Coordination polymers of 5-substituted
1,2,3,4-tetracyanocyclopentadienides: structural and
electrochemical properties of complex compounds of 5-amino- and
5-nitro-tetracyanocyclopentadienide

J 2021

Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide

NIMAX, Patrick René, Nils ROTTHOWE, Florian ZOLLER, Tobias BLOCKHAUS, Fritz WAGNER et. al.

Základní údaje

Originální název

Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide

Autoři

NIMAX, Patrick René (276 Německo, garant, domácí), Nils ROTTHOWE, Florian ZOLLER, Tobias BLOCKHAUS, Fritz WAGNER, Dina FATTAKHOVA a Karlheinz SÜNKEL

Vydání

Dalton Transactions, Royal Society of Chemistry, 2021, 1477-9226

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10404 Polymer science

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.569

Kód RIV

RIV/00216224:14310/21:00123145

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1039/d1dt02866a

UT WoS

000720965400001

Klíčová slova anglicky

CHARGE-TRANSFER COMPLEXES; ELECTRON-TRANSFER; CRYSTAL-STRUCTURES; METAL-COMPLEXES; OPEN FRAMEWORK; X-RAY; ANION; TRICYANOMETHANIDE; RADICALS; TCNQ

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 27. 1. 2022 11:57, Mgr. Marie Šípková, DiS.

Anotace

V originále

Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(ii) and iron(iii), silver(i) and potassium(i) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mossbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(i) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer.

Citovat

NIMAX, Patrick René, Nils ROTTHOWE, Florian ZOLLER, Tobias BLOCKHAUS, Fritz WAGNER, Dina FATTAKHOVA a Karlheinz SÜNKEL. Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide. Dalton Transactions. Royal Society of Chemistry, 2021, roč. 50, č. 47, s. 17643-17652. ISSN 1477-9226. Dostupné z: https://dx.doi.org/10.1039/d1dt02866a.

@article{1807861,
   author = {Nimax, Patrick René and Rotthowe, Nils and Zoller, Florian and Blockhaus, Tobias and Wagner, Fritz and Fattakhova, Dina and Sünkel, Karlheinz},
   article_number = {47},
   doi = {http://dx.doi.org/10.1039/d1dt02866a},
   keywords = {CHARGE-TRANSFER COMPLEXES; ELECTRON-TRANSFER; CRYSTAL-STRUCTURES; METAL-COMPLEXES; OPEN FRAMEWORK; X-RAY; ANION; TRICYANOMETHANIDE; RADICALS; TCNQ},
   language = {eng},
   issn = {1477-9226},
   journal = {Dalton Transactions},
   title = {Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide},
   url = {https://pubs.rsc.org/en/content/articlelanding/2021/dt/d1dt02866a},
   volume = {50},
   year = {2021}
}

TY  - JOUR
ID  - 1807861
AU  - Nimax, Patrick René - Rotthowe, Nils - Zoller, Florian - Blockhaus, Tobias - Wagner, Fritz - Fattakhova, Dina - Sünkel, Karlheinz
PY  - 2021
TI  - Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide
JF  - Dalton Transactions
VL  - 50
IS  - 47
SP  - 17643-17652
EP  - 17643-17652
PB  - Royal Society of Chemistry
SN  - 14779226
KW  - CHARGE-TRANSFER COMPLEXES
KW  - ELECTRON-TRANSFER
KW  - CRYSTAL-STRUCTURES
KW  - METAL-COMPLEXES
KW  - OPEN FRAMEWORK
KW  - X-RAY
KW  - ANION
KW  - TRICYANOMETHANIDE
KW  - RADICALS
KW  - TCNQ
UR  - https://pubs.rsc.org/en/content/articlelanding/2021/dt/d1dt02866a
N2  - Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(ii) and iron(iii), silver(i) and potassium(i) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mossbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(i) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer.
ER  -

NIMAX, Patrick René, Nils ROTTHOWE, Florian ZOLLER, Tobias BLOCKHAUS, Fritz WAGNER, Dina FATTAKHOVA a Karlheinz SÜNKEL. Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide. \textit{Dalton Transactions}. Royal Society of Chemistry, 2021, roč.~50, č.~47, s.~17643-17652. ISSN~1477-9226. Dostupné z: https://dx.doi.org/10.1039/d1dt02866a.

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