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@article{2361599,
author = {Novák, Milan and Toman, Jiří and Škoda, Radek and Šikola, Drahos and Mazuch, Jiří},
article_number = {2},
doi = {http://dx.doi.org/10.3190/jgeosci.370},
keywords = {zeolites; mineral assemblages; chemical composition; Straiek Unit; Moldanubian Zone},
language = {eng},
issn = {1802-6222},
journal = {Journal of Geosciences},
title = {Review of zeolite mineralizations from the high-grade metamorphosed Strážek Unit, Moldanubian Zone, Czech Republic},
url = {http://www.jgeosci.org/detail/jgeosci.370},
volume = {68},
year = {2023}
}
TY - JOUR
ID - 2361599
AU - Novák, Milan - Toman, Jiří - Škoda, Radek - Šikola, Drahos - Mazuch, Jiří
PY - 2023
TI - Review of zeolite mineralizations from the high-grade metamorphosed Strážek Unit, Moldanubian Zone, Czech Republic
JF - Journal of Geosciences
VL - 68
IS - 2
SP - 111-138
EP - 111-138
PB - Česká geologická společnost
SN - 18026222
KW - zeolites
KW - mineral assemblages
KW - chemical composition
KW - Straiek Unit
KW - Moldanubian Zone
UR - http://www.jgeosci.org/detail/jgeosci.370
N2 - Geological position, mineral assemblages, and compositional evolution of several types of mostly hydrothermal zeolite mineralizations were examined in the easternmost part of the Moldanubian Zone (Strážek Unit), Czech Republic, using EPMA and Raman spectroscopy. The zeolite mineralizations are related to the following geological processes: (A1) late magmatic to (A2, A3) hydrothermal crystallization (pseudomorphs, brittle tectonic fractures) in granitic pegmatites; (B) retrograde stages of the Variscan metamorphism - (B1) Alpine-type hydrothermal veins on ductile to brittle fractures with epidote, prehnite and zeolites, (B2) laumontite and (B3) natrolite veinlets; the latter two on thin brittle fissures; (C) hydrothermal zeolite veins with dominant stilbite-(Ca) + heulandite-(Ca) and sulfides on ductile to brittle fractures, and (D) thin brittle fissure-filling veinlets lined with harmotome ± calcite. The zeolite mineralizations include pollucite (A), analcime (A, B), phillipsite-(Ca) (A), harmotome (A, D), chabazite-(Ca) and chabazite-(K) (A, B), thomsonite-(Ca) (A), natrolite (A, B), laumontite (A, B, C), stilbite-(Ca) (B, C), scolecite (B), and heulandite-(Ca) (B, C). The individual zeolite mineralizations differ significantly in their regional distribution: (B) Alpine-type hydrothermal veins and laumontite and natrolite veinlets are widespread within almost the whole region, whereas zeolites in (A) granitic pegmatites and in (C, D) hydrothermal veins are concentrated along the eastern border of the Strážek Unit, the latter two assemblages restricted to the Rožná-Olší ore field. Fluids with variable composition and origin facilitated the formation of individual zeolite mineralizations. They evolved from moderate-T (~400 °C) to low-T (~50 °C) conditions characterized by the following extra-framework cations ± volatiles with dominant H2O: (A1) - Cs, Ba, Ca, Na ˃ K, (A2) - Ca, K, Ba ˃ Na, (A3) - Ca, Na, Ba (A: T ~400-50 °C); (B1) - Ca ± B, (B2) - Ca, (B3) - Na, Ca (B: T ~350-50 °C); (C) - Ca ˃ Na ± S, F (C: T ~240-50 °C); (D) - Ba, Ca ± CO2 (D: T ~100-50 °C). Sources of fluids include - residual fluids exsolved from pegmatite melt (A1) and external fluids derived from host rock (A2, A3); fluids related to retrograde stages of the Variscan metamorphism (A3?, B1, B2, B3, C?); likely post-Variscan fluids of various origin (C, D). The zeolite assemblages demonstrate that the PTX conditions suitable for their origin were attained in the late stages of distinctive geological processes. Zeolites may be used as a valuable indicator of alkaline to neutral and low-T to very low-T hydrothermal fluids with high activity of Ca, K, Na and/or Ba, and variable aSiO2 on tectonic fractures and fissures.
ER -
NOVÁK, Milan, Jiří TOMAN, Radek ŠKODA, Drahos ŠIKOLA a Jiří MAZUCH. Review of zeolite mineralizations from the high-grade metamorphosed Strážek Unit, Moldanubian Zone, Czech Republic. \textit{Journal of Geosciences}. Česká geologická společnost, 2023, roč.~68, č.~2, s.~111-138. ISSN~1802-6222. Dostupné z: https://dx.doi.org/10.3190/jgeosci.370.
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