BIRDSALL, David J., Josef NOVOSAD, Alexandra M. Z. SLAWIN and J. Derek WOOLLINS. Synthesis and crystal structures of tellurium complexes containing imidodiphosphinate ligands. J. Chem. Soc., Dalton Trans. Velká Británie: Royal Society of Chemistry, 2000, vol. 2000, No 4, p. 435-439. ISSN 0300-9246.
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Basic information
Original name Synthesis and crystal structures of tellurium complexes containing imidodiphosphinate ligands
Authors BIRDSALL, David J., Josef NOVOSAD, Alexandra M. Z. SLAWIN and J. Derek WOOLLINS.
Edition J. Chem. Soc., Dalton Trans. Velká Británie, Royal Society of Chemistry, 2000, 0300-9246.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher Czech Republic
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 2.310 in 1999
RIV identification code RIV/00216224:14310/00:00002969
Organization unit Faculty of Science
Keywords in English MOLECULAR-STRUCTURE; PD
Tags MOLECULAR-STRUCTURE, PD
Changed by Changed by: doc. RNDr. Josef Novosad, CSc., učo 2768. Changed: 26/2/2001 12:52.
Abstract
The synthesis of TeL2 complexes for a variety of imidophosphinate ligands [R-2(E)PNP(E)R-2'](-) (E = S or Se) is described. The crystal structures of ve examples are reported. Generally the complexes adopt square planar geometries but in one case [R = Et, R' = OPh] two-coordinate geometry is observed. It appears that electronic effects are more important in controlling geometry than steric effects. Two examples of five-coordinate TeL(C6H4OCH3)Cl-2 complexes have also been prepared and structurally characterised.
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MSM 143100011, plan (intention)Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles
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