First functionalized diorganotin (IV) derivative containing the
imidobis(diphenylselenophosphinate-Se,Se') ligand. The
synthesis and X-ray crystal structures of
Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and
Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O

J 1997

First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O

FLORES SANTOS, L., R. CEA OLIVARES, S. HERNANDEZ ORTEGA, RA TOSCANO, V. GARCIA MONTALVO et. al.

Basic information

Original name

First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O

Authors

FLORES SANTOS, L. (484 Mexico), R. CEA OLIVARES (484 Mexico), S. HERNANDEZ ORTEGA (484 Mexico), RA TOSCANO (484 Mexico), V. GARCIA MONTALVO (484 Mexico), J. NOVOSAD (203 Czech Republic) and JD WOOLLINS (826 United Kingdom of Great Britain and Northern Ireland)

Edition

J. Organomet. Chem. 1997, 0022-328X

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Switzerland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 1.724

RIV identification code

RIV/00216224:14310/97:00000592

Organization unit

Faculty of Science

Keywords in English

MOLECULAR-STRUCTURE; ORGANOTIN CARBOXYLATES; CHEMISTRY; COMPLEXES; ACID

Abstract

V originále

Reaction of the appropriate R2SnCl2 with the potassium salt of the imidobis(diphenylselenophosphinate-Se,Se') ligand (1c) in 1:2 stoichiometry yields n-Bu2Sn[{N(SePPh2}(2)-Se,Se')(2)] (2) and Ph2ClSn[N(SePPh2)(2)-Se,Se']. H2O (3). The crystal and the molecular structures of both compounds were determined by X-ray diffractometry. The core geometry in compound 2 is a quasi perfect octahedron. Two selenide ligands are coordinated symmetrically to the tin atom forming a spiro-bicyclic NP2Se2SnSe2P2N system [Sigma(Se-Sn-Se) = 360 degrees]. Both organo substituents are in trans positions [(C'-Sn-C'A) = 180.0(1)degrees] and they are almost perpendicular to the SnSe4 plane. In derivative 3 only one selenium-based ligand is coordinated asymmetrically to the tin atom and unexpectedly a chlorine atom remains attached to the metal center. The geometry around the tin atom corresponds to a distorted trigonal bipyramid with the Se(1) and Cl atoms at the axial positions.

Links

MSM 143100011, plan (intention)

Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles

Citovat

FLORES SANTOS, L., R. CEA OLIVARES, S. HERNANDEZ ORTEGA, RA TOSCANO, V. GARCIA MONTALVO, J. NOVOSAD and JD WOOLLINS. First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O. J. Organomet. Chem. 1997, vol. 1997, No 544, p. 37-41. ISSN 0022-328X.

@article{197888,
   author = {Flores Santos, L. and Cea Olivares, R. and Hernandez Ortega, S. and Toscano, RA and Garcia Montalvo, V. and Novosad, J. and Woollins, JD},
   article_number = {544},
   keywords = {MOLECULAR-STRUCTURE; ORGANOTIN CARBOXYLATES; CHEMISTRY; COMPLEXES; ACID},
   language = {eng},
   issn = {0022-328X},
   journal = {J. Organomet. Chem.},
   title = {First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O},
   volume = {1997},
   year = {1997}
}

TY  - JOUR
ID  - 197888
AU  - Flores Santos, L. - Cea Olivares, R. - Hernandez Ortega, S. - Toscano, RA - Garcia Montalvo, V. - Novosad, J. - Woollins, JD
PY  - 1997
TI  - First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)(2)-Se,Se'}(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O
JF  - J. Organomet. Chem.
VL  - 1997
IS  - 544
SP  - 37-41
EP  - 37-41
SN  - 0022328X
KW  - MOLECULAR-STRUCTURE
KW  - ORGANOTIN CARBOXYLATES
KW  - CHEMISTRY
KW  - COMPLEXES
KW  - ACID
N2  - Reaction of the appropriate R2SnCl2 with the potassium salt of the imidobis(diphenylselenophosphinate-Se,Se') ligand (1c) in 1:2 stoichiometry yields n-Bu2Sn[{N(SePPh2}(2)-Se,Se')(2)] (2) and Ph2ClSn[N(SePPh2)(2)-Se,Se']. H2O (3). The crystal and the molecular structures of both compounds were determined by X-ray diffractometry. The core geometry in compound 2 is a quasi perfect octahedron. Two selenide ligands are coordinated symmetrically to the tin atom forming a spiro-bicyclic NP2Se2SnSe2P2N system [Sigma(Se-Sn-Se) = 360 degrees]. Both organo substituents are in trans positions [(C'-Sn-C'A) = 180.0(1)degrees] and they are almost perpendicular to the SnSe4 plane. In derivative 3 only one selenium-based ligand is coordinated asymmetrically to the tin atom and unexpectedly a chlorine atom remains attached to the metal center. The geometry around the tin atom corresponds to a distorted trigonal bipyramid with the Se(1) and Cl atoms at the axial positions.
ER  -

FLORES SANTOS, L., R. CEA OLIVARES, S. HERNANDEZ ORTEGA, RA TOSCANO, V. GARCIA MONTALVO, J. NOVOSAD and JD WOOLLINS. First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se') ligand. The synthesis and X-ray crystal structures of Bu2Sn[$\{$N(SePPh2)(2)-Se,Se'$\}$(2)] and Ph2ClSn[N(SePPh2)(2)-Se,Se'].H2O. \textit{J. Organomet. Chem.}. 1997, vol.~1997, No~544, p.~37-41. ISSN~0022-328X.

Detailed Information on Publication Record