chemicals in the Waste Stream, MSCA Marie Skłodowska-Curie Actions (Excellent Science)

Citovat

OMO-OKORO, Patricia N., Christopher J. CURTIS, Pavlína KACER, Lisa Emily MELYMUK, Opeyemi A. OYEWO a Jonathan O. OKONKWO. Kinetics, Isotherm, and Thermodynamic Studies of the Adsorption Mechanism of PFOS and PFOA Using Inactivated and Chemically Activated Maize Tassel. Water, Air and Soil Pollution. Dordrecht: Springer, 2020, roč. 231, č. 9, s. 1-21. ISSN 0049-6979. Dostupné z: https://dx.doi.org/10.1007/s11270-020-04852-z.

@article{1709819,
   author = {OmoandOkoro, Patricia N. and Curtis, Christopher J. and Kacer, Pavlína and Melymuk, Lisa Emily and Oyewo, Opeyemi A. and Okonkwo, Jonathan O.},
   article_location = {Dordrecht},
   article_number = {9},
   doi = {http://dx.doi.org/10.1007/s11270-020-04852-z},
   keywords = {PFOS; PFOA; Maize tassel; Activated-maize tassel; Adsorption kinetics; Adsorption isotherm},
   language = {eng},
   issn = {0049-6979},
   journal = {Water, Air and Soil Pollution},
   title = {Kinetics, Isotherm, and Thermodynamic Studies of the Adsorption Mechanism of PFOS and PFOA Using Inactivated and Chemically Activated Maize Tassel},
   url = {https://link.springer.com/article/10.1007%2Fs11270-020-04852-z},
   volume = {231},
   year = {2020}
}

TY  - JOUR
ID  - 1709819
AU  - Omo-Okoro, Patricia N. - Curtis, Christopher J. - Kacer, Pavlína - Melymuk, Lisa Emily - Oyewo, Opeyemi A. - Okonkwo, Jonathan O.
PY  - 2020
TI  - Kinetics, Isotherm, and Thermodynamic Studies of the Adsorption Mechanism of PFOS and PFOA Using Inactivated and Chemically Activated Maize Tassel
JF  - Water, Air and Soil Pollution
VL  - 231
IS  - 9
SP  - 1-21
EP  - 1-21
PB  - Springer
SN  - 00496979
KW  - PFOS
KW  - PFOA
KW  - Maize tassel
KW  - Activated-maize tassel
KW  - Adsorption kinetics
KW  - Adsorption isotherm
UR  - https://link.springer.com/article/10.1007%2Fs11270-020-04852-z
L2  - https://link.springer.com/article/10.1007%2Fs11270-020-04852-z
N2  - The extreme persistence, bioaccumulative, and toxicity tendencies of per- and polyfluoroalkyl substances (PFAS) have contributed to the ever-increasing quest for effective and low-cost technologies for removing PFAS from aqueous solutions. Therefore, in the present study, maize tassel (MT) was activated using phosphoric acid. The chemically activated maize tassel (CAMT) was thereafter applied as an adsorbent for removing perfluorooctanoate (PFOA) and perfluorooctanesulfonate (PFOS) from aqueous media in comparison with the inactivated MT. The adsorption behaviors of PFOS and PFOA onto MT and CAMT were investigated via adsorption experiments. It was found that the isothermal data fit better with the Freundlich isotherm model than with the Langmuir isotherm model. Maximum adsorption capacities of 1552.5 mg g(-1) (3.10 mmol g(-1)) and 380.32 mg g(-1) (0.92 mmol g(-1)) were recorded for PFOS and PFOA, respectively, using CAMT, when the Freundlich model was applied. Equilibrium was attained within 60 min using both MT and CAMT. The pseudo-second-order kinetics model suited the kinetics data better. It was observed from the thermodynamic studies that the adsorption mechanism of PFOS and PFOA on MT and CAMT is spontaneous and feasible. All the values for the Gibb's free energy change (Delta G(0), kJ mol(-1)) obtained in the present study were below -20 kJ mol(-1). The adsorption of PFOS and PFOA using CAMT is exothermic in nature (enthalpy, Delta H-0 was negative) whereas the adsorption of PFOS and PFOA using MT is endothermic. The PFOS and PFOA adsorption processes using both MT and CAMT were greatly influenced by electrostatic and hydrophobic interactions.
ER  -

OMO-OKORO, Patricia N., Christopher J. CURTIS, Pavlína KACER, Lisa Emily MELYMUK, Opeyemi A. OYEWO a Jonathan O. OKONKWO. Kinetics, Isotherm, and Thermodynamic Studies of the Adsorption Mechanism of PFOS and PFOA Using Inactivated and Chemically Activated Maize Tassel. \textit{Water, Air and Soil Pollution}. Dordrecht: Springer, 2020, roč.~231, č.~9, s.~1-21. ISSN~0049-6979. Dostupné z: https://dx.doi.org/10.1007/s11270-020-04852-z.

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