Gradual modification of the YSZ structures by Au ion
implantation and high-energy Si ion irradiation

J 2023

Gradual modification of the YSZ structures by Au ion implantation and high-energy Si ion irradiation

MIKŠOVÁ, R., A. JAGEROVÁ, J. CAJZL, Václav HOLÝ, M. VRONKA et. al.

Základní údaje

Originální název

Gradual modification of the YSZ structures by Au ion implantation and high-energy Si ion irradiation

Autoři

MIKŠOVÁ, R., A. JAGEROVÁ, J. CAJZL, Václav HOLÝ (203 Česká republika, domácí), M. VRONKA a A. MACKOVÁ

Vydání

Ceramics International, Elsevier, 2023, 0272-8842

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10302 Condensed matter physics

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 5.200 v roce 2022

Kód RIV

RIV/00216224:14310/23:00133322

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.ceramint.2023.06.196

UT WoS

001072407200001

Klíčová slova anglicky

GOLD NANOPARTICLES; OPTICAL-PROPERTIES; METAL NANOPARTICLES; DAMAGE; NANOSTRUCTURES; NANOCRYSTALS; SCATTERING; ZIRCONIA; DEFECTS; FIELD

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 8. 4. 2024 14:37, Mgr. Marie Šípková, DiS.

Anotace

V originále

Gold nanoparticles (Au-NPs) were created in crystalline yttria-stabilized zirconia (YSZ). (100)-, (110)- and (111)oriented YSZ samples were implanted by 1 MeV Au+ ions at room temperature and fluences ranging from 1.5 x 1016 cm-2 to 7.5 x 1016 cm-2. The prepared Au: YSZ structures were annealed at 1100 degrees C for 1 h on air to support the Au-NPs coalescence and YSZ structure recovery. Subsequent irradiation with the 10 MeV Si3+ ions with a fluence of 5.0 x 1014 cm-2 was performed to enable gradual modification of Au-NPs. Au-depth profiles and YSZ structure modification in the produced samples were analysed via Rutherford backscattering spectrometry in channelling mode (RBS-C) and X-ray diffraction (XRD). RBS-C showed the gold distributed in the region of about 50-300 nm below the YSZ surface. The disorder was accumulated in the region with Au-NPs and the concentration of the disorder increases as a function of ion implantation fluence. The Zr-disorder was partially decreased after the annealing, while the subsequent Si-ion irradiation increased Zr-disorder again, however, the disorder does not reach values before the annealing. XRD measurement evidenced elastic deformation of the YSZ host lattice in the Au-implanted samples. Optical absorbance showed the appearance of the new absorption band at 550 nm for the Au-ion fluences above 5.0 x 1016 cm-2 ascribed to the Au-NPs formation. After the annealing, the absorption band is shifted to the wavelength of 580 nm which could be connected to the proceeding clustering of Au. The maximum absorption peak intensity increases which is connected to the increasing amount of the Au-NPs. Transmission electron microscopy (TEM) with Energy dispersive spectroscopy (EDS) confirmed the presence of Au-NPs in the implanted layer after the annealing. The subsequent Si-ion irradiation did not change the Au-NP shape which remained spherical with a slight size increase.

Návaznosti

90110, velká výzkumná infrastruktura

Název: CzechNanoLab

Citovat

MIKŠOVÁ, R., A. JAGEROVÁ, J. CAJZL, Václav HOLÝ, M. VRONKA a A. MACKOVÁ. Gradual modification of the YSZ structures by Au ion implantation and high-energy Si ion irradiation. Ceramics International. Elsevier, 2023, roč. 49, č. 18, s. 29659-29670. ISSN 0272-8842. Dostupné z: https://dx.doi.org/10.1016/j.ceramint.2023.06.196.

@article{2367624,
   author = {Mikšová, R. and Jagerová, A. and Cajzl, J. and Holý, Václav and Vronka, M. and Macková, A.},
   article_number = {18},
   doi = {http://dx.doi.org/10.1016/j.ceramint.2023.06.196},
   keywords = {GOLD NANOPARTICLES; OPTICAL-PROPERTIES; METAL NANOPARTICLES; DAMAGE; NANOSTRUCTURES; NANOCRYSTALS; SCATTERING; ZIRCONIA; DEFECTS; FIELD},
   language = {eng},
   issn = {0272-8842},
   journal = {Ceramics International},
   title = {Gradual modification of the YSZ structures by Au ion implantation and high-energy Si ion irradiation},
   url = {https://www.sciencedirect.com/science/article/pii/S0272884223017820},
   volume = {49},
   year = {2023}
}

TY  - JOUR
ID  - 2367624
AU  - Mikšová, R. - Jagerová, A. - Cajzl, J. - Holý, Václav - Vronka, M. - Macková, A.
PY  - 2023
TI  - Gradual modification of the YSZ structures by Au ion implantation and high-energy Si ion irradiation
JF  - Ceramics International
VL  - 49
IS  - 18
SP  - 29659-29670
EP  - 29659-29670
PB  - Elsevier
SN  - 02728842
KW  - GOLD NANOPARTICLES
KW  - OPTICAL-PROPERTIES
KW  - METAL NANOPARTICLES
KW  - DAMAGE
KW  - NANOSTRUCTURES
KW  - NANOCRYSTALS
KW  - SCATTERING
KW  - ZIRCONIA
KW  - DEFECTS
KW  - FIELD
UR  - https://www.sciencedirect.com/science/article/pii/S0272884223017820
N2  - Gold nanoparticles (Au-NPs) were created in crystalline yttria-stabilized zirconia (YSZ). (100)-, (110)- and (111)oriented YSZ samples were implanted by 1 MeV Au+ ions at room temperature and fluences ranging from 1.5 x 1016 cm-2 to 7.5 x 1016 cm-2. The prepared Au: YSZ structures were annealed at 1100 degrees C for 1 h on air to support the Au-NPs coalescence and YSZ structure recovery. Subsequent irradiation with the 10 MeV Si3+ ions with a fluence of 5.0 x 1014 cm-2 was performed to enable gradual modification of Au-NPs. Au-depth profiles and YSZ structure modification in the produced samples were analysed via Rutherford backscattering spectrometry in channelling mode (RBS-C) and X-ray diffraction (XRD). RBS-C showed the gold distributed in the region of about 50-300 nm below the YSZ surface. The disorder was accumulated in the region with Au-NPs and the concentration of the disorder increases as a function of ion implantation fluence. The Zr-disorder was partially decreased after the annealing, while the subsequent Si-ion irradiation increased Zr-disorder again, however, the disorder does not reach values before the annealing. XRD measurement evidenced elastic deformation of the YSZ host lattice in the Au-implanted samples. Optical absorbance showed the appearance of the new absorption band at 550 nm for the Au-ion fluences above 5.0 x 1016 cm-2 ascribed to the Au-NPs formation. After the annealing, the absorption band is shifted to the wavelength of 580 nm which could be connected to the proceeding clustering of Au. The maximum absorption peak intensity increases which is connected to the increasing amount of the Au-NPs. Transmission electron microscopy (TEM) with Energy dispersive spectroscopy (EDS) confirmed the presence of Au-NPs in the implanted layer after the annealing. The subsequent Si-ion irradiation did not change the Au-NP shape which remained spherical with a slight size increase.
ER  -

MIKŠOVÁ, R., A. JAGEROVÁ, J. CAJZL, Václav HOLÝ, M. VRONKA a A. MACKOVÁ. Gradual modification of the YSZ structures by Au ion implantation and high-energy Si ion irradiation. \textit{Ceramics International}. Elsevier, 2023, roč.~49, č.~18, s.~29659-29670. ISSN~0272-8842. Dostupné z: https://dx.doi.org/10.1016/j.ceramint.2023.06.196.

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