A new cotton functionalized with iron(III) trimer-like metal
framework as an effective strategy for the adsorption of
triarylmethane dye: An insight into the dye adsorption
processes

J 2021

A new cotton functionalized with iron(III) trimer-like metal framework as an effective strategy for the adsorption of triarylmethane dye: An insight into the dye adsorption processes

CONDE-GONZÁLEZ, José Elías, Pablo LORENZO-LUIS, Victoria SALVADÓ, Josef HAVEL, Eladia Maria PENA-MÉNDEZ et. al.

Základní údaje

Originální název

A new cotton functionalized with iron(III) trimer-like metal framework as an effective strategy for the adsorption of triarylmethane dye: An insight into the dye adsorption processes

Autoři

CONDE-GONZÁLEZ, José Elías, Pablo LORENZO-LUIS, Victoria SALVADÓ, Josef HAVEL (203 Česká republika, domácí) a Eladia Maria PENA-MÉNDEZ

Vydání

Heliyon, Elsevier Ltd, 2021, 2405-8440

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10400 1.4 Chemical sciences

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 3.776

Kód RIV

RIV/00216224:14310/21:00123857

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.heliyon.2021.e08524

UT WoS

000740741300008

Klíčová slova anglicky

Natural cotton; Fe-BTC; Water; Solvation; desolvation penalty processes; Triphenylmetane dye; Adsorption

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 20. 1. 2022 09:47, Mgr. Marie Šípková, DiS.

Anotace

V originále

A new Cotton@Fe-BTC composite formed by Fe-BTC (BTC-H3 : trimesic acid) metal framework (Fe-BTC MOF loading as high 38 wt %) supported by cellulose fibre is synthesised in aqueous media using a simple and green preparation method, described for the first time in this manuscript. This new strategy relies on the synergetic effect of the pure cellulose and MOFs frameworks resulting in hybrid nanofibers of MOFs@cellulose composite. A complete characterization of the composite material reveals its structural similarity to MIL-100(Fe), a Fe-BTC material. The Cotton@Fe-BTC composite potential use as an eco-friendly and low-cost adsorbent was evaluated for its adsorptive performance for the removal of dyes belonging to the triarylmethane dye family (Malachite Green (MQ), Brilliant Green (BG), Pararosaniline (PR), Basic Fuchsine (BF), Crystal Violet (CV), Methyl Green (Met-G), Victoria Blue B (VB), Acid Fuchsin (AF) and Aniline Blue (AB)) in aqueous solution. The fast kinetics and high dye removal efficiencies ( > 90%) obtained in aqueous solutions. The structure of Cotton@Fe-BTC netwok, contributed to the remarkable adsorption properties towards a variety of triphenylmethanedyes. The interparticle studies showed two main steps in the dye’s adsorption processes, with the exception of AF and BG. The equilibrium adsorption capacities qe (mg/g) follow the order: AF (3.64) < Met-G (3.70) < AB (4.87) < PR (5.52) < BF (5.76) < Met-G (7.22) < CV (9.63) < BG (16.34). However, going insight the adsorption mechanisms, it was remarkable the finding that the reaction paths taking into account the influence of water molecules on the anionic dye adsorption, through the so-called solvation/desolvation penalty processes, may not be ignored. The easy preparation and manipulation of Cotton@Fe-BTC network as well as its stability and excellent performance for the adsorption makes this material a good candidate for a broad range of applications.

Citovat

CONDE-GONZÁLEZ, José Elías, Pablo LORENZO-LUIS, Victoria SALVADÓ, Josef HAVEL a Eladia Maria PENA-MÉNDEZ. A new cotton functionalized with iron(III) trimer-like metal framework as an effective strategy for the adsorption of triarylmethane dye: An insight into the dye adsorption processes. Heliyon. Elsevier Ltd, 2021, roč. 7, č. 12, s. "e08524", 13 s. ISSN 2405-8440. Dostupné z: https://dx.doi.org/10.1016/j.heliyon.2021.e08524.

@article{1824452,
   author = {CondeandGonzález, José Elías and LorenzoandLuis, Pablo and Salvadó, Victoria and Havel, Josef and PenaandMéndez, Eladia Maria},
   article_number = {12},
   doi = {http://dx.doi.org/10.1016/j.heliyon.2021.e08524},
   keywords = {Natural cotton; Fe-BTC; Water; Solvation; desolvation penalty processes; Triphenylmetane dye; Adsorption},
   language = {eng},
   issn = {2405-8440},
   journal = {Heliyon},
   title = {A new cotton functionalized with iron(III) trimer-like metal framework as an effective strategy for the adsorption of triarylmethane dye: An insight into the dye adsorption processes},
   url = {https://www.sciencedirect.com/science/article/pii/S240584402102627X?via%3Dihub},
   volume = {7},
   year = {2021}
}

TY  - JOUR
ID  - 1824452
AU  - Conde-González, José Elías - Lorenzo-Luis, Pablo - Salvadó, Victoria - Havel, Josef - Pena-Méndez, Eladia Maria
PY  - 2021
TI  - A new cotton functionalized with iron(III) trimer-like metal framework as an effective strategy for the adsorption of triarylmethane dye: An insight into the dye adsorption processes
JF  - Heliyon
VL  - 7
IS  - 12
SP  - "e08524"
EP  - "e08524"
PB  - Elsevier Ltd
SN  - 24058440
KW  - Natural cotton
KW  - Fe-BTC
KW  - Water
KW  - Solvation
KW  - desolvation penalty processes
KW  - Triphenylmetane dye
KW  - Adsorption
UR  - https://www.sciencedirect.com/science/article/pii/S240584402102627X?via%3Dihub
N2  - A new Cotton@Fe-BTC composite formed by Fe-BTC (BTC-H3 : trimesic acid) metal framework (Fe-BTC MOF loading as high 38 wt %) supported by cellulose fibre is synthesised in aqueous media using a simple and green preparation method, described for the first time in this manuscript. This new strategy relies on the synergetic effect of the pure cellulose and MOFs frameworks resulting in hybrid nanofibers of MOFs@cellulose composite. A complete characterization of the composite material reveals its structural similarity to MIL-100(Fe), a Fe-BTC material. The Cotton@Fe-BTC composite potential use as an eco-friendly and low-cost adsorbent was evaluated for its adsorptive performance for the removal of dyes belonging to the triarylmethane dye family (Malachite Green (MQ), Brilliant Green (BG), Pararosaniline (PR), Basic Fuchsine (BF), Crystal Violet (CV), Methyl Green (Met-G), Victoria Blue B (VB), Acid Fuchsin (AF) and Aniline Blue (AB)) in aqueous solution. The fast kinetics and high dye removal efficiencies ( > 90%) obtained in aqueous solutions. The structure of Cotton@Fe-BTC netwok, contributed to the remarkable adsorption properties towards a variety of triphenylmethanedyes. The interparticle studies showed two main steps in the dye’s adsorption processes, with the exception of AF and BG. The equilibrium adsorption capacities qe (mg/g) follow the order: AF (3.64) < Met-G (3.70) < AB (4.87) < PR (5.52) < BF (5.76) < Met-G (7.22) < CV (9.63) < BG (16.34). However, going insight the adsorption mechanisms, it was remarkable the finding that the reaction paths taking into account the influence of water molecules on the anionic dye adsorption, through the so-called solvation/desolvation penalty processes, may not be ignored. The easy preparation and manipulation of Cotton@Fe-BTC network as well as its stability and excellent performance for the adsorption makes this material a good candidate for a broad range of applications.
ER  -

CONDE-GONZÁLEZ, José Elías, Pablo LORENZO-LUIS, Victoria SALVADÓ, Josef HAVEL a Eladia Maria PENA-MÉNDEZ. A new cotton functionalized with iron(III) trimer-like metal framework as an effective strategy for the adsorption of triarylmethane dye: An insight into the dye adsorption processes. \textit{Heliyon}. Elsevier Ltd, 2021, roč.~7, č.~12, s.~''e08524'', 13 s. ISSN~2405-8440. Dostupné z: https://dx.doi.org/10.1016/j.heliyon.2021.e08524.

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