| NOVOSAD, Josef, Marek NEČAS, Jaromír MAREK, Panagiotis VELTSISTAS, Christos PAPADIMITRIOU, Ionel HAIDUC, Makoto WATANABE and Derek J. WOOLLINS. Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles. Inorganica Chimica Acta. USA: Elsevier Science, 1999, vol. 290, No 2, p. 256-260. ISSN 0020-1693. |
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@article{207451,
author = {Novosad, Josef and Nečas, Marek and Marek, Jaromír and Veltsistas, Panagiotis and Papadimitriou, Christos and Haiduc, Ionel and Watanabe, Makoto and Woollins, Derek J.},
article_location = {USA},
article_number = {2},
keywords = {crystal structures; copper complexes; diselenoimidodiphosphinato complexes},
language = {eng},
issn = {0020-1693},
journal = {Inorganica Chimica Acta},
title = {Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles},
volume = {290},
year = {1999}
}
TY - JOUR
ID - 207451
AU - Novosad, Josef - Nečas, Marek - Marek, Jaromír - Veltsistas, Panagiotis - Papadimitriou, Christos - Haiduc, Ionel - Watanabe, Makoto - Woollins, Derek J.
PY - 1999
TI - Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles
JF - Inorganica Chimica Acta
VL - 290
IS - 2
SP - 256
EP - 256
PB - Elsevier Science
SN - 00201693
KW - crystal structures
KW - copper complexes
KW - diselenoimidodiphosphinato complexes
N2 - The reaction of Cu(PPh3)2NO3 with K[Ph2P(Se)-N-P(Se)Ph2] produced a tricoordinate copper(I) complex, Cu(PPh3)[Ph2P(Se)-N-P(Se)Ph2], containing the novel inorganic (carbon-free) CuSe2P2N metallocycle. The same diselenium reagent gave with Co(PPh3)2Cl2 a spirobicyclic compound Co[Ph2P(Se)-N-P(Se)Ph2]2, containing the novel inorganic CoSe2P2N metallocycle. The crystal structure of the two compounds was investigated by X-Ray diffraction. In both compounds the inorganic metallocycles are nonplanar and display strongly distorted twisted boat conformations.
ER -
NOVOSAD, Josef, Marek NEČAS, Jaromír MAREK, Panagiotis VELTSISTAS, Christos PAPADIMITRIOU, Ionel HAIDUC, Makoto WATANABE and Derek J. WOOLLINS. Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles. \textit{Inorganica Chimica Acta}. USA: Elsevier Science, 1999, vol.~290, No~2, p.~256-260. ISSN~0020-1693.
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