2024
Multi-element analysis (Pb, Al, Fe) of Antarctic flora using HR-CS ETAAS with an extended working range
ZVĚŘINA, Ondřej, Lenka BRŮHOVÁ, Pavel COUFALIK, Christopher D. STRINGER, Jaqueline RIEGER et. al.Základní údaje
Originální název
Multi-element analysis (Pb, Al, Fe) of Antarctic flora using HR-CS ETAAS with an extended working range
Autoři
ZVĚŘINA, Ondřej (203 Česká republika, domácí), Lenka BRŮHOVÁ (203 Česká republika, domácí), Pavel COUFALIK (203 Česká republika), Christopher D. STRINGER (826 Velká Británie a Severní Irsko), Jaqueline RIEGER (40 Rakousko) a Walter GOESSLER (40 Rakousko)
Vydání
Spectrochimica Acta - Part B Atomic Spectroscopy, Oxford, PERGAMON-ELSEVIER SCIENCE LTD, 2024, 0584-8547
Další údaje
Jazyk
angličtina
Typ výsledku
Článek v odborném periodiku
Obor
10301 Atomic, molecular and chemical physics
Stát vydavatele
Velká Británie a Severní Irsko
Utajení
není předmětem státního či obchodního tajemství
Odkazy
Impakt faktor
Impact factor: 3.300 v roce 2022
Organizační jednotka
Lékařská fakulta
UT WoS
001261848200001
Klíčová slova anglicky
Simultaneous multi-element analysis; HR-CS ETAAS; Antarctic flora analysis; Biomonitoring; Antarctica
Příznaky
Mezinárodní význam, Recenzováno
Změněno: 25. 9. 2024 08:44, Mgr. Tereza Miškechová
Anotace
V originále
This paper introduces a new method for the simultaneous determination of lead, aluminum, and iron in plant samples using high-resolution continuum source electrothermal atomic absorption spectrometry (HR-CS ETAAS). The method is suitable for covering a wide range of concentrations for all three elements, by utilizing two spectral lines for Al and employing the wavelength-selected absorbance (WSA) approach, which combines the reading of absorbance signals at both the central and wing parts of the spectral lines. The method was validated against certified reference materials and was then applied in a large-scale analysis of Antarctic flora collected from Nelson Island in the South Shetland Islands, Antarctica. The method was found to be a useful biomonitoring tool for assessing Pb pollution in various plant materials, including lichens, mosses, grass and mushrooms, while Al and Fe contents may serve as normalizing elements in calculations of environmental indices. The observed Pb levels in lichens (median content 0.19 mg Pb/kg) were lower than those reported in other Antarctic regions. These findings indicate that the Stansbury Peninsula on Nelson Island is relatively unaffected by local pollution, compared to other Antarctic regions, and that the data might serve as an example of background levels in the South Shetland Islands.
Návaznosti
MUNI/A/1366/2022, interní kód MU |
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MUNI/A/1623/2023, interní kód MU |
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