Effect of Low Molecular Weight Oxidized Materials and Nitrogen
Groups on Adhesive Joints of Polypropylene Treated by a Cold
Atmospheric Plasma Jet

J 2021

Effect of Low Molecular Weight Oxidized Materials and Nitrogen Groups on Adhesive Joints of Polypropylene Treated by a Cold Atmospheric Plasma Jet

POLÁŠKOVÁ, Kateřina, Miloš KLÍMA, Zdeňka JENÍKOVÁ, Lucie BLAHOVÁ, Lenka ZAJÍČKOVÁ et. al.

Základní údaje

Originální název

Effect of Low Molecular Weight Oxidized Materials and Nitrogen Groups on Adhesive Joints of Polypropylene Treated by a Cold Atmospheric Plasma Jet

Autoři

POLÁŠKOVÁ, Kateřina (203 Česká republika, domácí), Miloš KLÍMA, Zdeňka JENÍKOVÁ, Lucie BLAHOVÁ a Lenka ZAJÍČKOVÁ (203 Česká republika, garant, domácí)

Vydání

Polymers, MDPI, 2021, 2073-4360

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10305 Fluids and plasma physics

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.967

Kód RIV

RIV/00216224:14310/21:00123678

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.3390/polym13244396

UT WoS

000738931900001

Klíčová slova anglicky

cold atmospheric plasma; plasma treatment; adhesion; polypropylene; X-ray photoelectron spectroscopy; water contact angle

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 15. 2. 2023 19:00, doc. Mgr. Lenka Zajíčková, Ph.D.

Anotace

V originále

Polypropylene is a typical representative of synthetic polymers that, for many applications including adhesive joints, requires an increase in wettability and chemical surface reactivity. Plasma processing offers efficient methods for such surface modifications. A particular disadvantage of the plasma jets can be the small plasma area. Here, we present a cold atmospheric plasma radio-frequency slit jet developed with a width of 150 mm applied to polypropylene plasma treatment in Ar, Ar/O2 and Ar/N2 We identified two main parameters influencing the tensile strength of adhesive joints mediated by epoxy adhesive DP 190, nitrogen content, and the amount of low molecular weight oxidized materials (LMWOMs). Nitrogen functional groups promoted adhesion between epoxy adhesive DP 190 and the PP by taking part in the curing process. LMWOMs formed a weak boundary layer, inhibiting adhesion by inducing a cohesive failure of the joint. A trade off between these two parameters determined the optimized conditions at which the strength of the adhesive joint increased 4.5 times. Higher adhesion strength was previously observed when using a translational plasma gliding arc plasma jet with higher plasma gas temperatures, resulting in better cross linking of polymer chains caused by local PP melting.

Citovat

POLÁŠKOVÁ, Kateřina, Miloš KLÍMA, Zdeňka JENÍKOVÁ, Lucie BLAHOVÁ a Lenka ZAJÍČKOVÁ. Effect of Low Molecular Weight Oxidized Materials and Nitrogen Groups on Adhesive Joints of Polypropylene Treated by a Cold Atmospheric Plasma Jet. Polymers. MDPI, 2021, roč. 13, č. 24, s. 4396-4413. ISSN 2073-4360. Dostupné z: https://dx.doi.org/10.3390/polym13244396.

@article{1820123,
   author = {Polášková, Kateřina and Klíma, Miloš and Jeníková, Zdeňka and Blahová, Lucie and Zajíčková, Lenka},
   article_number = {24},
   doi = {http://dx.doi.org/10.3390/polym13244396},
   keywords = {cold atmospheric plasma; plasma treatment; adhesion; polypropylene; X-ray photoelectron spectroscopy; water contact angle},
   language = {eng},
   issn = {2073-4360},
   journal = {Polymers},
   title = {Effect of Low Molecular Weight Oxidized Materials and Nitrogen Groups on Adhesive Joints of Polypropylene Treated by a Cold Atmospheric Plasma Jet},
   url = {https://www.mdpi.com/2073-4360/13/24/4396},
   volume = {13},
   year = {2021}
}

TY  - JOUR
ID  - 1820123
AU  - Polášková, Kateřina - Klíma, Miloš - Jeníková, Zdeňka - Blahová, Lucie - Zajíčková, Lenka
PY  - 2021
TI  - Effect of Low Molecular Weight Oxidized Materials and Nitrogen Groups on Adhesive Joints of Polypropylene Treated by a Cold Atmospheric Plasma Jet
JF  - Polymers
VL  - 13
IS  - 24
SP  - 4396
EP  - 4396
PB  - MDPI
SN  - 20734360
KW  - cold atmospheric plasma
KW  - plasma treatment
KW  - adhesion
KW  - polypropylene
KW  - X-ray photoelectron spectroscopy
KW  - water contact angle
UR  - https://www.mdpi.com/2073-4360/13/24/4396
N2  - Polypropylene is a typical representative of synthetic polymers that, for many applications including adhesive joints, requires an increase in wettability and chemical surface reactivity. Plasma processing offers efficient methods for such surface modifications. A particular disadvantage of the plasma jets can be the small plasma area. Here, we present a cold atmospheric plasma radio-frequency slit jet developed with a width of 150 mm applied to polypropylene plasma treatment in Ar, Ar/O2 and Ar/N2 We identified two main parameters influencing the tensile strength of adhesive joints mediated by epoxy adhesive DP 190, nitrogen content, and the amount of low molecular weight oxidized materials (LMWOMs). Nitrogen functional groups promoted adhesion between epoxy adhesive DP 190 and the PP by taking part in the curing process. LMWOMs formed a weak boundary layer, inhibiting adhesion by inducing a cohesive failure of the joint. A trade off between these two parameters determined the optimized conditions at which the strength of the adhesive joint increased 4.5 times. Higher adhesion strength was previously observed when using a translational plasma gliding arc plasma jet with higher plasma gas temperatures, resulting in better cross linking of polymer chains caused by local PP melting.
ER  -

POLÁŠKOVÁ, Kateřina, Miloš KLÍMA, Zdeňka JENÍKOVÁ, Lucie BLAHOVÁ a Lenka ZAJÍČKOVÁ. Effect of Low Molecular Weight Oxidized Materials and Nitrogen Groups on Adhesive Joints of Polypropylene Treated by a Cold Atmospheric Plasma Jet. \textit{Polymers}. MDPI, 2021, roč.~13, č.~24, s.~4396-4413. ISSN~2073-4360. Dostupné z: https://dx.doi.org/10.3390/polym13244396.

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