Polymerization mechanisms of hexamethyldisiloxane in
low-pressure plasmas involving complex geometries

J 2024

Polymerization mechanisms of hexamethyldisiloxane in low-pressure plasmas involving complex geometries

NAVASCUES, Paula, Martina BUCHTELOVA, Lenka ZAJÍČKOVÁ, Patrick RUPPER, Dirk HEGEMANN et. al.

Základní údaje

Originální název

Polymerization mechanisms of hexamethyldisiloxane in low-pressure plasmas involving complex geometries

Autoři

NAVASCUES, Paula, Martina BUCHTELOVA, Lenka ZAJÍČKOVÁ (203 Česká republika, domácí), Patrick RUPPER a Dirk HEGEMANN

Vydání

Applied Surface Science, Elsevier, 2024, 0169-4332

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10300 1.3 Physical sciences

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 6.700 v roce 2022

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.apsusc.2023.158824

UT WoS

001111754700001

Klíčová slova anglicky

Plasma polymerization; HMDSO; ATR-FTIR; Surface oxidation

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 31. 1. 2024 11:36, Mgr. Marie Šípková, DiS.

Anotace

V originále

Hexamethyldisiloxane (HMDSO) low-pressure plasmas are known for their versatility in the deposition of plasma polymer films (PPFs) with different properties and applications. Although they have been studied for decades, the reaction mechanisms of plasma polymer formation leave open questions, particularly when deposition on 3D materials with complex geometries such as cavities and undercuts is considered. In the present study, two configurations named "cavity" and "undercut" have been selected to study the influence of diffusion of film forming species and surface reactivity in HMDSO plasmas without and with O2 admixture. A varying spatial chemical composition of the plasma polymer deposit along the penetration depth of the studied configurations indicates different sticking probabilities of the film-forming species. Furthermore, although ion-induced effects are usually only considered for direct plasma exposure, the obtained results and additional etching experiments reveal that the contribution of high-energy particles might still be considered underneath small openings. Finally, the relevance of oxidizing chemical reactions at the surface inside the configurations is clarified when O2 is added to the plasma.

Citovat

NAVASCUES, Paula, Martina BUCHTELOVA, Lenka ZAJÍČKOVÁ, Patrick RUPPER a Dirk HEGEMANN. Polymerization mechanisms of hexamethyldisiloxane in low-pressure plasmas involving complex geometries. Applied Surface Science. Elsevier, 2024, roč. 645, February, s. 1-9. ISSN 0169-4332. Dostupné z: https://dx.doi.org/10.1016/j.apsusc.2023.158824.

@article{2368078,
   author = {Navascues, Paula and Buchtelova, Martina and Zajíčková, Lenka and Rupper, Patrick and Hegemann, Dirk},
   article_number = {February},
   doi = {http://dx.doi.org/10.1016/j.apsusc.2023.158824},
   keywords = {Plasma polymerization; HMDSO; ATR-FTIR; Surface oxidation},
   language = {eng},
   issn = {0169-4332},
   journal = {Applied Surface Science},
   title = {Polymerization mechanisms of hexamethyldisiloxane in low-pressure plasmas involving complex geometries},
   url = {https://www.sciencedirect.com/science/article/pii/S0169433223025047},
   volume = {645},
   year = {2024}
}

TY  - JOUR
ID  - 2368078
AU  - Navascues, Paula - Buchtelova, Martina - Zajíčková, Lenka - Rupper, Patrick - Hegemann, Dirk
PY  - 2024
TI  - Polymerization mechanisms of hexamethyldisiloxane in low-pressure plasmas involving complex geometries
JF  - Applied Surface Science
VL  - 645
IS  - February
SP  - 1-9
EP  - 1-9
PB  - Elsevier
SN  - 01694332
KW  - Plasma polymerization
KW  - HMDSO
KW  - ATR-FTIR
KW  - Surface oxidation
UR  - https://www.sciencedirect.com/science/article/pii/S0169433223025047
N2  - Hexamethyldisiloxane (HMDSO) low-pressure plasmas are known for their versatility in the deposition of plasma polymer films (PPFs) with different properties and applications. Although they have been studied for decades, the reaction mechanisms of plasma polymer formation leave open questions, particularly when deposition on 3D materials with complex geometries such as cavities and undercuts is considered. In the present study, two configurations named "cavity" and "undercut" have been selected to study the influence of diffusion of film forming species and surface reactivity in HMDSO plasmas without and with O2 admixture. A varying spatial chemical composition of the plasma polymer deposit along the penetration depth of the studied configurations indicates different sticking probabilities of the film-forming species. Furthermore, although ion-induced effects are usually only considered for direct plasma exposure, the obtained results and additional etching experiments reveal that the contribution of high-energy particles might still be considered underneath small openings. Finally, the relevance of oxidizing chemical reactions at the surface inside the configurations is clarified when O2 is added to the plasma.
ER  -

NAVASCUES, Paula, Martina BUCHTELOVA, Lenka ZAJÍČKOVÁ, Patrick RUPPER a Dirk HEGEMANN. Polymerization mechanisms of hexamethyldisiloxane in low-pressure plasmas involving complex geometries. \textit{Applied Surface Science}. Elsevier, 2024, roč.~645, February, s.~1-9. ISSN~0169-4332. Dostupné z: https://dx.doi.org/10.1016/j.apsusc.2023.158824.

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