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@article{1824450,
author = {Trnková, Libuše},
article_location = {Lausanne},
article_number = {January},
doi = {http://dx.doi.org/10.1016/j.jelechem.2021.115961},
keywords = {Elimination voltammetry with linear scan (EVLS); Voltammetric current component; Elimination function; Adsorbed electroactive species; Peak-counterpeak elimination signal; Preceding chemical reaction},
language = {eng},
issn = {1572-6657},
journal = {Journal of Electroanalytical Chemistry},
title = {Elimination voltammetry as an innovative tool of electroanalysis},
url = {https://www.sciencedirect.com/science/article/pii/S1572665721009887},
volume = {905},
year = {2022}
}
TY - JOUR
ID - 1824450
AU - Trnková, Libuše
PY - 2022
TI - Elimination voltammetry as an innovative tool of electroanalysis
JF - Journal of Electroanalytical Chemistry
VL - 905
IS - January
SP - 115961
EP - 115961
PB - Elsevier
SN - 15726657
KW - Elimination voltammetry with linear scan (EVLS)
KW - Voltammetric current component
KW - Elimination function
KW - Adsorbed electroactive species
KW - Peak-counterpeak elimination signal
KW - Preceding chemical reaction
UR - https://www.sciencedirect.com/science/article/pii/S1572665721009887
N2 - The review presents the application potential of elimination voltammetry with linear scan (EVLS) in the electroanalysis of organic and inorganic electroactive substances. This innovative method can be considered a software tool that transforms the total current-voltage records measured at different scan rates into elimination functions providing new useful information about a given electrode process. Some EVLS functions are capable of separating overlapped voltammetric signals, identifying the adsorbed state of the analyze, and detecting the preceding chemical reaction before the electron transfer. EVLS finds use in solving the mechanisms of electrode processes and determining significant physicochemical parameters, such as charge transfer coefficients and electrochemical equilibrium protonation constants. This review selects and draws attention to certain problems that may accompany EVLS in voltammetric experiments on solid electrodes.
ER -
TRNKOVÁ, Libuše. Elimination voltammetry as an innovative tool of electroanalysis. \textit{Journal of Electroanalytical Chemistry}. Lausanne: Elsevier, 2022, roč.~905, January, s.~115961-115969. ISSN~1572-6657. Dostupné z: https://dx.doi.org/10.1016/j.jelechem.2021.115961.
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