Application of Elimination Voltammetry to the Electroanalysis
of an Adsorbed Substance

D 2000

Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance

TRNKOVÁ, Libuše, René KIZEK a Oldřich DRAČKA

Základní údaje

Originální název

Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance

Autoři

TRNKOVÁ, Libuše, René KIZEK a Oldřich DRAČKA

Vydání

Band/Volume22. Bonn, Electroanalysis ESEAC 2000 SEAC, od s. D 27, 1 s. Reihe Umwelt/Environment, 2000

Nakladatel

Rheinische-Friedrich-Wilhelms-Universitaet Bonn

Další údaje

Jazyk

angličtina

Typ výsledku

Stať ve sborníku

Obor

10405 Electrochemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Kód RIV

RIV/00216224:14310/00:00003067

Organizační jednotka

Přírodovědecká fakulta

ISBN

3-89336-261-4

Klíčová slova anglicky

Linear scan voltammetry; Elimination voltammetry; Adsorption

Štítky

adsorption, Elimination voltammetry, Linear scan voltammetry

Změněno: 12. 3. 2001 16:49, prof. RNDr. Libuše Trnková, CSc.

Anotace

V originále

In the elimination voltammetry with a linear scan rate (EVLS), elimination of the selected particular currents from the linear scan voltammetry results is achieved by an elimination function formed by a linear combination of the total currents measured at different scan rates.Theoretical curves of an irreversible current with adsorbed substance being electroactive were calculated for three elimination functions: A - the function eliminating Ik and Ic and conserving Ir , B - the function eliminating Ic and Ir , conserving Ik , and C - the function eliminating Ir and Ik and conserving Ic, where Ic , Ir , and Ik are the charging current, the reversible diffusion current, and the kinetic current, respectively. A larger difference between diffusion and adsorption was exhibited by the elimination function A. It provides a substantial increase in resolution and sensitivity as compared to the linear scan voltammetry current peak and clearly marks the adsorption.

Návaznosti

GV204/97/K084, projekt VaV

Název: Elektrody modifikované nukleovými kyselinami a bílkovinami. Nové nástroje v biochemickém a biomedicínském výzkumu

Investor: Grantová agentura ČR, Elektrody modifikované nukleovými kyselinami a bílkovinami. Nové nástroje v biochemickém a biomedicínském výzkumu

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

TRNKOVÁ, Libuše, René KIZEK a Oldřich DRAČKA. Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance. In Electroanalysis ESEAC 2000 SEAC. Band/Volume22. Bonn: Rheinische-Friedrich-Wilhelms-Universitaet Bonn, 2000, s. D 27, 1 s. Reihe Umwelt/Environment. ISBN 3-89336-261-4.

@inproceedings{325692,
   author = {Trnková, Libuše and Kizek, René and Dračka, Oldřich},
   address = {Bonn},
   booktitle = {Electroanalysis ESEAC 2000 SEAC},
   edition = {Band/Volume22},
   keywords = {Linear scan voltammetry; Elimination voltammetry; Adsorption},
   language = {eng},
   location = {Bonn},
   isbn = {3-89336-261-4},
   pages = {D 27},
   publisher = {Rheinische-Friedrich-Wilhelms-Universitaet Bonn},
   title = {Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance},
   year = {2000}
}

TY  - JOUR
ID  - 325692
AU  - Trnková, Libuše - Kizek, René - Dračka, Oldřich
PY  - 2000
TI  - Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance
VL  - Reihe Umwelt/Environment
PB  - Rheinische-Friedrich-Wilhelms-Universitaet Bonn
CY  - Bonn
SN  - 3893362614
KW  - Linear scan voltammetry
KW  - Elimination voltammetry
KW  - Adsorption
N2  - In the elimination voltammetry with a linear scan rate (EVLS), elimination of the selected particular currents from the linear scan voltammetry results is achieved by an elimination function formed by a linear combination of the total currents measured at different scan rates.Theoretical curves of an irreversible current with adsorbed substance being electroactive were calculated for three elimination functions: A - the function eliminating Ik and Ic and conserving Ir , B - the function eliminating Ic and Ir , conserving Ik , and C - the function eliminating Ir and Ik and conserving Ic, where Ic , Ir , and Ik are the charging current, the reversible diffusion current, and the kinetic current, respectively. A larger difference between diffusion and adsorption was exhibited by the elimination function A. It provides a substantial increase in resolution and sensitivity as compared to the linear scan voltammetry current peak and clearly marks the adsorption.
ER  -

TRNKOVÁ, Libuše, René KIZEK a Oldřich DRAČKA. Application of Elimination Voltammetry to the Electroanalysis of an Adsorbed Substance. In \textit{Electroanalysis ESEAC 2000 SEAC}. Band/Volume22. Bonn: Rheinische-Friedrich-Wilhelms-Universitaet Bonn, 2000, s.~D 27, 1 s. Reihe Umwelt/Environment. ISBN~3-89336-261-4.

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