| HLOŽKOVÁ, Michaela, Michaela VAŠINOVÁ GALIOVÁ, Pavel COUFALÍK, Karel BREITER, Radek ŠKODA, Matěj BŽEZINA, Martin BRTNICKÝ a Jindřich KYNICKÝ. Determination of tin in geological materials using LA-ICP-MS: Seemingly simple analysis? Chemical Geology. Elsevier, 2023, roč. 641, December, s. 1-15. ISSN 0009-2541. Dostupné z: https://dx.doi.org/10.1016/j.chemgeo.2023.121775. |
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@article{2347777,
author = {Hložková, Michaela and Vašinová Galiová, Michaela and Coufalík, Pavel and Breiter, Karel and Škoda, Radek and Bžezina, Matěj and Brtnický, Martin and Kynický, Jindřich},
article_number = {December},
doi = {http://dx.doi.org/10.1016/j.chemgeo.2023.121775},
keywords = {tin; memory effect; spectral and non-spectral interferences; homogeneity of standards; LA-ICP-MS},
language = {eng},
issn = {0009-2541},
journal = {Chemical Geology},
title = {Determination of tin in geological materials using LA-ICP-MS: Seemingly simple analysis?},
url = {https://doi.org/10.1016/j.chemgeo.2023.121775},
volume = {641},
year = {2023}
}
TY - JOUR
ID - 2347777
AU - Hložková, Michaela - Vašinová Galiová, Michaela - Coufalík, Pavel - Breiter, Karel - Škoda, Radek - Bžezina, Matěj - Brtnický, Martin - Kynický, Jindřich
PY - 2023
TI - Determination of tin in geological materials using LA-ICP-MS: Seemingly simple analysis?
JF - Chemical Geology
VL - 641
IS - December
SP - 1-15
EP - 1-15
PB - Elsevier
SN - 00092541
KW - tin
KW - memory effect
KW - spectral and non-spectral interferences
KW - homogeneity of standards
KW - LA-ICP-MS
UR - https://doi.org/10.1016/j.chemgeo.2023.121775
N2 - Laser ablation inductively coupled plasma mass spectrometry is a unique technique designated for in situ analysis of a wide variety of solid samples. Nowadays, LA-ICP-MS is almost routinely used to study chemical and isotopic composition of geological materials. This paper reviews our experience with the analysis of tin in geological samples and comprehensively summarizes the limitations that may lead to inaccurate and imprecise outcomes. Experimental results show the extent of cross-contamination given by the ablation of materials containing tenths and tens of %m/m of Sn, and elucidate the impact of contamination on a background progress. Moreover, an analysis is also jeopardized by the occurrence of doubly charged ions of uranium as well as by the matrix effect amplified with operating conditions. Finally, the inhomogeneity of NIST SRM 614 is highlighted via 2D mapping especially within the rim area where tin content reaches up to 8 mg kg−1. Furthermore, a real quartz sample is subjected to LA-ICP-MS analysis to demonstrate the manifestation of discussed negative effects. The true tin content in quartz sample and NIST 614 is verified via GF-AAS. The result of NIST 614 bulk analysis is in a good agreement with GeoReM value.
ER -
HLOŽKOVÁ, Michaela, Michaela VAŠINOVÁ GALIOVÁ, Pavel COUFALÍK, Karel BREITER, Radek ŠKODA, Matěj BŽEZINA, Martin BRTNICKÝ a Jindřich KYNICKÝ. Determination of tin in geological materials using LA-ICP-MS: Seemingly simple analysis? \textit{Chemical Geology}. Elsevier, 2023, roč.~641, December, s.~1-15. ISSN~0009-2541. Dostupné z: https://dx.doi.org/10.1016/j.chemgeo.2023.121775.
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