Novel room temperature ionic liquids and low melting mixtures
based on imidazolium: Cheap ionic solvents for chemical and
biological applications

J 2021

Novel room temperature ionic liquids and low melting mixtures based on imidazolium: Cheap ionic solvents for chemical and biological applications

ARYAFARD, M., B. MINOFAR, E. CSEFALVAY, L. MALINOVA, D. REHA et. al.

Základní údaje

Originální název

Novel room temperature ionic liquids and low melting mixtures based on imidazolium: Cheap ionic solvents for chemical and biological applications

Autoři

ARYAFARD, M., B. MINOFAR, E. CSEFALVAY, L. MALINOVA a D. REHA

Vydání

JOURNAL OF MOLECULAR LIQUIDS, 2021, 0167-7322

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10400 1.4 Chemical sciences

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 6.633

Kód RIV

RIV/00216224:14740/21:00124501

Organizační jednotka

Středoevropský technologický institut

DOI

http://dx.doi.org/10.1016/j.molliq.2021.117877

UT WoS

000713873400021

Klíčová slova anglicky

Protic ionic liquidsDesigner solventsNew ionic solvents based on imidazoliumGreen solventsNon-aqueous solvents for carbohydratesdeep eutectic solventslow melting mixtures Keywords PlusCHLORIDESTABILITYDESS

Štítky

CF NMR, ne MU, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 18. 5. 2022 15:04, Mgr. Pavla Foltynová, Ph.D.

Anotace

V originále

Novel protic ionic liquids (PILs) and low melting mixtures (LMMs) have been synthesized based on green components, cheap sources, the high purity, and easy way of preparation. PILs include [Im][For], [Im] [Ace], [Im][Pro], [Im][But], and [Im][Pen]. LMMs include [ImCl][EG], [ImCl][Gly], [ImCl][PEG], [ImCl] [ETA], and [ImCl][carbohydrate] + DMSO. These solvents contain imidazolium/imidazolium chloride as a cation/salt. NMR spectroscopy was used to analyze the structures of solvents. Melting points, and thermal stabilities were measured via thermal analyses. We were looking to synthesize new DESs with imidazolium chloride (ImCl); Due to lack of observation the melting points for mixtures of ImCl + hydrogen bond donors (HBDs), these mixtures were called low melting mixtures (LMMs) in this work. The mixtures of PILs/LMMs with molecular solvents showed good implications for homogenous and heterogenous systems which can be used for separation goals. Solubilities of carbohydrates, and some amino acids were tested in pure and mixed of ILs with molecular liquids. Adding DMSO to ILs/LMMs increased the dissolution of carbohydrates. As well, adding water to ILs had a remarkable effect for increasing the solubility of amino acids. (C) 2021 Published by Elsevier B.V.

Návaznosti

90127, velká výzkumná infrastruktura

Název: CIISB II

Citovat

ARYAFARD, M., B. MINOFAR, E. CSEFALVAY, L. MALINOVA a D. REHA. Novel room temperature ionic liquids and low melting mixtures based on imidazolium: Cheap ionic solvents for chemical and biological applications. JOURNAL OF MOLECULAR LIQUIDS. 2021, roč. 344, DEC, s. 117877-117883. ISSN 0167-7322. Dostupné z: https://dx.doi.org/10.1016/j.molliq.2021.117877.

@article{1845720,
   author = {Aryafard, M. and Minofar, B. and Csefalvay, E. and Malinova, L. and Reha, D.},
   article_number = {DEC},
   doi = {http://dx.doi.org/10.1016/j.molliq.2021.117877},
   keywords = {Protic ionic liquidsDesigner solventsNew ionic solvents based on imidazoliumGreen solventsNon-aqueous solvents for carbohydratesdeep eutectic solventslow melting mixtures Keywords PlusCHLORIDESTABILITYDESS},
   language = {eng},
   issn = {0167-7322},
   journal = {JOURNAL OF MOLECULAR LIQUIDS},
   title = {Novel room temperature ionic liquids and low melting mixtures based on imidazolium: Cheap ionic solvents for chemical and biological applications},
   url = {https://www.sciencedirect.com/science/article/pii/S0167732221026027?via%3Dihub},
   volume = {344},
   year = {2021}
}

TY  - JOUR
ID  - 1845720
AU  - Aryafard, M. - Minofar, B. - Csefalvay, E. - Malinova, L. - Reha, D.
PY  - 2021
TI  - Novel room temperature ionic liquids and low melting mixtures based on imidazolium: Cheap ionic solvents for chemical and biological applications
JF  - JOURNAL OF MOLECULAR LIQUIDS
VL  - 344
IS  - DEC
SP  - 117877
EP  - 117877
SN  - 01677322
KW  - Protic ionic liquidsDesigner solventsNew ionic solvents based on imidazoliumGreen solventsNon-aqueous solvents for carbohydratesdeep eutectic solventslow melting mixtures Keywords PlusCHLORIDESTABILITYDESS
UR  - https://www.sciencedirect.com/science/article/pii/S0167732221026027?via%3Dihub
N2  - Novel protic ionic liquids (PILs) and low melting mixtures (LMMs) have been synthesized based on green components, cheap sources, the high purity, and easy way of preparation. PILs include [Im][For], [Im] [Ace], [Im][Pro], [Im][But], and [Im][Pen]. LMMs include [ImCl][EG], [ImCl][Gly], [ImCl][PEG], [ImCl] [ETA], and [ImCl][carbohydrate] + DMSO. These solvents contain imidazolium/imidazolium chloride as a cation/salt. NMR spectroscopy was used to analyze the structures of solvents. Melting points, and thermal stabilities were measured via thermal analyses. We were looking to synthesize new DESs with imidazolium chloride (ImCl); Due to lack of observation the melting points for mixtures of ImCl + hydrogen bond donors (HBDs), these mixtures were called low melting mixtures (LMMs) in this work. The mixtures of PILs/LMMs with molecular solvents showed good implications for homogenous and heterogenous systems which can be used for separation goals. Solubilities of carbohydrates, and some amino acids were tested in pure and mixed of ILs with molecular liquids. Adding DMSO to ILs/LMMs increased the dissolution of carbohydrates. As well, adding water to ILs had a remarkable effect for increasing the solubility of amino acids. (C) 2021 Published by Elsevier B.V.
ER  -

ARYAFARD, M., B. MINOFAR, E. CSEFALVAY, L. MALINOVA a D. REHA. Novel room temperature ionic liquids and low melting mixtures based on imidazolium: Cheap ionic solvents for chemical and biological applications. \textit{JOURNAL OF MOLECULAR LIQUIDS}. 2021, roč.~344, DEC, s.~117877-117883. ISSN~0167-7322. Dostupné z: https://dx.doi.org/10.1016/j.molliq.2021.117877.

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