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@article{1789442,
author = {Wetzel, Marius Holger and Rabending, Tina Trixy and Friák, Martin and Všianská, Monika and Šob, Mojmír and Leineweber, Andreas},
article_number = {14},
doi = {http://dx.doi.org/10.3390/ma14143963},
keywords = {iron nitride; high pressure; phase stability; phase transitions; phase diagrams; phase equilibria},
language = {eng},
issn = {1996-1944},
journal = {Materials},
title = {Phase Stability of Iron Nitride Fe4N at High Pressure—Pressure-Dependent Evolution of Phase Equilibria in the Fe–N System},
url = {https://doi.org/10.3390/ma14143963},
volume = {14},
year = {2021}
}
TY - JOUR
ID - 1789442
AU - Wetzel, Marius Holger - Rabending, Tina Trixy - Friák, Martin - Všianská, Monika - Šob, Mojmír - Leineweber, Andreas
PY - 2021
TI - Phase Stability of Iron Nitride Fe4N at High Pressure—Pressure-Dependent Evolution of Phase Equilibria in the Fe–N System
JF - Materials
VL - 14
IS - 14
SP - "3963"
EP - "3963"
PB - MDPI
SN - 19961944
KW - iron nitride
KW - high pressure
KW - phase stability
KW - phase transitions
KW - phase diagrams
KW - phase equilibria
UR - https://doi.org/10.3390/ma14143963
N2 - Although the general instability of the iron nitride γ′-Fe4N with respect to other phases at high pressure is well established, the actual type of phase transitions and equilibrium conditions of their occurrence are, as of yet, poorly investigated. In the present study, samples of γ′-Fe4N and mixtures of α Fe and γ′-Fe4N powders have been heat-treated at temperatures between 250 and 1000 °C and pressures between 2 and 8 GPa in a multi-anvil press, in order to investigate phase equilibria involving the γ′ phase. Samples heat-treated at high-pressure conditions, were quenched, subsequently decompressed, and then analysed ex situ. Microstructure analysis is used to derive implications on the phase transformations during the heat treatments. Further, it is confirmed that the Fe–N phases in the target composition range are quenchable. Thus, phase proportions and chemical composition of the phases, determined from ex situ X-ray diffraction data, allowed conclusions about the phase equilibria at high-pressure conditions. Further, evidence for the low-temperature eutectoid decomposition γ′→α+ε′ is presented for the first time. From the observed equilibria, a P–T projection of the univariant equilibria in the Fe-rich portion of the Fe–N system is derived, which features a quadruple point at 5 GPa and 375 °C, above which γ′-Fe4N is thermodynamically unstable. The experimental work is supplemented by ab initio calculations in order to discuss the relative phase stability and energy landscape in the Fe–N system, from the ground state to conditions accessible in the multi-anvil experiments. It is concluded that γ′-Fe4N, which is unstable with respect to other phases at 0 K (at any pressure), has to be entropically stabilised in order to occur as stable phase in the system. In view of the frequently reported metastable retention of the γ′ phase during room temperature compression experiments, energetic and kinetic aspects of the polymorphic transition γ′⇌ε′ are discussed.
ER -
WETZEL, Marius Holger, Tina Trixy RABENDING, Martin FRIÁK, Monika VŠIANSKÁ, Mojmír ŠOB a Andreas LEINEWEBER. Phase Stability of Iron Nitride Fe4N at High Pressure—Pressure-Dependent Evolution of Phase Equilibria in the Fe–N System. \textit{Materials}. MDPI, 2021, roč.~14, č.~14, s.~''3963'', 27 s. ISSN~1996-1944. Dostupné z: https://dx.doi.org/10.3390/ma14143963.
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