Mapping the X-B-C Systems: Search for the Elusive X2BC Phase

a 2022

Mapping the X-B-C Systems: Search for the Elusive X2BC Phase

SOUČEK, Pavel, Stanislava DEBNÁROVÁ, Mostafa ALISHAHI, Saeed MIRZAEI, Michael KROKER et. al.

Základní údaje

Originální název

Mapping the X-B-C Systems: Search for the Elusive X2BC Phase

Autoři

SOUČEK, Pavel (203 Česká republika, domácí), Stanislava DEBNÁROVÁ (703 Slovensko, domácí), Mostafa ALISHAHI (364 Írán, domácí), Saeed MIRZAEI (364 Írán, domácí), Michael KROKER (203 Česká republika, domácí), Lukáš ZÁBRANSKÝ (203 Česká republika, domácí), Vilma BURŠÍKOVÁ (203 Česká republika, domácí), Zsolt CZIGÁNY (348 Maďarsko), Katalin BALÁZSI (348 Maďarsko), Marcus HANS (276 Německo), Damian HOLZAPFEL (276 Německo), Stanislav MRÁZ (703 Slovensko), Jochen Michael SCHNEIDER (276 Německo) a Petr VAŠINA (203 Česká republika, garant, domácí)

Vydání

48th International Conference on Metallurgical Coatings and Thin Films, 2022

Další údaje

Jazyk

angličtina

Typ výsledku

Konferenční abstrakt

Obor

10305 Fluids and plasma physics

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Kód RIV

RIV/00216224:14310/22:00129079

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

magnetron sputtering;X2BC;borides;carbides

Příznaky

Mezinárodní význam

Změněno: 7. 6. 2022 19:35, doc. Mgr. Pavel Souček, Ph.D.

Anotace

V originále

Binary borides and binary carbides have been known for many decades. Their outstanding mechanical‚ electrical and thermal properties made them indispensable in the industry‚ either in bulk or as thin films. The idea of combining these systems into a ternary X-B-C system naturally evolved. Such systems in the form of bulk have been investigated since the 1950s. The X has been from all of the s‚ p d and f blocks of the periodic table of the elements. Different structures were found. The orthorhombic Mo2BC phase‚ being the first with the X2BC stoichiometry‚ was described by Jeitschko in 1963 [1]. This structure attracted interest for its superconducting properties. Sixty years later‚ this is still the only synthesised X2BC phase. An interest in the X-B-C thin films can be traced to the mid-1980s‚ with experimental work accelerating in the 1990s. The focus was on the Ti-B-C system in the form of multilayers or in the form of a crystalline-crystalline nanocomposite. Superior mechanical properties of this system were described. A renaissance of the X2BC phases‚ this time in the form of the thin films‚ has begun in 2009 when the Mo2BC phase was prepared by direct current magnetron sputtering [2]. This phase was no longer studied for its superconducting properties‚ in which other materials superseded it‚ but for its highly unusual combination of high hardness and moderate ductility. Theoretical studies describing other crystalline ternary X2BC phases predicting the thermodynamic possibility of their preparation together with even better mechanical properties followed [3]. Since then‚ several different systems from these predictions have been studied‚ including W-B-C‚ Nb-B-C and Ta-B-C. No definitive proof of the existence of any X2BC phase apart from the original Mo2BC phase was found. This contribution will cruise through the ups and downs of this research in the last decade. It will be shown that thin films from these systems can have interesting mechanical and thermal properties even without the formation of the desired and elusive X2BC phase. It will be discussed why these phases won’t form even under energetically very harsh conditions such as HiPIMS. We will also sketch the possibilities for the future directions of the studies of the X2BCs.

Návaznosti

GA19-03899S, projekt VaV

Název: Nanolaminátní vrstvy připravené magnetronovým naprašováním - perspektivní tvrdý materiál se zvýšenou lomovou houževnatostí

Investor: Grantová agentura ČR, Nanolaminátní vrstvy připravené magnetronovým naprašováním - perspektivní tvrdý materiál se zvýšenou lomovou houževnatostí

Citovat

SOUČEK, Pavel, Stanislava DEBNÁROVÁ, Mostafa ALISHAHI, Saeed MIRZAEI, Michael KROKER, Lukáš ZÁBRANSKÝ, Vilma BURŠÍKOVÁ, Zsolt CZIGÁNY, Katalin BALÁZSI, Marcus HANS, Damian HOLZAPFEL, Stanislav MRÁZ, Jochen Michael SCHNEIDER a Petr VAŠINA. Mapping the X-B-C Systems: Search for the Elusive X2BC Phase. In 48th International Conference on Metallurgical Coatings and Thin Films. 2022.

@proceedings{1858919,
   author = {Souček, Pavel and Debnárová, Stanislava and Alishahi, Mostafa and Mirzaei, Saeed and Kroker, Michael and Zábranský, Lukáš and Buršíková, Vilma and Czigány, Zsolt and Balázsi, Katalin and Hans, Marcus and Holzapfel, Damian and Mráz, Stanislav and Schneider, Jochen Michael and Vašina, Petr},
   booktitle = {48th International Conference on Metallurgical Coatings and Thin Films},
   keywords = {magnetron sputtering;X2BC;borides;carbides},
   language = {eng},
   title = {Mapping the X-B-C Systems: Search for the Elusive X2BC Phase},
   year = {2022}
}

TY  - CONF
ID  - 1858919
AU  - Souček, Pavel - Debnárová, Stanislava - Alishahi, Mostafa - Mirzaei, Saeed - Kroker, Michael - Zábranský, Lukáš - Buršíková, Vilma - Czigány, Zsolt - Balázsi, Katalin - Hans, Marcus - Holzapfel, Damian - Mráz, Stanislav - Schneider, Jochen Michael - Vašina, Petr
PY  - 2022
TI  - Mapping the X-B-C Systems: Search for the Elusive X2BC Phase
KW  - magnetron sputtering;X2BC;borides;carbides
N2  - Binary borides and binary carbides have been known for many decades. Their outstanding mechanical‚ electrical and thermal properties made them indispensable in the industry‚ either in bulk or as thin films. The idea of combining these systems into a ternary X-B-C system naturally evolved. Such systems in the form of bulk have been investigated since the 1950s. The X has been from all of the s‚ p d and f blocks of the periodic table of the elements. Different structures were found. The orthorhombic Mo2BC phase‚ being the first with the X2BC stoichiometry‚ was described by Jeitschko in 1963 [1]. This structure attracted interest for its superconducting properties. Sixty years later‚ this is still the only synthesised X2BC phase. An interest in the X-B-C thin films can be traced to the mid-1980s‚ with experimental work accelerating in the 1990s. The focus was on the Ti-B-C system in the form of multilayers or in the form of a crystalline-crystalline nanocomposite. Superior mechanical properties of this system were described. A renaissance of the X2BC phases‚ this time in the form of the thin films‚ has begun in 2009 when the Mo2BC phase was prepared by direct current magnetron sputtering [2]. This phase was no longer studied for its superconducting properties‚ in which other materials superseded it‚ but for its highly unusual combination of high hardness and moderate ductility. Theoretical studies describing other crystalline ternary X2BC phases predicting the thermodynamic possibility of their preparation together with even better mechanical properties followed [3]. Since then‚ several different systems from these predictions have been studied‚ including W-B-C‚ Nb-B-C and Ta-B-C. No definitive proof of the existence of any X2BC phase apart from the original Mo2BC phase was found. This contribution will cruise through the ups and downs of this research in the last decade. It will be shown that thin films from these systems can have interesting mechanical and thermal properties even without the formation of the desired and elusive X2BC phase. It will be discussed why these phases won’t form even under energetically very harsh conditions such as HiPIMS. We will also sketch the possibilities for the future directions of the studies of the X2BCs.
ER  -

SOUČEK, Pavel, Stanislava DEBNÁROVÁ, Mostafa ALISHAHI, Saeed MIRZAEI, Michael KROKER, Lukáš ZÁBRANSKÝ, Vilma BURŠÍKOVÁ, Zsolt CZIGÁNY, Katalin BALÁZSI, Marcus HANS, Damian HOLZAPFEL, Stanislav MRÁZ, Jochen Michael SCHNEIDER a Petr VAŠINA. Mapping the X-B-C Systems: Search for the Elusive X2BC Phase. In \textit{48th International Conference on Metallurgical Coatings and Thin Films}. 2022.

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