Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D
Germanane Heterostructures via Click Chemistry

J 2022

Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry

MUNOZ, Jose, Mario PALACIOS-CORELLA, Inmaculada Jennifer GOMEZ PEREZ, Lenka ZAJÍČKOVÁ, Martin PUMERA et. al.

Základní údaje

Originální název

Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry

Autoři

MUNOZ, Jose, Mario PALACIOS-CORELLA, Inmaculada Jennifer GOMEZ PEREZ (724 Španělsko, domácí), Lenka ZAJÍČKOVÁ (203 Česká republika, domácí) a Martin PUMERA (garant)

Vydání

Advanced Materials, Wiley-VCH Verlag GmbH, 2022, 0935-9648

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10405 Electrochemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 29.400

Kód RIV

RIV/00216224:14310/22:00128051

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1002/adma.202206382

UT WoS

000865568200001

Klíčová slova anglicky

2D materials; carbon dots; fluorescence resonance energy transfer; optoelectronics; thiol-ene

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 15. 2. 2023 18:15, doc. Mgr. Lenka Zajíčková, Ph.D.

Anotace

V originále

ucceeding graphene, 2D inorganic materials made of reactive van der Waals layers, like 2D germanane (2D-Ge) derivatives, have attracted great attention because their physicochemical characteristics can be entirely tuned by modulating the nature of the surface substituent. Although very interesting from a scientific point of view, almost all the reported works involving 2D-Ge derivatives are focused on computational studies. Herein, a first prototype of organic–inorganic 2D-Ge heterostructure has been synthesized by covalently anchoring thiol-rich carbon dots (CD–SH) onto 2D allyl germanane (2D-aGe) via a simple and green “one-pot” click chemistry approach. Remarkably, the implanted characteristics of the carbon nanomaterial provide new physicochemical features to the resulting 0D/2D heterostructure, making possible its implementation in yet unexplored optoelectronic tasks—e.g., as a fluorescence resonance energy transfer (FRET) sensing system triggered by supramolecular π–π interactions—that are inaccessible for the pristine 2D-aGe counterpart. Consequently, this work builds a foundation toward the robust achievement of functional organic–inorganic 2D-Ge nanoarchitectonics through covalently assembling thiol-rich carbon nanoallotropes on commercially available 2D-aGe.

Návaznosti

EF20_079/0017045, projekt VaV

Název: MSCAfellow4@MUNI

90110, velká výzkumná infrastruktura

Název: CzechNanoLab

Citovat

MUNOZ, Jose, Mario PALACIOS-CORELLA, Inmaculada Jennifer GOMEZ PEREZ, Lenka ZAJÍČKOVÁ a Martin PUMERA. Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry. Advanced Materials. Wiley-VCH Verlag GmbH, 2022, roč. 34, č. 45, s. 1-8. ISSN 0935-9648. Dostupné z: https://dx.doi.org/10.1002/adma.202206382.

@article{2247374,
   author = {Munoz, Jose and PalaciosandCorella, Mario and Gomez Perez, Inmaculada Jennifer and Zajíčková, Lenka and Pumera, Martin},
   article_number = {45},
   doi = {http://dx.doi.org/10.1002/adma.202206382},
   keywords = {2D materials; carbon dots; fluorescence resonance energy transfer; optoelectronics; thiol-ene},
   language = {eng},
   issn = {0935-9648},
   journal = {Advanced Materials},
   title = {Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry},
   url = {https://doi.org/10.1002/adma.202206382},
   volume = {34},
   year = {2022}
}

TY  - JOUR
ID  - 2247374
AU  - Munoz, Jose - Palacios-Corella, Mario - Gomez Perez, Inmaculada Jennifer - Zajíčková, Lenka - Pumera, Martin
PY  - 2022
TI  - Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry
JF  - Advanced Materials
VL  - 34
IS  - 45
SP  - 1-8
EP  - 1-8
PB  - Wiley-VCH Verlag GmbH
SN  - 09359648
KW  - 2D materials
KW  - carbon dots
KW  - fluorescence resonance energy transfer
KW  - optoelectronics
KW  - thiol-ene
UR  - https://doi.org/10.1002/adma.202206382
N2  - ucceeding graphene, 2D inorganic materials made of reactive van der Waals layers, like 2D germanane (2D-Ge) derivatives, have attracted great attention because their physicochemical characteristics can be entirely tuned by modulating the nature of the surface substituent. Although very interesting from a scientific point of view, almost all the reported works involving 2D-Ge derivatives are focused on computational studies. Herein, a first prototype of organic–inorganic 2D-Ge heterostructure has been synthesized by covalently anchoring thiol-rich carbon dots (CD–SH) onto 2D allyl germanane (2D-aGe) via a simple and green “one-pot” click chemistry approach. Remarkably, the implanted characteristics of the carbon nanomaterial provide new physicochemical features to the resulting 0D/2D heterostructure, making possible its implementation in yet unexplored optoelectronic tasks—e.g., as a fluorescence resonance energy transfer (FRET) sensing system triggered by supramolecular π–π interactions—that are inaccessible for the pristine 2D-aGe counterpart. Consequently, this work builds a foundation toward the robust achievement of functional organic–inorganic 2D-Ge nanoarchitectonics through covalently assembling thiol-rich carbon nanoallotropes on commercially available 2D-aGe.
ER  -

MUNOZ, Jose, Mario PALACIOS-CORELLA, Inmaculada Jennifer GOMEZ PEREZ, Lenka ZAJÍČKOVÁ a Martin PUMERA. Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry. \textit{Advanced Materials}. Wiley-VCH Verlag GmbH, 2022, roč.~34, č.~45, s.~1-8. ISSN~0935-9648. Dostupné z: https://dx.doi.org/10.1002/adma.202206382.

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