First functionalized diorganotin (IV) derivative containing the
imidobis(diphenylselenophosphinate-Se,Se') ligand. The
synthesis and X-ray crystal structures of
Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and
Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O

J 1997

First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O

FLORES SANTOS, L., R. CEA OLIVARES, S. HERNANDEZ ORTEGA, RA TOSCANO, V. GARCIA MONTALVO et. al.

Základní údaje

Originální název

First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O

Autoři

FLORES SANTOS, L. (484 Mexiko), R. CEA OLIVARES (484 Mexiko), S. HERNANDEZ ORTEGA (484 Mexiko), RA TOSCANO (484 Mexiko), V. GARCIA MONTALVO (484 Mexiko), J. NOVOSAD (203 Česká republika) a JD WOOLLINS (826 Velká Británie a Severní Irsko)

Vydání

J. Organomet. Chem. 1997, 0022-328X

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.724

Kód RIV

RIV/00216224:14310/97:00000592

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

MOLECULAR-STRUCTURE; ORGANOTIN CARBOXYLATES; CHEMISTRY; COMPLEXES; ACID

Štítky

ACID, chemistry, Complexes, MOLECULAR-STRUCTURE, ORGANOTIN CARBOXYLATES

Změněno: 27. 5. 2003 05:03, doc. RNDr. Josef Novosad, CSc.

Anotace

V originále

Reaction of the appropriate R2SnCl2 with the potassium salt of the imidobis(diphenylselenophosphinate-Se,Se') ligand (1c) in 1:2 stoichiometry yields n-Bu2Sn[{N(SePPh2}(2)-Se,Se')(2)] (2) and Ph2ClSn[N(SePPh2)(2)-Se,Se']. H2O (3). The crystal and the molecular structures of both compounds were determined by X-ray diffractometry. The core geometry in compound 2 is a quasi perfect octahedron. Two selenide ligands are coordinated symmetrically to the tin atom forming a spiro-bicyclic NP2Se2SnSe2P2N system [Sigma(Se-Sn-Se) = 360 degrees]. Both organo substituents are in trans positions [(C'-Sn-C'A) = 180.0(1)degrees] and they are almost perpendicular to the SnSe4 plane. In derivative 3 only one selenium-based ligand is coordinated asymmetrically to the tin atom and unexpectedly a chlorine atom remains attached to the metal center. The geometry around the tin atom corresponds to a distorted trigonal bipyramid with the Se(1) and Cl atoms at the axial positions.

Návaznosti

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

FLORES SANTOS, L., R. CEA OLIVARES, S. HERNANDEZ ORTEGA, RA TOSCANO, V. GARCIA MONTALVO, J. NOVOSAD a JD WOOLLINS. First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O. J. Organomet. Chem. 1997, roč. 1997, č. 544, s. 37-41. ISSN 0022-328X.

@article{197888,
   author = {Flores Santos, L. and Cea Olivares, R. and Hernandez Ortega, S. and Toscano, RA and Garcia Montalvo, V. and Novosad, J. and Woollins, JD},
   article_number = {544},
   keywords = {MOLECULAR-STRUCTURE; ORGANOTIN CARBOXYLATES; CHEMISTRY; COMPLEXES; ACID},
   language = {eng},
   issn = {0022-328X},
   journal = {J. Organomet. Chem.},
   title = {First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O},
   volume = {1997},
   year = {1997}
}

TY  - JOUR
ID  - 197888
AU  - Flores Santos, L. - Cea Olivares, R. - Hernandez Ortega, S. - Toscano, RA - Garcia Montalvo, V. - Novosad, J. - Woollins, JD
PY  - 1997
TI  - First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O
JF  - J. Organomet. Chem.
VL  - 1997
IS  - 544
SP  - 37-41
EP  - 37-41
SN  - 0022328X
KW  - MOLECULAR-STRUCTURE
KW  - ORGANOTIN CARBOXYLATES
KW  - CHEMISTRY
KW  - COMPLEXES
KW  - ACID
N2  - Reaction of the appropriate R2SnCl2 with the potassium salt of the imidobis(diphenylselenophosphinate-Se,Se') ligand (1c) in 1:2 stoichiometry yields n-Bu2Sn[{N(SePPh2}(2)-Se,Se')(2)] (2) and Ph2ClSn[N(SePPh2)(2)-Se,Se']. H2O (3). The crystal and the molecular structures of both compounds were determined by X-ray diffractometry. The core geometry in compound 2 is a quasi perfect octahedron. Two selenide ligands are coordinated symmetrically to the tin atom forming a spiro-bicyclic NP2Se2SnSe2P2N system [Sigma(Se-Sn-Se) = 360 degrees]. Both organo substituents are in trans positions [(C'-Sn-C'A) = 180.0(1)degrees] and they are almost perpendicular to the SnSe4 plane. In derivative 3 only one selenium-based ligand is coordinated asymmetrically to the tin atom and unexpectedly a chlorine atom remains attached to the metal center. The geometry around the tin atom corresponds to a distorted trigonal bipyramid with the Se(1) and Cl atoms at the axial positions.
ER  -

FLORES SANTOS, L., R. CEA OLIVARES, S. HERNANDEZ ORTEGA, RA TOSCANO, V. GARCIA MONTALVO, J. NOVOSAD a JD WOOLLINS. First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[$\{$N(SePPh2)(2)-Se,Se'$\}$(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O. \textit{J. Organomet. Chem.}. 1997, roč.~1997, č.~544, s.~37-41. ISSN~0022-328X.

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