Laser-induced breakdown spectroscopy in analysis of algae

k 2024

Laser-induced breakdown spectroscopy in analysis of algae

HRDLIČKA, Aleš, Jana HORSKÁ, Jitka HEGROVÁ, Martina BUCKOVÁ, David PROCHAZKA et. al.

Základní údaje

Originální název

Laser-induced breakdown spectroscopy in analysis of algae

Autoři

HRDLIČKA, Aleš (203 Česká republika, domácí), Jana HORSKÁ (203 Česká republika), Jitka HEGROVÁ (203 Česká republika), Martina BUCKOVÁ (203 Česká republika), David PROCHAZKA (203 Česká republika), Jakub BUDAY (703 Slovensko), Viktor KANICKÝ (203 Česká republika), Pavel POŘÍZKA (203 Česká republika) a Jozef KAISER (703 Slovensko)

Vydání

Czech - Slovak Spectroscopic Conference & Mössbauer Spectroscopy in Material Science, 2024

Další údaje

Jazyk

angličtina

Typ výsledku

Prezentace na konferencích

Obor

10406 Analytical chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Odkazy

odkaz na konferenční stránky

Organizační jednotka

Přírodovědecká fakulta

ISBN

978-80-88195-54-2

Klíčová slova česky

spektroskopie laserem buzeného plazmatu (LIBS); analýza; řasy; kontaminace; stínové zobrazení

Klíčová slova anglicky

laser-induced breakdown spectroscopy; analysis; algae; contamination; shadowgraphy

Příznaky

Mezinárodní význam

Změněno: 4. 7. 2024 15:12, Mgr. Aleš Hrdlička, Ph.D.

Anotace

V originále

Green algae Desmodesmus subspicatus are single cell freshwater organisms capable of heavy metals accumulation from water. They are analyzed with Inductively Coupled Plasma Mass Spectrometry (ICP-MS) but the parent solution with algae is filtered, the filter with an algae sediment is decomposed and the resulting solution is analyzed with ICP-MS. However, such procedure is laborious and time-consuming. An alternative technique is Laser-Induced Breakdown Spectroscopy (LIBS) with a Czerny-Turner spectrometer in a double pulse (DP) 1064-1064nm configuration [1]. It is sufficiently sensitive to the heavy metals concentrations of about tens of ng cm-2 on the filter surface. A semiquantitative analysis is then possible. Besides, some interesting facts about LIBS of the cellulose filter were revealed. Contaminated algae show monotonous decrease of lines intensities with number of used layers of adhesive tapes for fixing the filter to a microscope glass while blank and non-contaminated samples do not. Also the total emissivity, electron number density and the matrix elements lines are less intensive on the blank than on the contaminated sample. Analogical behaviour shows also plasma shockwave from shadowgraphy experiments. Behaviour of the analyte and the matrix lines is more similar if their signal-to-noise ratio is high or they have similar excitation energies which can be important for possible internal standardization.

Návaznosti

MUNI/A/1575/2023, interní kód MU

Název: Metody chemické a fyzikálně-chemické analýzy pro studium přírodních a syntetických materiálů.

Investor: Masarykova univerzita, Metody chemické a fyzikálně-chemické analýzy pro studium přírodních a syntetických materiálů.

Citovat

HRDLIČKA, Aleš, Jana HORSKÁ, Jitka HEGROVÁ, Martina BUCKOVÁ, David PROCHAZKA, Jakub BUDAY, Viktor KANICKÝ, Pavel POŘÍZKA a Jozef KAISER. Laser-induced breakdown spectroscopy in analysis of algae. In Czech - Slovak Spectroscopic Conference & Mössbauer Spectroscopy in Material Science. 2024. ISBN 978-80-88195-54-2.

@proceedings{2411037,
   author = {Hrdlička, Aleš and Horská, Jana and Hegrová, Jitka and Bucková, Martina and Prochazka, David and Buday, Jakub and Kanický, Viktor and Pořízka, Pavel and Kaiser, Jozef},
   booktitle = {Czech - Slovak Spectroscopic Conference & Mössbauer Spectroscopy in Material Science},
   keywords = {laser-induced breakdown spectroscopy; analysis; algae; contamination; shadowgraphy},
   language = {eng},
   isbn = {978-80-88195-54-2},
   title = {Laser-induced breakdown spectroscopy in analysis of algae},
   url = {https://cssc2024.spektroskopie.cz/},
   year = {2024}
}

TY  - CONF
ID  - 2411037
AU  - Hrdlička, Aleš - Horská, Jana - Hegrová, Jitka - Bucková, Martina - Prochazka, David - Buday, Jakub - Kanický, Viktor - Pořízka, Pavel - Kaiser, Jozef
PY  - 2024
TI  - Laser-induced breakdown spectroscopy in analysis of algae
SN  - 9788088195542
KW  - laser-induced breakdown spectroscopy
KW  - analysis
KW  - algae
KW  - contamination
KW  - shadowgraphy
UR  - https://cssc2024.spektroskopie.cz/
N2  - Green algae Desmodesmus subspicatus are single cell freshwater organisms capable of heavy metals accumulation from water. They are analyzed with Inductively Coupled Plasma Mass Spectrometry (ICP-MS) but the parent solution with algae is filtered, the filter with an algae sediment is decomposed and the resulting solution is analyzed with ICP-MS. However, such procedure is laborious and time-consuming. An alternative technique is Laser-Induced Breakdown Spectroscopy (LIBS) with a Czerny-Turner spectrometer in a double pulse (DP) 1064-1064nm configuration [1]. It is sufficiently sensitive to the heavy metals concentrations of about tens of ng cm-2 on the filter surface. A semiquantitative analysis is then possible. Besides, some interesting facts about LIBS of the cellulose filter were revealed. Contaminated algae show monotonous decrease of lines intensities with number of used layers of adhesive tapes for fixing the filter to a microscope glass while blank and non-contaminated samples do not. Also the total emissivity, electron number density and the matrix elements lines are less intensive on the blank than on the contaminated sample. Analogical behaviour shows also plasma shockwave from shadowgraphy experiments. Behaviour of the analyte and the matrix lines is more similar if their signal-to-noise ratio is high or they have similar excitation energies which can be important for possible internal standardization.
ER  -

HRDLIČKA, Aleš, Jana HORSKÁ, Jitka HEGROVÁ, Martina BUCKOVÁ, David PROCHAZKA, Jakub BUDAY, Viktor KANICKÝ, Pavel POŘÍZKA a Jozef KAISER. Laser-induced breakdown spectroscopy in analysis of algae. In \textit{Czech - Slovak Spectroscopic Conference \&{} Mössbauer Spectroscopy in Material Science}. 2024. ISBN~978-80-88195-54-2.

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