Asymmetric Phase-Transfer Catalysis - From Classical
Applications to New Concepts

C 2022

Asymmetric Phase-Transfer Catalysis - From Classical Applications to New Concepts

OTEVŘEL, Jan a Mario WASER

Základní údaje

Originální název

Asymmetric Phase-Transfer Catalysis - From Classical Applications to New Concepts

Autoři

OTEVŘEL, Jan (203 Česká republika, garant, domácí) a Mario WASER (40 Rakousko)

Vydání

1. vyd. Weinheim, Germany, Asymmetric Organocatalysis: New Strategies, Catalysts, and Opportunities, od s. 71-120, 50 s. 1. vydání, 2022

Nakladatel

WILEY‐VCH GmbH

Další údaje

Jazyk

angličtina

Typ výsledku

Kapitola resp. kapitoly v odborné knize

Obor

30104 Pharmacology and pharmacy

Utajení

není předmětem státního či obchodního tajemství

Forma vydání

tištěná verze "print"

Odkazy

URL

Kód RIV

RIV/00216224:14160/22:00130179

Organizační jednotka

Farmaceutická fakulta

ISBN

978-3-527-83221-7

DOI

http://dx.doi.org/10.1002/9783527832217.ch3

Klíčová slova anglicky

Phase-Transfer Catalysis; Ion-Pairing Catalysis; Organocatalysis

Štítky

rivok, ÚChL

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 5. 4. 2024 07:42, Mgr. Daniela Černá

Anotace

V originále

Asymmetric (ion-pairing) phase-transfer catalysis has emerged as a powerful concept within the realm of asymmetric (organo)-catalysis over the course of the last four decades. Whereas early approaches mainly focused around the use of chiral ammonium salt catalysts for the control of enolate-type nucleophiles, the last years have witnessed a remarkable diversity of novel catalyst motives and new applications, reaching beyond what was classically considered as phase-transfer catalysis. As a consequence, a strict mechanistic classification of whether a reaction is really a phase-transfer-catalyzed process or not is also often not so easily possible anymore, underscoring the diversity of this field. Within this chapter, we wish to highlight the unique potential of chiral cationic, anionic, and neutral phase-transfer catalysts (PTCs) to facilitate challenging target transformations by discussing some of the, in our opinion, most important catalyst classes and applications thereof, with a special focus on some of the most recently introduced concepts.

Citovat

OTEVŘEL, Jan a Mario WASER. Asymmetric Phase-Transfer Catalysis - From Classical Applications to New Concepts. In Łukasz Albrecht, Anna Albrecht, Luca Dell'Amico. Asymmetric Organocatalysis: New Strategies, Catalysts, and Opportunities. 1. vyd. Weinheim, Germany: WILEY‐VCH GmbH, 2022, s. 71-120. 1. vydání. ISBN 978-3-527-83221-7. Dostupné z: https://dx.doi.org/10.1002/9783527832217.ch3.

@inbook{2245937,
   author = {Otevřel, Jan and Waser, Mario},
   address = {Weinheim, Germany},
   booktitle = {Asymmetric Organocatalysis: New Strategies, Catalysts, and Opportunities},
   doi = {http://dx.doi.org/10.1002/9783527832217.ch3},
   edition = {1.},
   editor = {Łukasz Albrecht, Anna Albrecht, Luca Dell'Amico},
   keywords = {Phase-Transfer Catalysis; Ion-Pairing Catalysis; Organocatalysis},
   howpublished = {tištěná verze "print"},
   language = {eng},
   location = {Weinheim, Germany},
   isbn = {978-3-527-83221-7},
   pages = {71-120},
   publisher = {WILEY‐VCH GmbH},
   title = {Asymmetric Phase-Transfer Catalysis - From Classical Applications to New Concepts},
   url = {https://onlinelibrary.wiley.com/doi/10.1002/9783527832217.ch3},
   year = {2022}
}

TY  - CHAP
ID  - 2245937
AU  - Otevřel, Jan - Waser, Mario
PY  - 2022
TI  - Asymmetric Phase-Transfer Catalysis - From Classical Applications to New Concepts
VL  - 1. vydání
PB  - WILEY‐VCH GmbH
CY  - Weinheim, Germany
SN  - 9783527832217
KW  - Phase-Transfer Catalysis
KW  - Ion-Pairing Catalysis
KW  - Organocatalysis
UR  - https://onlinelibrary.wiley.com/doi/10.1002/9783527832217.ch3
N2  - Asymmetric (ion-pairing) phase-transfer catalysis has emerged as a powerful concept within the realm of asymmetric (organo)-catalysis over the course of the last four decades. Whereas early approaches mainly focused around the use of chiral ammonium salt catalysts for the control of enolate-type nucleophiles, the last years have witnessed a remarkable diversity of novel catalyst motives and new applications, reaching beyond what was classically considered as phase-transfer catalysis. As a consequence, a strict mechanistic classification of whether a reaction is really a phase-transfer-catalyzed process or not is also often not so easily possible anymore, underscoring the diversity of this field. Within this chapter, we wish to highlight the unique potential of chiral cationic, anionic, and neutral phase-transfer catalysts (PTCs) to facilitate challenging target transformations by discussing some of the, in our opinion, most important catalyst classes and applications thereof, with a special focus on some of the most recently introduced concepts.
ER  -

OTEVŘEL, Jan a Mario WASER. Asymmetric Phase-Transfer Catalysis - From Classical Applications to New Concepts. In Łukasz Albrecht, Anna Albrecht, Luca Dell'Amico. \textit{Asymmetric Organocatalysis: New Strategies, Catalysts, and Opportunities}. 1. vyd. Weinheim, Germany: WILEY‐VCH GmbH, 2022, s.~71-120. 1. vydání. ISBN~978-3-527-83221-7. Dostupné z: https://dx.doi.org/10.1002/9783527832217.ch3.

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