Qualitative assessment of 27 current-use pesticides in air at
20 sampling sites across Africa

J 2020

Qualitative assessment of 27 current-use pesticides in air at 20 sampling sites across Africa

FUHRIMANN, Samuel, Jana KLÁNOVÁ, Petra PŘIBYLOVÁ, Jiří KOHOUTEK, Mohamed Aqiel DALVIE et. al.

Základní údaje

Originální název

Qualitative assessment of 27 current-use pesticides in air at 20 sampling sites across Africa

Autoři

FUHRIMANN, Samuel (528 Nizozemské království), Jana KLÁNOVÁ (203 Česká republika, domácí), Petra PŘIBYLOVÁ (203 Česká republika, domácí), Jiří KOHOUTEK (203 Česká republika, domácí), Mohamed Aqiel DALVIE (710 Jižní Afrika), Martin ROOSLI (756 Švýcarsko) a Céline DEGRENDELE (250 Francie, garant, domácí)

Vydání

Chemosphere, Elsevier Ltd, 2020, 0045-6535

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10511 Environmental sciences

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 7.086

Kód RIV

RIV/00216224:14310/20:00117456

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.chemosphere.2020.127333

UT WoS

000566446500067

Klíčová slova anglicky

Africa; Air; Atrazine; Chlorpyrifos; Current-use pesticides; Spatial variations

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 15. 4. 2021 18:20, Mgr. Marie Šípková, DiS.

Anotace

V originále

Increasing use of current-use pesticides (CUPs) in Africa raises environmental and public health concerns. But there is a large uncertainty about their occurrence and the composition of pesticide mixtures on this continent. This paper investigates the presence of 27 CUPs in air across 20 sampling sites in Africa. 166 passive air samples, consisting of polyurethane foam (PUF), were collected in 12 African countries between 2010 and 2018. Samples were extracted with methanol and analyzed via high-performance liquid chromatography coupled with tandem mass spectrometry. The detection frequencies of CUPs per site were compared to land use patterns and sampling years, while their similarities were assessed using hierarchical cluster analysis. Overall, 24 CUPs were detected at least once. In 93% of all samples, at least one CUP was detected, while 78% of the samples had mixtures of two or more CUPs (median 3, interquartile range 5). Atrazine and chlorpyrifos were detected in 19 out of 20 sampling sites. Carbaryl, metazachlor, simazine, tebuconazole and terbuthylazine had the highest detection frequencies at sampling sites dominated by croplands. Across all the sampling years, 16 CUPs were present. Seven CUPs were newly detected from 2016 onwards (azinfos-methyl, dimetachlor, chlorsulfuron, chlortoluron, isoproturon, prochloraz and pyrazon), while metamitron was only present before 2012. Sites within a radius of about 200 km showed similarities in detected CUP mixtures across all samples. Our results show the presence of CUP mixtures across multiple agricultural and urban locations in Africa which requires further investigation of related environmental and human health risks.

Návaznosti

CZ.02.1.01/0.0/0.0/16_013/0001315, interní kód MU

Název: ACTRIS - CZ - RI (Akronym: ACTRIS-CZ RI)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, ACTRIS - CZ - RI, PO 1 Posilování kapacit pro kvalitní výzkum

LM2018121, projekt VaV

Název: Výzkumná infrastruktura RECETOX (Akronym: RECETOX RI)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, RECETOX RI

LM2018122, projekt VaV

Název: ACTRIS – účast České republiky

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, ACTRIS-CZ

Citovat

FUHRIMANN, Samuel, Jana KLÁNOVÁ, Petra PŘIBYLOVÁ, Jiří KOHOUTEK, Mohamed Aqiel DALVIE, Martin ROOSLI a Céline DEGRENDELE. Qualitative assessment of 27 current-use pesticides in air at 20 sampling sites across Africa. Chemosphere. Elsevier Ltd, 2020, roč. 258, November, s. 1-11. ISSN 0045-6535. Dostupné z: https://dx.doi.org/10.1016/j.chemosphere.2020.127333.

@article{1712956,
   author = {Fuhrimann, Samuel and Klánová, Jana and Přibylová, Petra and Kohoutek, Jiří and Dalvie, Mohamed Aqiel and Roosli, Martin and Degrendele, Céline},
   article_number = {November},
   doi = {http://dx.doi.org/10.1016/j.chemosphere.2020.127333},
   keywords = {Africa; Air; Atrazine; Chlorpyrifos; Current-use pesticides; Spatial variations},
   language = {eng},
   issn = {0045-6535},
   journal = {Chemosphere},
   title = {Qualitative assessment of 27 current-use pesticides in air at 20 sampling sites across Africa},
   url = {https://www.sciencedirect.com/science/article/pii/S0045653520315265?via%3Dihub},
   volume = {258},
   year = {2020}
}

TY  - JOUR
ID  - 1712956
AU  - Fuhrimann, Samuel - Klánová, Jana - Přibylová, Petra - Kohoutek, Jiří - Dalvie, Mohamed Aqiel - Roosli, Martin - Degrendele, Céline
PY  - 2020
TI  - Qualitative assessment of 27 current-use pesticides in air at 20 sampling sites across Africa
JF  - Chemosphere
VL  - 258
IS  - November
SP  - 1-11
EP  - 1-11
PB  - Elsevier Ltd
SN  - 00456535
KW  - Africa
KW  - Air
KW  - Atrazine
KW  - Chlorpyrifos
KW  - Current-use pesticides
KW  - Spatial variations
UR  - https://www.sciencedirect.com/science/article/pii/S0045653520315265?via%3Dihub
L2  - https://www.sciencedirect.com/science/article/pii/S0045653520315265?via%3Dihub
N2  - Increasing use of current-use pesticides (CUPs) in Africa raises environmental and public health concerns. But there is a large uncertainty about their occurrence and the composition of pesticide mixtures on this continent. This paper investigates the presence of 27 CUPs in air across 20 sampling sites in Africa. 166 passive air samples, consisting of polyurethane foam (PUF), were collected in 12 African countries between 2010 and 2018. Samples were extracted with methanol and analyzed via high-performance liquid chromatography coupled with tandem mass spectrometry. The detection frequencies of CUPs per site were compared to land use patterns and sampling years, while their similarities were assessed using hierarchical cluster analysis. Overall, 24 CUPs were detected at least once. In 93% of all samples, at least one CUP was detected, while 78% of the samples had mixtures of two or more CUPs (median 3, interquartile range 5). Atrazine and chlorpyrifos were detected in 19 out of 20 sampling sites. Carbaryl, metazachlor, simazine, tebuconazole and terbuthylazine had the highest detection frequencies at sampling sites dominated by croplands. Across all the sampling years, 16 CUPs were present. Seven CUPs were newly detected from 2016 onwards (azinfos-methyl, dimetachlor, chlorsulfuron, chlortoluron, isoproturon, prochloraz and pyrazon), while metamitron was only present before 2012. Sites within a radius of about 200 km showed similarities in detected CUP mixtures across all samples. Our results show the presence of CUP mixtures across multiple agricultural and urban locations in Africa which requires further investigation of related environmental and human health risks.
ER  -

FUHRIMANN, Samuel, Jana KLÁNOVÁ, Petra PŘIBYLOVÁ, Jiří KOHOUTEK, Mohamed Aqiel DALVIE, Martin ROOSLI a Céline DEGRENDELE. Qualitative assessment of 27 current-use pesticides in air at 20 sampling sites across Africa. \textit{Chemosphere}. Elsevier Ltd, 2020, roč.~258, November, s.~1-11. ISSN~0045-6535. Dostupné z: https://dx.doi.org/10.1016/j.chemosphere.2020.127333.

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