Crystallization of Uranyl Silicate Natroboltwoodite during an
Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal
Structure and Raman Spectroscopy

J 2022

Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy

PLÁŠIL, Jakub, Radek ŠKODA a Karolína FATKOVÁ

Základní údaje

Originální název

Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy

Autoři

PLÁŠIL, Jakub (garant), Radek ŠKODA (203 Česká republika, domácí) a Karolína FATKOVÁ (203 Česká republika, domácí)

Vydání

Crystal Growth and Design, American Chemical Society, 2022, 1528-7483

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10504 Mineralogy

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 3.800

Kód RIV

RIV/00216224:14310/22:00125713

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1021/acs.cgd.1c01152

UT WoS

000757590600001

Klíčová slova anglicky

Dissolution; Minerals; Cations; Crystals; Crystal structure

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 26. 4. 2022 11:52, Mgr. Marie Šípková, DiS.

Anotace

V originále

A synthetic analogue of the mineral natroboltwoodite was obtained unprecedently during a dissolution experiment with the mineral yttrialite-(Y), at a temperature of 200 °C, pressure ∼1.5 MPa, and strongly alkaline conditions. Natroboltwoodite formed along with analcime and aegirine. Single crystals of natroboltwoodite obtained allowed us to reveal its crystal structure for the first time. It differs from the other known uranyl silicate structures in the size of its respective unit-cell volume. The increased size of the structure corresponds to the positional and occupational disorder among one of the Si-tetrahedrally coordinated sites. On the basis of structural complexity parameters, a comparison involving both known synthetic and naturally occurring uranyl silicates is provided and discussed.

Návaznosti

EF16_026/0008459, projekt VaV

Název: Dlouhodobý výzkum geochemických bariér pro ukládání jaderného odpadu

Citovat

PLÁŠIL, Jakub, Radek ŠKODA a Karolína FATKOVÁ. Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy. Crystal Growth and Design. American Chemical Society, 2022, roč. 22, č. 2, s. 1202 - 1211. ISSN 1528-7483. Dostupné z: https://dx.doi.org/10.1021/acs.cgd.1c01152.

@article{1849318,
   author = {Plášil, Jakub and Škoda, Radek and Fatková, Karolína},
   article_number = {2},
   doi = {http://dx.doi.org/10.1021/acs.cgd.1c01152},
   keywords = {Dissolution; Minerals; Cations; Crystals; Crystal structure},
   language = {eng},
   issn = {1528-7483},
   journal = {Crystal Growth and Design},
   title = {Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy},
   url = {https://pubs.acs.org/doi/abs/10.1021/acs.cgd.1c01152},
   volume = {22},
   year = {2022}
}

TY  - JOUR
ID  - 1849318
AU  - Plášil, Jakub - Škoda, Radek - Fatková, Karolína
PY  - 2022
TI  - Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy
JF  - Crystal Growth and Design
VL  - 22
IS  - 2
SP  - 1202 - 1211
EP  - 1202 - 1211
PB  - American Chemical Society
SN  - 15287483
KW  - Dissolution
KW  - Minerals
KW  - Cations
KW  - Crystals
KW  - Crystal structure
UR  - https://pubs.acs.org/doi/abs/10.1021/acs.cgd.1c01152
N2  - A synthetic analogue of the mineral natroboltwoodite was obtained unprecedently during a dissolution experiment with the mineral yttrialite-(Y), at a temperature of 200 °C, pressure ∼1.5 MPa, and strongly alkaline conditions. Natroboltwoodite formed along with analcime and aegirine. Single crystals of natroboltwoodite obtained allowed us to reveal its crystal structure for the first time. It differs from the other known uranyl silicate structures in the size of its respective unit-cell volume. The increased size of the structure corresponds to the positional and occupational disorder among one of the Si-tetrahedrally coordinated sites. On the basis of structural complexity parameters, a comparison involving both known synthetic and naturally occurring uranyl silicates is provided and discussed.
ER  -

PLÁŠIL, Jakub, Radek ŠKODA a Karolína FATKOVÁ. Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy. \textit{Crystal Growth and Design}. American Chemical Society, 2022, roč.~22, č.~2, s.~1202 - 1211. ISSN~1528-7483. Dostupné z: https://dx.doi.org/10.1021/acs.cgd.1c01152.

Podrobný výpis o publikaci