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@article{1789146, author = {Vanryckeghem, Francis and Huysman, Steve and Smedes, Foppe and Van Langenhove, Herman and Vanhaecke, Lynn and Demeestere, Kristof}, article_location = {Amsterdam}, article_number = {July 2021}, doi = {http://dx.doi.org/10.1016/j.scitotenv.2021.146055}, keywords = {Micropollutant; Passive sampling; Sampling rate; Equilibrium partitioning; Teabag; Marine environment}, language = {eng}, issn = {0048-9697}, journal = {Science of the Total Environment}, title = {A Simple Teabag Equilibrium Passive Sampler using hydrophilic divinylbenzene sorbent for contaminants of emerging concern in the marine environment}, url = {https://www.sciencedirect.com/science/article/pii/S0048969721011220?via%3Dihub}, volume = {777}, year = {2021} }
TY - JOUR ID - 1789146 AU - Vanryckeghem, Francis - Huysman, Steve - Smedes, Foppe - Van Langenhove, Herman - Vanhaecke, Lynn - Demeestere, Kristof PY - 2021 TI - A Simple Teabag Equilibrium Passive Sampler using hydrophilic divinylbenzene sorbent for contaminants of emerging concern in the marine environment JF - Science of the Total Environment VL - 777 IS - July 2021 SP - 1-9 EP - 1-9 PB - Elsevier Science SN - 00489697 KW - Micropollutant KW - Passive sampling KW - Sampling rate KW - Equilibrium partitioning KW - Teabag KW - Marine environment UR - https://www.sciencedirect.com/science/article/pii/S0048969721011220?via%3Dihub N2 - A promising concept for sampling contaminants of emerging concern (CECs) using a home-made Simple Teabag Equilibrium Passive Sampler (STEPS) containing hydrophilic divinylbenzene (h-DVB) sorbent is presented and evaluated for application in estuarine systems. The uptake of a multi-class mixture of CECs with a broad polarity range (Log P ranging from -0.1 to 9.9) was investigated in static exposure batch experiments. Sampling rates (R-s) and equilibrium partitioning coefficients (K-sw) were determined for up to 74 CECs. Fast uptake (R-s = 0.3-12 L d(-1)) was noticed and the STEPS attained equilibrium partitioning after 1 to 2 weeks of exposure, with Log K-sw ranging from 4.1 to 6.5 L kg(-1). Field application of this novel h-DVB containing STEPS, followed by ultra-high performance liquid chromatography coupled to high-resolution Orbitrap mass spectrometry, revealed the presence of up to 40 steroidal hormones, (alkyl)phenols, phthalates, pharmaceuticals, personal care products, and pesticides in the Belgian Part of the North Sea. The measured trace concentrations (from 0.003 ng L-1 to 1.9 mu g L-1) and good precision (average RSD < 30%, n = 3) demonstrate the STEPS as fit-for-purpose for micropollutant analysis in the marine environment. ER -
VANRYCKEGHEM, Francis, Steve HUYSMAN, Foppe SMEDES, Herman VAN LANGENHOVE, Lynn VANHAECKE a Kristof DEMEESTERE. A Simple Teabag Equilibrium Passive Sampler using hydrophilic divinylbenzene sorbent for contaminants of emerging concern in the marine environment. \textit{Science of the Total Environment}. Amsterdam: Elsevier Science, 2021, roč.~777, July 2021, s.~1-9. ISSN~0048-9697. Dostupné z: https://dx.doi.org/10.1016/j.scitotenv.2021.146055.
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