KAPUSTA, Jaroslav, Zdeněk DOLNÍČEK, Ondra SRACEK a Karel MALÝ. Origin of Historical Ba-Rich Slags Related to Pb-Ag Production from Jihlava Ore District (Czech Republic). Minerals. MDPI, 2022, roč. 12, č. 8, s. 1-25. ISSN 2075-163X. Dostupné z: https://dx.doi.org/10.3390/min12080985.
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Základní údaje
Originální název Origin of Historical Ba-Rich Slags Related to Pb-Ag Production from Jihlava Ore District (Czech Republic)
Autoři KAPUSTA, Jaroslav (203 Česká republika, garant, domácí), Zdeněk DOLNÍČEK, Ondra SRACEK a Karel MALÝ.
Vydání Minerals, MDPI, 2022, 2075-163X.
Další údaje
Originální jazyk angličtina
Typ výsledku Článek v odborném periodiku
Obor 10505 Geology
Stát vydavatele Švýcarsko
Utajení není předmětem státního či obchodního tajemství
WWW URL
Impakt faktor Impact factor: 2.500
Kód RIV RIV/00216224:14310/22:00127679
Organizační jednotka Přírodovědecká fakulta
Doi http://dx.doi.org/10.3390/min12080985
UT WoS 000846696800001
Klíčová slova anglicky slags; lead; silver; baryte; Jihlava Ore District; archaeometry; smelting
Štítky rivok
Příznaky Mezinárodní význam, Recenzováno
Změnil Změnila: Mgr. Marie Šípková, DiS., učo 437722. Změněno: 4. 1. 2023 13:07.
Anotace
The aim of this study was to characterize historical slags which originated during silver production from the Jihlava ore district, Czech Republic. The area was among the head producers of silver within the Lands of the Czech Crown in 13th–14th centuries. The mined ores had complex composition, being formed mostly by pyrite, sphalerite, galena, chalcopyrite, and accessory silver-rich minerals such as silver-bearing tetrahedrite (freibergite) or pyrargyrite, with gangue represented by quartz and Mn-rich carbonates or baryte. Large volumes of slags with contrasting composition were generated during the Pb-Ag production. Altogether, two main types of slags were identified in the district. The first type is characterized by high BaO contents (up to 34.5 wt.%) and dominancy of glass, minor quartz, and accessory amounts of Ba-rich feldspar (up to 93 mol.% of Cls), metal-rich inclusions, Ba-Pb sulphates and only rare pyroxene, wollastonite and melilite. The composition of the second group belongs to fayalitic slags containing glass, Fe-rich olivine, accessory pyroxene, feldspar, quartz, and inclusions of various metallic phases. Fluxes were derived from gangue (quartz, carbonates, baryte) or local host rocks for both types of slag. The calculated viscosity indexes reflect (with minor exceptions) medium-to-high effectivity of metal separation. Smelting temperatures were estimated from a series of ternary plots; however, more reliable estimates for both types of slags were obtained only from experimental determination of melting temperature and calculations using bulk/glass compositions (~1100–1200 °C).
VytisknoutZobrazeno: 3. 8. 2024 04:16