Ice-nucleating particles near two major dust source regions

J 2022

Ice-nucleating particles near two major dust source regions

BEALL, Charlotte M., Thomas C. J. HILL, Paul J. DEMOTT, Tobias KONEMAN, Michael PIKRIDAS et. al.

Základní údaje

Originální název

Ice-nucleating particles near two major dust source regions

Autoři

Vydání

Atmospheric Chemistry and Physics, Göttingen, Germany, European Geosciences Union, 2022, 1680-7316

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10511 Environmental sciences

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 6.300

Kód RIV

RIV/00216224:14310/22:00127546

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.5194/acp-22-12607-2022

UT WoS

000860521300001

Klíčová slova anglicky

SEA SPRAY AEROSOL; SHIP-BORNE MEASUREMENTS; MINERAL DUST; ARABIAN PENINSULA; MEDITERRANEAN SEA; ACTIVE-SITES; MIXING STATE; SAHARAN DUST; MARINE AIR; NUCLEI

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 3. 1. 2023 09:00, Mgr. Marie Šípková, DiS.

Anotace

V originále

Mineral dust and sea spray aerosol represent important sources of ice-nucleating particles (INPs), the minor fraction of aerosol particles able to trigger cloud ice crystal formation and, consequently, influence multiple climate-relevant cloud properties including lifetime, radiative properties and precipitation initiation efficiency. Mineral dust is considered the dominant INP source in many parts of the world due to its ice nucleation efficiency and its sheer abundance, with global emission rates of up to 4700 Tg a(-1). However, INPs emitted from the ocean surface in sea spray aerosol frequently dominate INP populations in remote marine environments, including parts of the Southern Ocean where cloud-resolving model simulations have demonstrated that cloud radiative properties are likely strongly controlled by INPs. Here we report INP concentrations measured in aerosol and seawater samples during Air Quality and Climate Change in the Arabian Basin (AQABA), a shipborne campaign that spanned the Red Sea, Gulf of Aden, Arabian Sea, Arabian Gulf and part of the Mediterranean. In aerosol samples collected within a few hundred kilometers of the first and second ranked sources of dust globally, the Sahara and Arabian Peninsula, INP concentrations ranged from 0.2 to 11 L-1 at -20 degrees C with observed ice-active surface site densities (n(s)) 1-3 orders of magnitude below levels predicted by mineral dust INP parameterizations. Over half of the samples (at least 14 of 26) were collected during dust storms with average dust mass concentrations between 150 and 490 mu g m(-3) (PM10), as simulated by the Modern-Era Retrospective analysis for Research and Application, version 2 (MERRA-2). The impacts of heat and peroxide treatments indicate that organics dominated the observed ice nucleation (IN) activity at temperatures >= -15 degrees C with proteinaceous (heat-labile) INPs frequently observed at high freezing temperatures > - 10 degrees C. INP concentrations in seawater samples ranged between 3 and 46 mL(-1) at -19 degrees C, demonstrating the relatively low INP source potential of seawater in the region as compared to seawater from multiple other regions reported previously. Overall, our results demonstrate that despite proximity to the Sahara and the Arabian Peninsula and the dominance of mineral dust in the aerosol sampled, existing mineral dust parameterizations alone would not skillfully represent the near-surface n(s) in the observed temperature regime (-6 to -25 degrees C). Future efforts to develop or improve representations of dust INPs at modest supercooling (>= -15 degrees C) would benefit from a characterization of the specific organic species associated with dust INPs. More generally, an improved understanding of the organic species associated with increased IN activity and their variability across dust source regions would directly inform efforts to determine whether n(s)-based parameterizations are appropriate for faithful representation of dust INPs in this sensitive temperature regime, whether region-specific parameterizations are required, or whether an alternative to the n(s) approach is necessary.

Citovat

BEALL, Charlotte M., Thomas C. J. HILL, Paul J. DEMOTT, Tobias KONEMAN, Michael PIKRIDAS, Frank DREWNICK, Hartwig HARDER, Christopher POHLKER, Jos LELIEVELD, Bettina WEBER, Minas IAKOVIDES, Roman PROKEŠ, Jean SCIARE, Meinrat O. ANDREAE, M. Dale STOKES a Kimberly A. PRATHER. Ice-nucleating particles near two major dust source regions. Atmospheric Chemistry and Physics. Göttingen, Germany: European Geosciences Union, 2022, roč. 22, č. 18, s. 12607-12627. ISSN 1680-7316. Dostupné z: https://dx.doi.org/10.5194/acp-22-12607-2022.

@article{2241142,
   author = {Beall, Charlotte M. and Hill, Thomas C. J. and DeMott, Paul J. and Koneman, Tobias and Pikridas, Michael and Drewnick, Frank and Harder, Hartwig and Pohlker, Christopher and Lelieveld, Jos and Weber, Bettina and Iakovides, Minas and Prokeš, Roman and Sciare, Jean and Andreae, Meinrat O. and Stokes, M. Dale and Prather, Kimberly A.},
   article_location = {Göttingen, Germany},
   article_number = {18},
   doi = {http://dx.doi.org/10.5194/acp-22-12607-2022},
   keywords = {SEA SPRAY AEROSOL; SHIP-BORNE MEASUREMENTS; MINERAL DUST; ARABIAN PENINSULA; MEDITERRANEAN SEA; ACTIVE-SITES; MIXING STATE; SAHARAN DUST; MARINE AIR; NUCLEI},
   language = {eng},
   issn = {1680-7316},
   journal = {Atmospheric Chemistry and Physics},
   title = {Ice-nucleating particles near two major dust source regions},
   url = {https://acp.copernicus.org/articles/22/12607/2022/},
   volume = {22},
   year = {2022}
}

TY  - JOUR
ID  - 2241142
AU  - Beall, Charlotte M. - Hill, Thomas C. J. - DeMott, Paul J. - Koneman, Tobias - Pikridas, Michael - Drewnick, Frank - Harder, Hartwig - Pohlker, Christopher - Lelieveld, Jos - Weber, Bettina - Iakovides, Minas - Prokeš, Roman - Sciare, Jean - Andreae, Meinrat O. - Stokes, M. Dale - Prather, Kimberly A.
PY  - 2022
TI  - Ice-nucleating particles near two major dust source regions
JF  - Atmospheric Chemistry and Physics
VL  - 22
IS  - 18
SP  - 12607-12627
EP  - 12607-12627
PB  - European Geosciences Union
SN  - 16807316
KW  - SEA SPRAY AEROSOL
KW  - SHIP-BORNE MEASUREMENTS
KW  - MINERAL DUST
KW  - ARABIAN PENINSULA
KW  - MEDITERRANEAN SEA
KW  - ACTIVE-SITES
KW  - MIXING STATE
KW  - SAHARAN DUST
KW  - MARINE AIR
KW  - NUCLEI
UR  - https://acp.copernicus.org/articles/22/12607/2022/
N2  - Mineral dust and sea spray aerosol represent important sources of ice-nucleating particles (INPs), the minor fraction of aerosol particles able to trigger cloud ice crystal formation and, consequently, influence multiple climate-relevant cloud properties including lifetime, radiative properties and precipitation initiation efficiency. Mineral dust is considered the dominant INP source in many parts of the world due to its ice nucleation efficiency and its sheer abundance, with global emission rates of up to 4700 Tg a(-1). However, INPs emitted from the ocean surface in sea spray aerosol frequently dominate INP populations in remote marine environments, including parts of the Southern Ocean where cloud-resolving model simulations have demonstrated that cloud radiative properties are likely strongly controlled by INPs. Here we report INP concentrations measured in aerosol and seawater samples during Air Quality and Climate Change in the Arabian Basin (AQABA), a shipborne campaign that spanned the Red Sea, Gulf of Aden, Arabian Sea, Arabian Gulf and part of the Mediterranean. In aerosol samples collected within a few hundred kilometers of the first and second ranked sources of dust globally, the Sahara and Arabian Peninsula, INP concentrations ranged from 0.2 to 11 L-1 at -20 degrees C with observed ice-active surface site densities (n(s)) 1-3 orders of magnitude below levels predicted by mineral dust INP parameterizations. Over half of the samples (at least 14 of 26) were collected during dust storms with average dust mass concentrations between 150 and 490 mu g m(-3) (PM10), as simulated by the Modern-Era Retrospective analysis for Research and Application, version 2 (MERRA-2). The impacts of heat and peroxide treatments indicate that organics dominated the observed ice nucleation (IN) activity at temperatures >= -15 degrees C with proteinaceous (heat-labile) INPs frequently observed at high freezing temperatures > - 10 degrees C. INP concentrations in seawater samples ranged between 3 and 46 mL(-1) at -19 degrees C, demonstrating the relatively low INP source potential of seawater in the region as compared to seawater from multiple other regions reported previously. Overall, our results demonstrate that despite proximity to the Sahara and the Arabian Peninsula and the dominance of mineral dust in the aerosol sampled, existing mineral dust parameterizations alone would not skillfully represent the near-surface n(s) in the observed temperature regime (-6 to -25 degrees C). Future efforts to develop or improve representations of dust INPs at modest supercooling (>= -15 degrees C) would benefit from a characterization of the specific organic species associated with dust INPs. More generally, an improved understanding of the organic species associated with increased IN activity and their variability across dust source regions would directly inform efforts to determine whether n(s)-based parameterizations are appropriate for faithful representation of dust INPs in this sensitive temperature regime, whether region-specific parameterizations are required, or whether an alternative to the n(s) approach is necessary.
ER  -

BEALL, Charlotte M., Thomas C. J. HILL, Paul J. DEMOTT, Tobias KONEMAN, Michael PIKRIDAS, Frank DREWNICK, Hartwig HARDER, Christopher POHLKER, Jos LELIEVELD, Bettina WEBER, Minas IAKOVIDES, Roman PROKEŠ, Jean SCIARE, Meinrat O. ANDREAE, M. Dale STOKES a Kimberly A. PRATHER. Ice-nucleating particles near two major dust source regions. \textit{Atmospheric Chemistry and Physics}. Göttingen, Germany: European Geosciences Union, 2022, roč.~22, č.~18, s.~12607-12627. ISSN~1680-7316. Dostupné z: https://dx.doi.org/10.5194/acp-22-12607-2022.

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