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@article{1825240,
author = {DominguezandAlfaro, Antonio and Gomez Perez, Inmaculada Jennifer and Alegret, Nuria and Mecerreyes, David and Prato, Maurizio},
article_number = {3},
doi = {http://dx.doi.org/10.3390/polym13030436},
keywords = {fullerenes; CNT; PEDOT; electropolymerization; functional EDOT monomers},
language = {eng},
issn = {2073-4360},
journal = {Polymers},
title = {2D and 3D Immobilization of Carbon Nanomaterials into PEDOT via Electropolymerization of a Functional Bis-EDOT Monomer},
url = {https://www.mdpi.com/2073-4360/13/3/436},
volume = {13},
year = {2021}
}
TY - JOUR
ID - 1825240
AU - Dominguez-Alfaro, Antonio - Gomez Perez, Inmaculada Jennifer - Alegret, Nuria - Mecerreyes, David - Prato, Maurizio
PY - 2021
TI - 2D and 3D Immobilization of Carbon Nanomaterials into PEDOT via Electropolymerization of a Functional Bis-EDOT Monomer
JF - Polymers
VL - 13
IS - 3
SP - 1-15
EP - 1-15
PB - MDPI
SN - 20734360
KW - fullerenes
KW - CNT
KW - PEDOT
KW - electropolymerization
KW - functional EDOT monomers
UR - https://www.mdpi.com/2073-4360/13/3/436
N2 - Carbon nanomaterials (CNMs) and conjugated polymers (CPs) are actively investigated in applications such as optics, catalysis, solar cells, and tissue engineering. Generally, CNMs are implemented in devices where the relationship between the active elements and the micro and nanostructure has a crucial role. However, they present some limitations related to solubility, processibility and release or degradability that affect their manufacturing. CPs, such as poly(3,4-ethylenedioxythiophene) (PEDOT) or derivatives can hide this limitation by electrodeposition onto an electrode. In this work we have explored two different CNMs immobilization methods in 2D and 3D structures. First, CNM/CP hybrid 2D films with enhanced electrochemical properties have been developed using bis-malonyl PEDOT and fullerene C-60. The resulting 2D films nanoparticulate present novel electrochromic properties. Secondly, 3D porous self-standing scaffolds were prepared, containing carbon nanotubes and PEDOT by using the same bis-EDOT co-monomer, which show porosity and topography dependence on the composition. This article shows the validity of electropolymerization to obtain 2D and 3D materials including different carbon nanomaterials and conductive polymers.
ER -
DOMINGUEZ-ALFARO, Antonio, Inmaculada Jennifer GOMEZ PEREZ, Nuria ALEGRET, David MECERREYES a Maurizio PRATO. 2D and 3D Immobilization of Carbon Nanomaterials into PEDOT via Electropolymerization of a Functional Bis-EDOT Monomer. \textit{Polymers}. MDPI, 2021, roč.~13, č.~3, s.~1-15. ISSN~2073-4360. Dostupné z: https://dx.doi.org/10.3390/polym13030436.
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