NPAHs and OPAHs in the atmosphere of two central European
cities: Seasonality, urban-to-background gradients, cancer
risks and gas-to-particle partitioning

J 2021

NPAHs and OPAHs in the atmosphere of two central European cities: Seasonality, urban-to-background gradients, cancer risks and gas-to-particle partitioning

DEGRENDELE, Céline, Tjasa KANDUC, David KOCMAN, Gerhard LAMMEL, Adriana CAMBELOVÁ et. al.

Základní údaje

Originální název

NPAHs and OPAHs in the atmosphere of two central European cities: Seasonality, urban-to-background gradients, cancer risks and gas-to-particle partitioning

Autoři

DEGRENDELE, Céline (250 Francie, domácí), Tjasa KANDUC (705 Slovinsko), David KOCMAN (705 Slovinsko), Gerhard LAMMEL (276 Německo, domácí), Adriana CAMBELOVÁ (703 Slovensko, domácí), Saul Garcia DOS SANTOS (724 Španělsko), Milena HORVAT (705 Slovinsko), Petr KUKUČKA (203 Česká republika, domácí), Adela SMEJKALOVA HOLUBOVA (203 Česká republika), Ondřej MIKEŠ (203 Česká republika, domácí), Beatriz NUNEZ-CORCUERA (724 Španělsko), Petra PŘIBYLOVÁ (203 Česká republika, domácí), Roman PROKEŠ (203 Česká republika, domácí), Ondřej SÁŇKA (203 Česká republika, domácí), Thomas MAGGOS (300 Řecko), Denis SARIGIANNIS (300 Řecko) a Jana KLÁNOVÁ (203 Česká republika, garant, domácí)

Vydání

Science of the Total Environment, Amsterdam, Elsevier Science, 2021, 0048-9697

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10511 Environmental sciences

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 10.753

Kód RIV

RIV/00216224:14310/21:00119247

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.scitotenv.2021.148528

UT WoS

000691589200006

Klíčová slova anglicky

Polycyclic aromatic hydrocarbons; Fine particles; Atmosphere; Spatial variations; Cancer risk

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 5. 10. 2021 22:16, Mgr. Michaela Hylsová, Ph.D.

Anotace

V originále

Derivatives of polycyclic aromatic hydrocarbons (PAHs) such as nitrated-and oxygenated-PAHs (NPAHs and OPAHs) could be even more toxic and harmful for the environment and humans than PAHs. We assessed the spatial and seasonal variations of NPAHs and OPAHs atmospheric levels, their cancer risks and their gas-to-particle partitioning. To this end, about 250 samples of fine particulate matter (PM2.5) and 50 gaseous samples were collected in 2017 in central Europe in the cities of Brno and Ljubljana (two traffic and two urban background sites) as well as one rural site. The average particulate concentrations were ranging from below limit of quantification to 593 pg m-3 for Sigma 9NPAHs and from 1.64 to 4330 pg m(-3) for Sigma 11OPAHs, with significantly higher concentrations in winter compared to summer. In winter, the particulate levels of NPAHs and OPAHs were higher at the traffic site compared to the urban background site in Brno while the opposite was found in Ljubljana. NPAHs and OPAHs particulate levels were influ-enced by the meteorological parameters and co-varied with several air pollutants. The significance of secondary formation on the occurrence of some NPAHs and OPAHs is indicated. In winter, 27-47% of samples collected at all sites were above the acceptable lifetime carcinogenic risk. The gas-particle partitioning of NPAHs and OPAHs was influenced by their physico-chemical properties, the season and the site-specific aerosol composition. Three NPAHs and five OPAHs had higher particulate mass fractions at the traffic site, suggesting they could be primarily emitted as particles from vehicle traffic and subsequently partitioning to the gas phase along air transport. This study underlines the importance of inclusion of the gas phase in addition to the particulate phase when assessing the atmospheric fate of polycyclic aromatic compounds and also when assessing the related health risk.

Návaznosti

CZ.02.1.01/0.0/0.0/16_013/0001315, interní kód MU

Název: ACTRIS - CZ - RI (Akronym: ACTRIS-CZ RI)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, ACTRIS - CZ - RI, PO 1 Posilování kapacit pro kvalitní výzkum

EF16_013/0001761, projekt VaV

Název: RECETOX RI

GA20-07117S, projekt VaV

Název: Nitro- a oxyderiváty polycyklických aromatických uhlovodíků v atmosféře - distribuce, výměna mezi ovzduším a povrchy a potenciál dálkového přenosu

Investor: Grantová agentura ČR, Nitro- a oxyderiváty polycyklických aromatických uhlovodíků v atmosféře - distribuce, výměna mezi ovzduším a povrchy a potenciál dálkového přenosu

LM2018121, projekt VaV

Název: Výzkumná infrastruktura RECETOX (Akronym: RECETOX RI)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, RECETOX RI

LM2018122, projekt VaV

Název: ACTRIS – účast České republiky

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, ACTRIS-CZ

689443, interní kód MU

Název: ERA-PLANET - The European network for observing our changing planet (Akronym: ERA-PLANET)

Investor: Evropská unie, ERA-PLANET - The European network for observing our changing planet, Climate action, environment, resource efficiency and raw materials (Societal Challenges)

690105, interní kód MU

Název: ICARUS - Integrated Climate forcing and Air pollution Reduction in Urban Systems (Akronym: ICARUS)

Investor: Evropská unie, ICARUS - Integrated Climate forcing and Air pollution Reduction in Urban Systems, Climate action, environment, resource efficiency and raw materials (Societal Challenges)

Citovat

DEGRENDELE, Céline, Tjasa KANDUC, David KOCMAN, Gerhard LAMMEL, Adriana CAMBELOVÁ, Saul Garcia DOS SANTOS, Milena HORVAT, Petr KUKUČKA, Adela SMEJKALOVA HOLUBOVA, Ondřej MIKEŠ, Beatriz NUNEZ-CORCUERA, Petra PŘIBYLOVÁ, Roman PROKEŠ, Ondřej SÁŇKA, Thomas MAGGOS, Denis SARIGIANNIS a Jana KLÁNOVÁ. NPAHs and OPAHs in the atmosphere of two central European cities: Seasonality, urban-to-background gradients, cancer risks and gas-to-particle partitioning. Science of the Total Environment. Amsterdam: Elsevier Science, 2021, roč. 793, November 2021, s. 1-12. ISSN 0048-9697. Dostupné z: https://dx.doi.org/10.1016/j.scitotenv.2021.148528.

@article{1795917,
   author = {Degrendele, Céline and Kanduc, Tjasa and Kocman, David and Lammel, Gerhard and Cambelová, Adriana and Dos Santos, Saul Garcia and Horvat, Milena and Kukučka, Petr and Smejkalova Holubova, Adela and Mikeš, Ondřej and NunezandCorcuera, Beatriz and Přibylová, Petra and Prokeš, Roman and Sáňka, Ondřej and Maggos, Thomas and Sarigiannis, Denis and Klánová, Jana},
   article_location = {Amsterdam},
   article_number = {November 2021},
   doi = {http://dx.doi.org/10.1016/j.scitotenv.2021.148528},
   keywords = {Polycyclic aromatic hydrocarbons; Fine particles; Atmosphere; Spatial variations; Cancer risk},
   language = {eng},
   issn = {0048-9697},
   journal = {Science of the Total Environment},
   title = {NPAHs and OPAHs in the atmosphere of two central European cities: Seasonality, urban-to-background gradients, cancer risks and gas-to-particle partitioning},
   url = {https://www.sciencedirect.com/science/article/pii/S0048969721036007?via%3Dihub},
   volume = {793},
   year = {2021}
}

TY  - JOUR
ID  - 1795917
AU  - Degrendele, Céline - Kanduc, Tjasa - Kocman, David - Lammel, Gerhard - Cambelová, Adriana - Dos Santos, Saul Garcia - Horvat, Milena - Kukučka, Petr - Smejkalova Holubova, Adela - Mikeš, Ondřej - Nunez-Corcuera, Beatriz - Přibylová, Petra - Prokeš, Roman - Sáňka, Ondřej - Maggos, Thomas - Sarigiannis, Denis - Klánová, Jana
PY  - 2021
TI  - NPAHs and OPAHs in the atmosphere of two central European cities: Seasonality, urban-to-background gradients, cancer risks and gas-to-particle partitioning
JF  - Science of the Total Environment
VL  - 793
IS  - November 2021
SP  - 1-12
EP  - 1-12
PB  - Elsevier Science
SN  - 00489697
KW  - Polycyclic aromatic hydrocarbons
KW  - Fine particles
KW  - Atmosphere
KW  - Spatial variations
KW  - Cancer risk
UR  - https://www.sciencedirect.com/science/article/pii/S0048969721036007?via%3Dihub
N2  - Derivatives of polycyclic aromatic hydrocarbons (PAHs) such as nitrated-and oxygenated-PAHs (NPAHs and OPAHs) could be even more toxic and harmful for the environment and humans than PAHs. We assessed the spatial and seasonal variations of NPAHs and OPAHs atmospheric levels, their cancer risks and their gas-to-particle partitioning. To this end, about 250 samples of fine particulate matter (PM2.5) and 50 gaseous samples were collected in 2017 in central Europe in the cities of Brno and Ljubljana (two traffic and two urban background sites) as well as one rural site. The average particulate concentrations were ranging from below limit of quantification to 593 pg m-3 for Sigma 9NPAHs and from 1.64 to 4330 pg m(-3) for Sigma 11OPAHs, with significantly higher concentrations in winter compared to summer. In winter, the particulate levels of NPAHs and OPAHs were higher at the traffic site compared to the urban background site in Brno while the opposite was found in Ljubljana. NPAHs and OPAHs particulate levels were influ-enced by the meteorological parameters and co-varied with several air pollutants. The significance of secondary formation on the occurrence of some NPAHs and OPAHs is indicated. In winter, 27-47% of samples collected at all sites were above the acceptable lifetime carcinogenic risk. The gas-particle partitioning of NPAHs and OPAHs was influenced by their physico-chemical properties, the season and the site-specific aerosol composition. Three NPAHs and five OPAHs had higher particulate mass fractions at the traffic site, suggesting they could be primarily emitted as particles from vehicle traffic and subsequently partitioning to the gas phase along air transport. This study underlines the importance of inclusion of the gas phase in addition to the particulate phase when assessing the atmospheric fate of polycyclic aromatic compounds and also when assessing the related health risk.
ER  -

DEGRENDELE, Céline, Tjasa KANDUC, David KOCMAN, Gerhard LAMMEL, Adriana CAMBELOVÁ, Saul Garcia DOS SANTOS, Milena HORVAT, Petr KUKUČKA, Adela SMEJKALOVA HOLUBOVA, Ondřej MIKEŠ, Beatriz NUNEZ-CORCUERA, Petra PŘIBYLOVÁ, Roman PROKEŠ, Ondřej SÁŇKA, Thomas MAGGOS, Denis SARIGIANNIS a Jana KLÁNOVÁ. NPAHs and OPAHs in the atmosphere of two central European cities: Seasonality, urban-to-background gradients, cancer risks and gas-to-particle partitioning. \textit{Science of the Total Environment}. Amsterdam: Elsevier Science, 2021, roč.~793, November 2021, s.~1-12. ISSN~0048-9697. Dostupné z: https://dx.doi.org/10.1016/j.scitotenv.2021.148528.

Podrobný výpis o publikaci