2000
Analysis of tungsten carbide coatings by UV laser ablation inductively coupled plasma atomic emission spectrometry
KANICKÝ, Viktor, Vítězslav OTRUBA a Jean-Michel MERMETZákladní údaje
Originální název
Analysis of tungsten carbide coatings by UV laser ablation inductively coupled plasma atomic emission spectrometry
Autoři
KANICKÝ, Viktor (203 Česká republika, garant), Vítězslav OTRUBA (203 Česká republika) a Jean-Michel MERMET
Vydání
Spectrochimica Acta Part B, Amsterdam, Elsevier Science, 2000, 0584-8547
Další údaje
Jazyk
angličtina
Typ výsledku
Článek v odborném periodiku
Obor
10406 Analytical chemistry
Stát vydavatele
Nizozemské království
Utajení
není předmětem státního či obchodního tajemství
Impakt faktor
Impact factor: 2.608
Kód RIV
RIV/00216224:14310/00:00002271
Organizační jednotka
Přírodovědecká fakulta
UT WoS
000087765700002
Klíčová slova anglicky
UV laser ablation; Tungsten carbide coatings; Inductively coupled plasma; Atomic emission spectrometry
Štítky
Příznaky
Mezinárodní význam, Recenzováno
Změněno: 29. 6. 2007 09:03, prof. RNDr. Viktor Kanický, DrSc.
V originále
Tungsten carbide coatings (thickness 0.1–0.2 mm) containing 8.0, 12.2, 17.2 and 22.9% Co were studied with laser ablation inductively coupled plasma atomic emission spectrometry (LA-ICP-AES). Composition of these plasma sprayed deposits on steel disks was determined using X-ray fluorescence spectrometry and electron microprobe energy/wavelength dispersive X-ray spectrometry. The coatings were ablated by means of a Q-switched Nd:YAG laser at 266 nm (10 Hz, 10 mJ per shot) coupled to an ICP echelle-based spectrometer equipped with a segmented charge-coupled device detector. Non-linear dependences of cobalt lines intensities on the Co percentage were observed both at a single spot ablation and at a sample translation. This behaviour could be attributed to a complex phase composition of the system W–C–Co. However, employing tungsten as internal standard the linear calibration was obtained for studied analytical lines Co II 228.616 nm, Co II 230.786 nm, Co II 236.379 nm and Co II 238.892 nm.
Česky
Tungsten carbide coatings (thickness 0.1–0.2 mm) containing 8.0, 12.2, 17.2 and 22.9% Co were studied with laser ablation inductively coupled plasma atomic emission spectrometry (LA-ICP-AES). Composition of these plasma sprayed deposits on steel disks was determined using X-ray fluorescence spectrometry and electron microprobe energy/wavelength dispersive X-ray spectrometry. The coatings were ablated by means of a Q-switched Nd:YAG laser at 266 nm (10 Hz, 10 mJ per shot) coupled to an ICP echelle-based spectrometer equipped with a segmented charge-coupled device detector. Non-linear dependences of cobalt lines intensities on the Co percentage were observed both at a single spot ablation and at a sample translation. This behaviour could be attributed to a complex phase composition of the system W–C–Co. However, employing tungsten as internal standard the linear calibration was obtained for studied analytical lines Co II 228.616 nm, Co II 230.786 nm, Co II 236.379 nm and Co II 238.892 nm.
Návaznosti
| GA203/97/0345, projekt VaV |
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| VS97020, projekt VaV |
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