Comparison of Cu+, Ag+, and Au+ Ions as Ionization Agents of
Volatile Organic Compounds at Subatmospheric Pressure

J 2024

Comparison of Cu+, Ag+, and Au+ Ions as Ionization Agents of Volatile Organic Compounds at Subatmospheric Pressure

KOKTAVÁ, Monika, Vadym PRYSIAZHNYI, Jan PREISLER a Antonín BEDNAŘÍK

Základní údaje

Originální název

Comparison of Cu+, Ag+, and Au+ Ions as Ionization Agents of Volatile Organic Compounds at Subatmospheric Pressure

Autoři

KOKTAVÁ, Monika (203 Česká republika, domácí), Vadym PRYSIAZHNYI (804 Ukrajina, domácí), Jan PREISLER (203 Česká republika, garant, domácí) a Antonín BEDNAŘÍK (203 Česká republika, domácí)

Vydání

Journal of the American Society for Mass Spectrometry, New York, Springer, 2024, 1044-0305

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 3.200 v roce 2022

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1021/jasms.3c00370

UT WoS

001158849900001

Klíčová slova anglicky

mass spectrometry; volatile organic compounds; laser ionization; gas phase reactions

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 5. 11. 2024 15:46, Mgr. Pavla Foltynová, Ph.D.

Anotace

V originále

Ionization of volatile organic compounds (VOCs) by coinage metal ions (Cu+, Ag+, and Au+) generated by laser desorption and ionization (LDI) of a metal nanolayer in subatmospheric conditions is explored. The study was performed in a commercial subatmospheric dual MALDI/ESI ion source. Five compounds representing different VOC classes were chosen for a detailed study of the metal ionization mechanism: ethanol, acetone, acetic acid, xylene, and cyclohexane. In the gas phase, ion molecular complexes of all three metal ions were formed, typically with two ligand molecules. The successful detection of the metal complexes with VOCs strongly depended on the applied voltages across the ion source, minimizing the in-source fragmentation. The employed orbital trap with ultrahigh resolving power and sub-parts-per-million mass accuracy allowed unambiguous identification of the formed complexes based on their molecular formulas. The detection limits of the studied compounds in the gas were in the range 0.1-1.4 nmol/L. Compared to Cu+ and Ag+ ions, Au+ ions exhibited the highest reactivity, often complicating spectra by side products of reactions. On the other hand, they also allowed detecting saturated hydrocarbons, which did not produce any signals with Ag+ and Cu+.

Návaznosti

GA21-12262S, projekt VaV

Název: Nanočásticové sondy pro zobrazovací hmotnostní spektrometrii

Investor: Grantová agentura ČR, Nanočásticové sondy pro zobrazovací hmotnostní spektrometrii

MUNI/A/1594/2023, interní kód MU

Název: Vývoj metod a instrumentace pro analýzu biologicky významných látek 2024

Investor: Masarykova univerzita, Vývoj metod a instrumentace pro analýzu biologicky významných látek 2024

Citovat

KOKTAVÁ, Monika, Vadym PRYSIAZHNYI, Jan PREISLER a Antonín BEDNAŘÍK. Comparison of Cu+, Ag+, and Au+ Ions as Ionization Agents of Volatile Organic Compounds at Subatmospheric Pressure. Journal of the American Society for Mass Spectrometry. New York: Springer, 2024, roč. 35, č. 2, s. 307-316. ISSN 1044-0305. Dostupné z: https://dx.doi.org/10.1021/jasms.3c00370.

@article{2379498,
   author = {Koktavá, Monika and Prysiazhnyi, Vadym and Preisler, Jan and Bednařík, Antonín},
   article_location = {New York},
   article_number = {2},
   doi = {http://dx.doi.org/10.1021/jasms.3c00370},
   keywords = {mass spectrometry; volatile organic compounds; laser ionization; gas phase reactions},
   language = {eng},
   issn = {1044-0305},
   journal = {Journal of the American Society for Mass Spectrometry},
   title = {Comparison of Cu+, Ag+, and Au+ Ions as Ionization Agents of Volatile Organic Compounds at Subatmospheric Pressure},
   url = {https://doi.org/10.1021/jasms.3c00370},
   volume = {35},
   year = {2024}
}

TY  - JOUR
ID  - 2379498
AU  - Koktavá, Monika - Prysiazhnyi, Vadym - Preisler, Jan - Bednařík, Antonín
PY  - 2024
TI  - Comparison of Cu+, Ag+, and Au+ Ions as Ionization Agents of Volatile Organic Compounds at Subatmospheric Pressure
JF  - Journal of the American Society for Mass Spectrometry
VL  - 35
IS  - 2
SP  - 307-316
EP  - 307-316
PB  - Springer
SN  - 10440305
KW  - mass spectrometry
KW  - volatile organic compounds
KW  - laser ionization
KW  - gas phase reactions
UR  - https://doi.org/10.1021/jasms.3c00370
N2  - Ionization of volatile organic compounds (VOCs) by coinage metal ions (Cu+, Ag+, and Au+) generated by laser desorption and ionization (LDI) of a metal nanolayer in subatmospheric conditions is explored. The study was performed in a commercial subatmospheric dual MALDI/ESI ion source. Five compounds representing different VOC classes were chosen for a detailed study of the metal ionization mechanism: ethanol, acetone, acetic acid, xylene, and cyclohexane. In the gas phase, ion molecular complexes of all three metal ions were formed, typically with two ligand molecules. The successful detection of the metal complexes with VOCs strongly depended on the applied voltages across the ion source, minimizing the in-source fragmentation. The employed orbital trap with ultrahigh resolving power and sub-parts-per-million mass accuracy allowed unambiguous identification of the formed complexes based on their molecular formulas. The detection limits of the studied compounds in the gas were in the range 0.1-1.4 nmol/L. Compared to Cu+ and Ag+ ions, Au+ ions exhibited the highest reactivity, often complicating spectra by side products of reactions. On the other hand, they also allowed detecting saturated hydrocarbons, which did not produce any signals with Ag+ and Cu+.
ER  -

KOKTAVÁ, Monika, Vadym PRYSIAZHNYI, Jan PREISLER a Antonín BEDNAŘÍK. Comparison of Cu+, Ag+, and Au+ Ions as Ionization Agents of Volatile Organic Compounds at Subatmospheric Pressure. \textit{Journal of the American Society for Mass Spectrometry}. New York: Springer, 2024, roč.~35, č.~2, s.~307-316. ISSN~1044-0305. Dostupné z: https://dx.doi.org/10.1021/jasms.3c00370.

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