New inorganic metallacycles and the first six-membered covalent

J 1999

New inorganic metallacycles and the first six-membered covalent "true" heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry

BIRDSALL, David J., Jason GREEN, Tuan Q. LY, Josef NOVOSAD, Marek NEČAS et. al.

Základní údaje

Originální název

New inorganic metallacycles and the first six-membered covalent "true" heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry

Autoři

BIRDSALL, David J., Jason GREEN, Tuan Q. LY, Josef NOVOSAD (203 Česká republika, garant), Marek NEČAS (203 Česká republika), A. M. Z. SLAWIN, J. D. WOOLLINS a Zdirad ŽÁK (203 Česká republika)

Vydání

Eur. J. Inorg. Chem. Germany, Wiley-VCH Verlag GMBH, 1999, 1434-1948

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Kód RIV

RIV/00216224:14310/99:00001176

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000083540900007

Klíčová slova anglicky

metallacycles; solid-state structures; heterocycles; oxidations

Štítky

heterocycles, metallacycles, oxidations, solid-state structures

Změněno: 25. 6. 2009 12:01, doc. Mgr. Marek Nečas, Ph.D.

Anotace

V originále

Direct oxidation of PhC(O)NHPPh2, H2NC(S)NHPPh2, (CSH4N)C(S)NHPPh2 with O-2, S-8, or Se gives [PhC(O)NHP(O)Ph-2] (1), [H2NC(S)NHP(S)Ph-2] (2), [H2NC(O)NHP(S)Ph-2] (3), [PhC(O)NHP(S)Ph-2] (4), [(C5H4N)C(S)NHP(S)Ph-2] (5), and [H2NC(S)NHP(Se)Ph-2] (6). Deprotonation of 1, 2, 4-6 with potassium tert-butoxide gives K[PhC(O)NP(O)Ph-2] (7), K[H2NC(S)NP(S)Ph-2] (8), K[PhC(O)NP(S)Ph-2] (9), K[(C5H4N)C(S)NP(S)Ph-2] (10), and K[H2NC(S)NP(Se)Ph-2] (11). Reaction of 4 with KOBu and [Cu(Ph3P)(2)][NO3] gives [Cu(Ph3P)(PhC(O)NP(S)Ph-2)] (12) which is the first crystallographically characterised example of a non-ionic six-membered "true" heterocycle (i.e. a ring in which every heterocatom is different). 9 and 10 were treated with [PdCl2(COD)] to give [Pd{PhC(O)NP(S)Ph-2}(2)] (13) and [Pd{(C5H4N)C(O)NP(S)Ph-2}(2)] (14), respectively The anion of 8 coordinates to zinc forming [Zn{H2NC(S)NP(S)Ph-2}(2)] (15). Treatment of 2 or 8 with [PtCl2(COD)] gives [Pt{H2NC(S)NP(S)Ph-2}{H2NC(S)NHP(S)Ph-2}]Cl-+(-) (16) and [Pt{H2NC(S)NP(S)Ph-2}(2)] (17), respectively. The X-ray structures of 12, 15-17 are reported.

Návaznosti

GA203/97/0955, projekt VaV

Název: Studium syntézy, struktury a vazebných poměrů ve sloučeninách obsahujících současně dusík, fosfor, chalkogen a/nebo halogen

Investor: Grantová agentura ČR, Studium syntézy, struktury a vazebných poměrů ve sloučeninách obsahujících současně dusík, fosfor, chalkogen a/nebo halogen

GA203/98/0676, projekt VaV

Název: Krystalová struktura a vazebné poměry sloučenin nekovů V., VI. a VII. grupy periodického systému

Investor: Grantová agentura ČR, Krystalová struktura a vazebné poměry sloučenin nekovů V., VI. a VII. grupy periodického systému

GA203/99/0067, projekt VaV

Název: Pronájem krystalografických databází

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

BIRDSALL, David J., Jason GREEN, Tuan Q. LY, Josef NOVOSAD, Marek NEČAS, A. M. Z. SLAWIN, J. D. WOOLLINS a Zdirad ŽÁK. New inorganic metallacycles and the first six-membered covalent "true" heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry. Eur. J. Inorg. Chem. Germany: Wiley-VCH Verlag GMBH, 1999, roč. 1999, č. 9, s. 1445-1452. ISSN 1434-1948.

@article{212091,
   author = {Birdsall, David J. and Green, Jason and Ly, Tuan Q. and Novosad, Josef and Nečas, Marek and Slawin, A. M. Z. and Woollins, J. D. and Žák, Zdirad},
   article_location = {Germany},
   article_number = {9},
   keywords = {metallacycles; solid-state structures; heterocycles; oxidations},
   language = {eng},
   issn = {1434-1948},
   journal = {Eur. J. Inorg. Chem.},
   title = {New inorganic metallacycles and the first six-membered covalent "true" heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry},
   volume = {1999},
   year = {1999}
}

TY  - JOUR
ID  - 212091
AU  - Birdsall, David J. - Green, Jason - Ly, Tuan Q. - Novosad, Josef - Nečas, Marek - Slawin, A. M. Z. - Woollins, J. D. - Žák, Zdirad
PY  - 1999
TI  - New inorganic metallacycles and the first six-membered covalent "true" heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry
JF  - Eur. J. Inorg. Chem.
VL  - 1999
IS  - 9
SP  - 1445
EP  - 1445
PB  - Wiley-VCH Verlag GMBH
SN  - 14341948
KW  - metallacycles
KW  - solid-state structures
KW  - heterocycles
KW  - oxidations
N2  - Direct oxidation of PhC(O)NHPPh2, H2NC(S)NHPPh2, (CSH4N)C(S)NHPPh2 with O-2, S-8, or Se gives [PhC(O)NHP(O)Ph-2] (1), [H2NC(S)NHP(S)Ph-2] (2), [H2NC(O)NHP(S)Ph-2] (3), [PhC(O)NHP(S)Ph-2] (4), [(C5H4N)C(S)NHP(S)Ph-2] (5), and [H2NC(S)NHP(Se)Ph-2] (6). Deprotonation of 1, 2, 4-6 with potassium tert-butoxide gives K[PhC(O)NP(O)Ph-2] (7), K[H2NC(S)NP(S)Ph-2] (8), K[PhC(O)NP(S)Ph-2] (9), K[(C5H4N)C(S)NP(S)Ph-2] (10), and K[H2NC(S)NP(Se)Ph-2] (11). Reaction of 4 with KOBu and [Cu(Ph3P)(2)][NO3] gives [Cu(Ph3P)(PhC(O)NP(S)Ph-2)] (12) which is the first crystallographically characterised example of a non-ionic six-membered "true" heterocycle (i.e. a ring in which every heterocatom is different). 9 and 10 were treated with [PdCl2(COD)] to give [Pd{PhC(O)NP(S)Ph-2}(2)] (13) and [Pd{(C5H4N)C(O)NP(S)Ph-2}(2)] (14), respectively The anion of 8 coordinates to zinc forming [Zn{H2NC(S)NP(S)Ph-2}(2)] (15). Treatment of 2 or 8 with [PtCl2(COD)] gives [Pt{H2NC(S)NP(S)Ph-2}{H2NC(S)NHP(S)Ph-2}]Cl-+(-) (16) and [Pt{H2NC(S)NP(S)Ph-2}(2)] (17), respectively. The X-ray structures of 12, 15-17 are reported.
ER  -

BIRDSALL, David J., Jason GREEN, Tuan Q. LY, Josef NOVOSAD, Marek NEČAS, A. M. Z. SLAWIN, J. D. WOOLLINS a Zdirad ŽÁK. New inorganic metallacycles and the first six-membered covalent ''true'' heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry. \textit{Eur. J. Inorg. Chem.}. Germany: Wiley-VCH Verlag GMBH, 1999, roč.~1999, č.~9, s.~1445-1452. ISSN~1434-1948.

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