Gallium Species Incorporated into MOF Structure: Insight into
the Formation of a 3D Polycrystalline Gallium-Imidazole
Framework

J 2020

Gallium Species Incorporated into MOF Structure: Insight into the Formation of a 3D Polycrystalline Gallium-Imidazole Framework

KOBERA, L., J. HAVLIN, S. ABBRENT, J. ROHLICEK, M. STRECKOVA et. al.

Základní údaje

Originální název

Gallium Species Incorporated into MOF Structure: Insight into the Formation of a 3D Polycrystalline Gallium-Imidazole Framework

Autoři

KOBERA, L., J. HAVLIN, S. ABBRENT, J. ROHLICEK, M. STRECKOVA, T. SOPCAK, V. KYSELOVA, J. CZERNEK a J. BRUS

Vydání

Inorganic Chemistry, Washington, American Chemical Society, 2020, 0020-1669

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 5.165

Kód RIV

RIV/00216224:14740/20:00121450

Organizační jednotka

Středoevropský technologický institut

DOI

http://dx.doi.org/10.1021/acs.inorgchem.0c01563

UT WoS

000580381700016

Klíčová slova anglicky

SOLID-STATE NMR; METAL-METAL BONDS; CATALYSIS; REMOVAL; NUCLEI; HYDROFORMYLATION; PSEUDOPOTENTIALS; CRYSTALLOGRAPHY; SIMULATION; PARAMETERS

Štítky

CF NMR, ne MU, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 29. 4. 2021 13:18, Mgr. Pavla Foltynová, Ph.D.

Anotace

V originále

The formation of a polycrystalline 3D gallium-imidazole framework (MOF) was closely studied in three steps using ssNMR, XRPD, and TGA. In all steps, the reaction products show relatively high temperature stability up to 500 degrees C. The final product was examined by structural analysis using NMR crystallography combined with TG and BET analyses, which enabled a detailed characterization of the polycrystalline MOF system on the atomic-resolution level. Ga-71 ssNMR spectra provided valuable structural information on the coexistence of several distinct gallium species, including a tunable liquid phase. Moreover, using an NMR crystallography approach, two structurally asymmetric units of Ga(Im(6))(6-) incorporated into the thermally stable polycrystalline 3D matrix were identified. Prepared polycrystalline MOF material with polymorphic gallium species is promising for use in catalytic processes.

Návaznosti

90085, velká výzkumná infrastruktura

Název: CERIT-SC

90127, velká výzkumná infrastruktura

Název: CIISB II

Citovat

KOBERA, L., J. HAVLIN, S. ABBRENT, J. ROHLICEK, M. STRECKOVA, T. SOPCAK, V. KYSELOVA, J. CZERNEK a J. BRUS. Gallium Species Incorporated into MOF Structure: Insight into the Formation of a 3D Polycrystalline Gallium-Imidazole Framework. Inorganic Chemistry. Washington: American Chemical Society, 2020, roč. 59, č. 19, s. 13933-13941. ISSN 0020-1669. Dostupné z: https://dx.doi.org/10.1021/acs.inorgchem.0c01563.

@article{1762516,
   author = {Kobera, L. and Havlin, J. and Abbrent, S. and Rohlicek, J. and Streckova, M. and Sopcak, T. and Kyselova, V. and Czernek, J. and Brus, J.},
   article_location = {Washington},
   article_number = {19},
   doi = {http://dx.doi.org/10.1021/acs.inorgchem.0c01563},
   keywords = {SOLID-STATE NMR; METAL-METAL BONDS; CATALYSIS; REMOVAL; NUCLEI; HYDROFORMYLATION; PSEUDOPOTENTIALS; CRYSTALLOGRAPHY; SIMULATION; PARAMETERS},
   language = {eng},
   issn = {0020-1669},
   journal = {Inorganic Chemistry},
   title = {Gallium Species Incorporated into MOF Structure: Insight into the Formation of a 3D Polycrystalline Gallium-Imidazole Framework},
   url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01563},
   volume = {59},
   year = {2020}
}

TY  - JOUR
ID  - 1762516
AU  - Kobera, L. - Havlin, J. - Abbrent, S. - Rohlicek, J. - Streckova, M. - Sopcak, T. - Kyselova, V. - Czernek, J. - Brus, J.
PY  - 2020
TI  - Gallium Species Incorporated into MOF Structure: Insight into the Formation of a 3D Polycrystalline Gallium-Imidazole Framework
JF  - Inorganic Chemistry
VL  - 59
IS  - 19
SP  - 13933-13941
EP  - 13933-13941
PB  - American Chemical Society
SN  - 00201669
KW  - SOLID-STATE NMR
KW  - METAL-METAL BONDS
KW  - CATALYSIS
KW  - REMOVAL
KW  - NUCLEI
KW  - HYDROFORMYLATION
KW  - PSEUDOPOTENTIALS
KW  - CRYSTALLOGRAPHY
KW  - SIMULATION
KW  - PARAMETERS
UR  - https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01563
N2  - The formation of a polycrystalline 3D gallium-imidazole framework (MOF) was closely studied in three steps using ssNMR, XRPD, and TGA. In all steps, the reaction products show relatively high temperature stability up to 500 degrees C. The final product was examined by structural analysis using NMR crystallography combined with TG and BET analyses, which enabled a detailed characterization of the polycrystalline MOF system on the atomic-resolution level. Ga-71 ssNMR spectra provided valuable structural information on the coexistence of several distinct gallium species, including a tunable liquid phase. Moreover, using an NMR crystallography approach, two structurally asymmetric units of Ga(Im(6))(6-) incorporated into the thermally stable polycrystalline 3D matrix were identified. Prepared polycrystalline MOF material with polymorphic gallium species is promising for use in catalytic processes.
ER  -

KOBERA, L., J. HAVLIN, S. ABBRENT, J. ROHLICEK, M. STRECKOVA, T. SOPCAK, V. KYSELOVA, J. CZERNEK a J. BRUS. Gallium Species Incorporated into MOF Structure: Insight into the Formation of a 3D Polycrystalline Gallium-Imidazole Framework. \textit{Inorganic Chemistry}. Washington: American Chemical Society, 2020, roč.~59, č.~19, s.~13933-13941. ISSN~0020-1669. Dostupné z: https://dx.doi.org/10.1021/acs.inorgchem.0c01563.

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