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@article{2243511, author = {Kapusta, Jaroslav and Dolníček, Zdeněk and Sracek, Ondra and Malý, Karel}, article_number = {8}, doi = {http://dx.doi.org/10.3390/min12080985}, keywords = {slags; lead; silver; baryte; Jihlava Ore District; archaeometry; smelting}, language = {eng}, issn = {2075-163X}, journal = {Minerals}, title = {Origin of Historical Ba-Rich Slags Related to Pb-Ag Production from Jihlava Ore District (Czech Republic)}, url = {https://www.mdpi.com/2075-163X/12/8/985}, volume = {12}, year = {2022} }
TY - JOUR ID - 2243511 AU - Kapusta, Jaroslav - Dolníček, Zdeněk - Sracek, Ondra - Malý, Karel PY - 2022 TI - Origin of Historical Ba-Rich Slags Related to Pb-Ag Production from Jihlava Ore District (Czech Republic) JF - Minerals VL - 12 IS - 8 SP - 1-25 EP - 1-25 PB - MDPI SN - 2075163X KW - slags KW - lead KW - silver KW - baryte KW - Jihlava Ore District KW - archaeometry KW - smelting UR - https://www.mdpi.com/2075-163X/12/8/985 N2 - The aim of this study was to characterize historical slags which originated during silver production from the Jihlava ore district, Czech Republic. The area was among the head producers of silver within the Lands of the Czech Crown in 13th–14th centuries. The mined ores had complex composition, being formed mostly by pyrite, sphalerite, galena, chalcopyrite, and accessory silver-rich minerals such as silver-bearing tetrahedrite (freibergite) or pyrargyrite, with gangue represented by quartz and Mn-rich carbonates or baryte. Large volumes of slags with contrasting composition were generated during the Pb-Ag production. Altogether, two main types of slags were identified in the district. The first type is characterized by high BaO contents (up to 34.5 wt.%) and dominancy of glass, minor quartz, and accessory amounts of Ba-rich feldspar (up to 93 mol.% of Cls), metal-rich inclusions, Ba-Pb sulphates and only rare pyroxene, wollastonite and melilite. The composition of the second group belongs to fayalitic slags containing glass, Fe-rich olivine, accessory pyroxene, feldspar, quartz, and inclusions of various metallic phases. Fluxes were derived from gangue (quartz, carbonates, baryte) or local host rocks for both types of slag. The calculated viscosity indexes reflect (with minor exceptions) medium-to-high effectivity of metal separation. Smelting temperatures were estimated from a series of ternary plots; however, more reliable estimates for both types of slags were obtained only from experimental determination of melting temperature and calculations using bulk/glass compositions (~1100–1200 °C). ER -
KAPUSTA, Jaroslav, Zdeněk DOLNÍČEK, Ondra SRACEK a Karel MALÝ. Origin of Historical Ba-Rich Slags Related to Pb-Ag Production from Jihlava Ore District (Czech Republic). \textit{Minerals}. MDPI, 2022, roč.~12, č.~8, s.~1-25. ISSN~2075-163X. Dostupné z: https://dx.doi.org/10.3390/min12080985.
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