Laser ablation synthesis of tellurium carbides using tellurium
with nanodiamond nanocomposite

J 2023

Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite

CHYGORIN, Eduard, Lukáš PEČINKA, Petr VAŇHARA, Karel NOVOTNÝ, Ivo KREMPL et. al.

Základní údaje

Originální název

Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite

Autoři

CHYGORIN, Eduard (804 Ukrajina, domácí), Lukáš PEČINKA (203 Česká republika, domácí), Petr VAŇHARA (203 Česká republika, domácí), Karel NOVOTNÝ (203 Česká republika, domácí), Ivo KREMPL (203 Česká republika, domácí) a Josef HAVEL (203 Česká republika, garant, domácí)

Vydání

Rapid Communications in Mass Spectrometry, Wiley, 2023, 0951-4198

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

20501 Materials engineering

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.000 v roce 2022

Kód RIV

RIV/00216224:14310/23:00131663

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1002/rcm.9520

UT WoS

000980740300001

Klíčová slova anglicky

tellurides; mass spectrometry; synthesis; thin films

Štítky

14110517, podil, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 6. 3. 2024 16:01, Mgr. Marie Šípková, DiS.

Anotace

V originále

Rationale: Carbides, including tellurium carbides (TeC), play crucial roles in diverse applications, but TeC synthesis has not been described in the literature. Laser ablation synthesis (LAS) coupled with mass spectrometry was used here for in situ TeC clusters synthesis and identification of the reaction products to better understand TeC formation. Methods: Laser desorption ionization time-of-flight mass spectrometry (LDI-TOFMS) was used to generate the TeC clusters and determine their stoichiometry via computer modeling of isotopic patterns. Results: A simple one-pot procedure was developed for Te-nanodiamond nanocomposite preparation. A suspension of fine-powdered Te was mixed with a suspension of nanodiamonds (both in acetonitrile), and the resulting precipitated nanocomposite was suitable for the synthesis of TemC(n) clusters using LDI. Various unary and binary clusters were formed. The stoichiometry of the novel TemC(n) clusters, determined via computer modeling of isotopic patterns, is reported here for the first time. Conclusions: The Te-nanodiamond composite was found to be the most suitable precursor for the generation of TemC(n) clusters. In total, 35 binary TemC(n) clusters were identified, when several of them were not obtained using commercial TeC material.

Návaznosti

GA22-07635S, projekt VaV

Název: Pokročilé metody přípravy telluridů polokovů a nepřechodných kovů

Investor: Grantová agentura ČR, Pokročilé metody přípravy telluridů polokovů a nepřechodných kovů

MUNI/A/1298/2022, interní kód MU

Název: Základní a aplikovaný výzkum a vývoj metod chemické a fyzikálně chemické analýzy pro studium přírody a pokročilé technologie

Investor: Masarykova univerzita, Základní a aplikovaný výzkum a vývoj metod chemické a fyzikálně chemické analýzy pro studium přírody a pokročilé technologie

MUNI/A/1301/2022, interní kód MU

Název: Zdroje pro tkáňové inženýrství 13

Investor: Masarykova univerzita, Zdroje pro tkáňové inženýrství 13

Citovat

CHYGORIN, Eduard, Lukáš PEČINKA, Petr VAŇHARA, Karel NOVOTNÝ, Ivo KREMPL a Josef HAVEL. Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite. Rapid Communications in Mass Spectrometry. Wiley, 2023, roč. 37, č. 12, s. 1-6. ISSN 0951-4198. Dostupné z: https://dx.doi.org/10.1002/rcm.9520.

@article{2309958,
   author = {Chygorin, Eduard and Pečinka, Lukáš and Vaňhara, Petr and Novotný, Karel and Krempl, Ivo and Havel, Josef},
   article_number = {12},
   doi = {http://dx.doi.org/10.1002/rcm.9520},
   keywords = {tellurides; mass spectrometry; synthesis; thin films},
   language = {eng},
   issn = {0951-4198},
   journal = {Rapid Communications in Mass Spectrometry},
   title = {Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite},
   url = {https://doi.org/10.1002/rcm.9520},
   volume = {37},
   year = {2023}
}

TY  - JOUR
ID  - 2309958
AU  - Chygorin, Eduard - Pečinka, Lukáš - Vaňhara, Petr - Novotný, Karel - Krempl, Ivo - Havel, Josef
PY  - 2023
TI  - Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite
JF  - Rapid Communications in Mass Spectrometry
VL  - 37
IS  - 12
SP  - 1-6
EP  - 1-6
PB  - Wiley
SN  - 09514198
KW  - tellurides
KW  - mass spectrometry
KW  - synthesis
KW  - thin films
UR  - https://doi.org/10.1002/rcm.9520
N2  - Rationale: Carbides, including tellurium carbides (TeC), play crucial roles in diverse applications, but TeC synthesis has not been described in the literature. Laser ablation synthesis (LAS) coupled with mass spectrometry was used here for in situ TeC clusters synthesis and identification of the reaction products to better understand TeC formation. Methods: Laser desorption ionization time-of-flight mass spectrometry (LDI-TOFMS) was used to generate the TeC clusters and determine their stoichiometry via computer modeling of isotopic patterns. Results: A simple one-pot procedure was developed for Te-nanodiamond nanocomposite preparation. A suspension of fine-powdered Te was mixed with a suspension of nanodiamonds (both in acetonitrile), and the resulting precipitated nanocomposite was suitable for the synthesis of TemC(n) clusters using LDI. Various unary and binary clusters were formed. The stoichiometry of the novel TemC(n) clusters, determined via computer modeling of isotopic patterns, is reported here for the first time. Conclusions: The Te-nanodiamond composite was found to be the most suitable precursor for the generation of TemC(n) clusters. In total, 35 binary TemC(n) clusters were identified, when several of them were not obtained using commercial TeC material.
ER  -

CHYGORIN, Eduard, Lukáš PEČINKA, Petr VAŇHARA, Karel NOVOTNÝ, Ivo KREMPL a Josef HAVEL. Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite. \textit{Rapid Communications in Mass Spectrometry}. Wiley, 2023, roč.~37, č.~12, s.~1-6. ISSN~0951-4198. Dostupné z: https://dx.doi.org/10.1002/rcm.9520.

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