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@article{2334040, author = {Skřápková, Lenka and Cempírek, Jan and Belley, Philippe M. and Groat, Lee A. and Škoda, Radek}, article_location = {London}, article_number = {5}, doi = {http://dx.doi.org/10.1180/mgm.2023.59}, keywords = {oxy-dravite; crystal structure; Beluga; EMPA; LA-ICP-MS; Al-Mg disorder; Raman spectroscopy}, language = {eng}, issn = {0026-461X}, journal = {Mineralogical Magazine}, title = {Physical properties and crystal structure of near end-member oxy-dravite from the Beluga occurrence, Nunavut territory, Canada}, url = {https://doi.org/10.1180/mgm.2023.59}, volume = {87}, year = {2023} }
TY - JOUR ID - 2334040 AU - Skřápková, Lenka - Cempírek, Jan - Belley, Philippe M. - Groat, Lee A. - Škoda, Radek PY - 2023 TI - Physical properties and crystal structure of near end-member oxy-dravite from the Beluga occurrence, Nunavut territory, Canada JF - Mineralogical Magazine VL - 87 IS - 5 SP - 719-730 EP - 719-730 PB - Mineralogical Society SN - 0026461X KW - oxy-dravite KW - crystal structure KW - Beluga KW - EMPA KW - LA-ICP-MS KW - Al-Mg disorder KW - Raman spectroscopy UR - https://doi.org/10.1180/mgm.2023.59 N2 - Oxy-dravite, ideally Na(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3(O), was found in a composition near its ideal end-member at the Beluga occurrence, Nunavut territory, Canada. It occurs in retrograde albite–muscovite–corundum–calcite domains in a calc-silicate rock. This uncommon oxy-dravite occurs as dark brown, equant to short-prismatic, idiomorphic crystals with vitreous lustre and up to ca. 4 × 3 cm in size. The oxy-dravite is optically uniaxial (–), with ω = 1.6453(5) and ε = 1.6074(18); its calculated density is 3.069 g.cm–3 with a compatibility index of 0.016. The Beluga oxy-dravite has trigonal symmetry, space group R3m with a = 15.9121(2) Å, c = 7.1788(10) Å, V = 1574.12(5) Å3 and Z = 3. The crystal structure was refined to R1 = 1.45 using 1613 unique reflections. The empirical crystal-chemical formula is X(Na0.88Ca0.08□0.03K0.01)Y(Al1.49Mg1.31Fe0.15Ti0.04Zn0.01)Z(Al5.42Mg0.58)T(Si5.84Al0.16O18)B(BO3)3 V(OH2.95O0.05)W(O0.84OH0.01F0.15). Oxy-dravite in nature commonly occurs in a solid solution with foitite, schorl and oxy-schorl. At the Beluga occurrence, its minor contents of Al, vacancy [□], and Ca are most likely compensated by (□Al)(NaR2+)–1 and (CaMg)(NaAl)–1 exchanges of the oxy-magnesio-foitite and magnesio-lucchesiite components. The Beluga occurrence of oxy-dravite is characterised by an Mg-rich environment related to a metamorphic overprint of the original sedimentary sequence. This sequence of marine dolomitic argillaceous marl was influenced by (B,Cl)-rich fluids, probably proximally-derived from mineral breakdown reactions in the calc-silicate during the retrograde stage of metamorphism. The locality is a rare example of a tourmaline + corundum assemblage. ER -
SKŘÁPKOVÁ, Lenka, Jan CEMPÍREK, Philippe M. BELLEY, Lee A. GROAT a Radek ŠKODA. Physical properties and crystal structure of near end-member oxy-dravite from the Beluga occurrence, Nunavut territory, Canada. \textit{Mineralogical Magazine}. London: Mineralogical Society, 2023, roč.~87, č.~5, s.~719-730. ISSN~0026-461X. Dostupné z: https://dx.doi.org/10.1180/mgm.2023.59.
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