NIMAX, Patrick René, Nils ROTTHOWE, Florian ZOLLER, Tobias BLOCKHAUS, Fritz WAGNER, Dina FATTAKHOVA a Karlheinz SÜNKEL. Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide. Dalton Transactions. Royal Society of Chemistry, 2021, roč. 50, č. 47, s. 17643-17652. ISSN 1477-9226. Dostupné z: https://dx.doi.org/10.1039/d1dt02866a. |
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@article{1807861, author = {Nimax, Patrick René and Rotthowe, Nils and Zoller, Florian and Blockhaus, Tobias and Wagner, Fritz and Fattakhova, Dina and Sünkel, Karlheinz}, article_number = {47}, doi = {http://dx.doi.org/10.1039/d1dt02866a}, keywords = {CHARGE-TRANSFER COMPLEXES; ELECTRON-TRANSFER; CRYSTAL-STRUCTURES; METAL-COMPLEXES; OPEN FRAMEWORK; X-RAY; ANION; TRICYANOMETHANIDE; RADICALS; TCNQ}, language = {eng}, issn = {1477-9226}, journal = {Dalton Transactions}, title = {Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide}, url = {https://pubs.rsc.org/en/content/articlelanding/2021/dt/d1dt02866a}, volume = {50}, year = {2021} }
TY - JOUR ID - 1807861 AU - Nimax, Patrick René - Rotthowe, Nils - Zoller, Florian - Blockhaus, Tobias - Wagner, Fritz - Fattakhova, Dina - Sünkel, Karlheinz PY - 2021 TI - Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide JF - Dalton Transactions VL - 50 IS - 47 SP - 17643-17652 EP - 17643-17652 PB - Royal Society of Chemistry SN - 14779226 KW - CHARGE-TRANSFER COMPLEXES KW - ELECTRON-TRANSFER KW - CRYSTAL-STRUCTURES KW - METAL-COMPLEXES KW - OPEN FRAMEWORK KW - X-RAY KW - ANION KW - TRICYANOMETHANIDE KW - RADICALS KW - TCNQ UR - https://pubs.rsc.org/en/content/articlelanding/2021/dt/d1dt02866a N2 - Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(ii) and iron(iii), silver(i) and potassium(i) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mossbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(i) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer. ER -
NIMAX, Patrick René, Nils ROTTHOWE, Florian ZOLLER, Tobias BLOCKHAUS, Fritz WAGNER, Dina FATTAKHOVA a Karlheinz SÜNKEL. Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide. \textit{Dalton Transactions}. Royal Society of Chemistry, 2021, roč.~50, č.~47, s.~17643-17652. ISSN~1477-9226. Dostupné z: https://dx.doi.org/10.1039/d1dt02866a.
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