1999
The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry
KLÁN, Petr, Jaromír LITERÁK a Milan HÁJEKZákladní údaje
Originální název
The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry
Autoři
KLÁN, Petr (203 Česká republika, garant), Jaromír LITERÁK (203 Česká republika) a Milan HÁJEK
Vydání
Journal of Photochemistry and Photobiology A: Chemistry, Amsterdam, The Netherlands, Elsevier Science, 1999, 1010-6030
Další údaje
Jazyk
angličtina
Typ výsledku
Článek v odborném periodiku
Obor
10401 Organic chemistry
Stát vydavatele
Nizozemské království
Utajení
není předmětem státního či obchodního tajemství
Impakt faktor
Impact factor: 1.034
Kód RIV
RIV/00216224:14310/99:00001184
Organizační jednotka
Přírodovědecká fakulta
UT WoS
000083774300019
Klíčová slova česky
Fotochemie
Klíčová slova anglicky
Photochemistry
Štítky
Změněno: 7. 4. 2010 18:29, Mgr. Jaromír Literák, Ph.D.
V originále
A simple photochemical reactor has been developed and tested for photochemical reactions. It consisted of an electrodeless discharge lamp (MWL) placed into the reactor vessel of a commercial microwave oven. The microwave (MW) field generated ultraviolet irradiation by the lamp at the same time as it interacted with a studied sample. This technique brings a unique possibility to study the simultaneous effect of both UV/VIS and MW irradiations on photochemical reactions. The use of MWL in a MW reactor has been studied in terms of (1) an operating MW power and temperature influence on the lamp, (2) solvent polarity influence, (3) MWL heating capabilities, and (4) dependence of the photoreaction efficiency on the MW power output. It was found that the lamp produced enough heat to quickly warm up any liquid to boil even in case of 'transparent' liquids in the MW field. An efficiency of light-induced photofragmentation reaction of valerophenone (Type II reaction) was investigated.
Česky
A simple photochemical reactor has been developed and tested for photochemical reactions. It consisted of an electrodeless discharge lamp (MWL) placed into the reactor vessel of a commercial microwave oven. The microwave (MW) field generated ultraviolet irradiation by the lamp at the same time as it interacted with a studied sample. This technique brings a unique possibility to study the simultaneous effect of both UV/VIS and MW irradiations on photochemical reactions. The use of MWL in a MW reactor has been studied in terms of (1) an operating MW power and temperature influence on the lamp, (2) solvent polarity influence, (3) MWL heating capabilities, and (4) dependence of the photoreaction efficiency on the MW power output. It was found that the lamp produced enough heat to quickly warm up any liquid to boil even in case of 'transparent' liquids in the MW field. An efficiency of light-induced photofragmentation reaction of valerophenone (Type II reaction) was investigated.
Návaznosti
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