New P-S-N containing ring systems. Reaction of
2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disu
lfide and its 4-methoxonaphthalene derivative with
hexamethyldisilazane.

J 1998

New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.

KILIÁN, Petr; Jaromír MAREK; Jiří TOUŽÍN; Otakar HUMPA; Josef NOVOSAD et al.

Basic information

Original name

New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.

Authors

KILIÁN, Petr; Jaromír MAREK ; Jiří TOUŽÍN; Otakar HUMPA; Josef NOVOSAD; J. D. WOOLLINNS and Radek MAREK

Edition

J. Chem. Soc. Dalton Trans. 1998, 0300-9246

Other information

Language

English

Type of outcome

Article in a journal

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

is not subject to a state or trade secret

Impact factor

Impact factor: 2.507

Marked to be transferred to RIV

Yes

RIV identification code

RIV/00216224:14310/98:00005903

Organization unit

Faculty of Science

Keywords in English

X-RAY STRUCTURE; NMR

Abstract

In the original language

Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1 with hexamethyldisilazane (hmds) in acetonitrile gave the N,N'-bis(trimethylsilyl)acetamidinium salt of the [(C10H6)P(S)(NHSiMe3)SP(S)(2)](-) anion 2, a product of P,S, ring cleavage, together with the new thiazaphosphetidine (C10H6)P(S)SN(SiMe3)P(S) 3. Analogous (methoxy derived) products to 2 (2a, 2b) and 3 (3a) were obtained when 2,4-(4-methoxynaphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1a was used instead of 1. When the reaction of 1 with hmds was performed in dichloromethane a mixture of the products was obtained, from which the hexamethyldisilazan-2-ium salt of the anion of identical structure to that in 2 has been isolated. No reaction occurred when a solventless system was used. The new compounds were studied spectroscopically (one-and two-dimensional NMR, IR spectroscopy) and by X-ray crystallography (3, 3a and 4).

Links

GA203/97/0955, research and development project

Name: Studium syntézy, struktury a vazebných poměrů ve sloučeninách obsahujících současně dusík, fosfor, chalkogen a/nebo halogen

Investor: Czech Science Foundation, Synthesis ,structure and bonding of compounds containing phosphorus,nitrogen,chalcogene and/or halogene atoms

Cite

KILIÁN, Petr; Jaromír MAREK; Jiří TOUŽÍN; Otakar HUMPA; Josef NOVOSAD; J. D. WOOLLINNS and Radek MAREK. New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane. (: New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.). J. Chem. Soc. Dalton Trans. 1998, vol. 1998, No 7, p. 1175-1180. ISSN 0300-9246.

@article{211971,
   author = {Kilián, Petr and Marek, Jaromír and Toužín, Jiří and Humpa, Otakar and Novosad, Josef and Woollinns, J. D. and Marek, Radek},
   article_number = {7},
   keywords = {X-RAY STRUCTURE; NMR},
   language = {eng},
   issn = {0300-9246},
   journal = {J. Chem. Soc. Dalton Trans.},
   title = {New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.},
   volume = {1998},
   year = {1998}
}

TY  - JOUR
ID  - 211971
AU  - Kilián, Petr - Marek, Jaromír - Toužín, Jiří - Humpa, Otakar - Novosad, Josef - Woollinns, J. D. - Marek, Radek
PY  - 1998
TI  - New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.
JF  - J. Chem. Soc. Dalton Trans.
VL  - 1998
IS  - 7
SP  - 1175
EP  - 1175
SN  - 03009246
KW  - X-RAY STRUCTURE
KW  - NMR
N2  - Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1 with hexamethyldisilazane (hmds) in acetonitrile gave the N,N'-bis(trimethylsilyl)acetamidinium salt of the [(C10H6)P(S)(NHSiMe3)SP(S)(2)](-) anion 2, a product of P,S, ring cleavage, together with the new thiazaphosphetidine (C10H6)P(S)SN(SiMe3)P(S) 3. Analogous (methoxy derived) products to 2 (2a, 2b) and 3 (3a) were obtained when 2,4-(4-methoxynaphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1a was used instead of 1. When the reaction of 1 with hmds was performed in dichloromethane a mixture of the products was obtained, from which the hexamethyldisilazan-2-ium salt of the anion of identical structure to that in 2 has been isolated. No reaction occurred when a solventless system was used. The new compounds were studied spectroscopically (one-and two-dimensional NMR, IR spectroscopy) and by X-ray crystallography (3, 3a and 4).
ER  -

KILIÁN, Petr; Jaromír MAREK; Jiří TOUŽÍN; Otakar HUMPA; Josef NOVOSAD; J. D. WOOLLINNS and Radek MAREK. New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane. (: New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.). \textit{J. Chem. Soc. Dalton Trans.}. 1998, vol.~1998, No~7, p.~1175-1180. ISSN~0300-9246.

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