MIKŠÍK, Dávid, Jana PAVLŮ a Ondřej ZOBAČ. An investigation of phase behavior in the Co-Se-Sn ternary system using experiments and thermodynamic modeling. In 3rd Journal of Thermal Analysis and Calorimetry Conference and 9th V4 (Joint Czech-Hungarian-Polish-Slovakian) Thermoanalytical Conference. 2023.
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Základní údaje
Originální název An investigation of phase behavior in the Co-Se-Sn ternary system using experiments and thermodynamic modeling
Autoři MIKŠÍK, Dávid (703 Slovensko, domácí), Jana PAVLŮ (203 Česká republika, domácí) a Ondřej ZOBAČ (203 Česká republika, garant).
Vydání 3rd Journal of Thermal Analysis and Calorimetry Conference and 9th V4 (Joint Czech-Hungarian-Polish-Slovakian) Thermoanalytical Conference, 2023.
Další údaje
Originální jazyk angličtina
Typ výsledku Konferenční abstrakt
Obor 10403 Physical chemistry
Stát vydavatele Maďarsko
Utajení není předmětem státního či obchodního tajemství
Kód RIV RIV/00216224:14310/23:00133888
Organizační jednotka Přírodovědecká fakulta
Klíčová slova anglicky Co-Se-Sn system; phase equilibria; CALPHAD; thermodynamic modelling; scanning electron microscopy; X-ray diffraction; thermal analysis
Změnil Změnila: doc. Mgr. Jana Pavlů, Ph.D., učo 10394. Změněno: 24. 3. 2024 23:22.
Anotace
The ternary Co-Se-Sn system has been investigated experimentally to determine the phase equilibria and the microstructure of the alloys formed at different temperatures (400, 700, 1000 °C). Samples of various compositions were prepared by melting, annealing, and quenching techniques and characterized using scanning electron microscopy, X-ray diffraction and thermal analysis. The combined experimental results confirmed the presence of several binary phases in this system, including Co3Sn2, CoSn2, CoSe, Co9Se8, CoSe2, SeSn and one ternary phase Co2(SnSe)3. Furthermore, a new thermodynamic description of this system was introduced using the CALPHAD (CALculation of PHAse Diagrams) approach to predict and describe the phase equilibria, including the development of new models for phases CoSe Co9Se8 and CoSe2. The models and thermodynamic description were verified by comparing the predicted phase diagrams with the experimental data obtained in this study. The experimental and modelling results obtained in this study provide new insights into the behaviour of the Co-Se-Sn system and can be applied in the design and optimization of Co-based alloys for various industrial applications, such as magnetic storage media, hightemperature materials, and thermoelectric devices.
VytisknoutZobrazeno: 18. 7. 2024 01:32