KOPEL, P., Z. TRÁVNÍČEK, L. KVÍTEK, M. BILER, M. PAVLÍČEK, Z. ŠINDELÁŘ and Jaromír MAREK. Coordination compounds of nickel with trithiocyanuric acid. Part IV. Structure of [Ni(pmdien)(ttcH)] (pmdien = N,N,N ',N ',N''-pentamethyldiethylenetriamine, ttcH(3) = trithiocyanuric acid). Transition Metal Chemistry. Dordrecht: Kluwer Academic Publishers, 2001, vol. 26, No 3, p. 282-286. ISSN 0340-4285.
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Basic information
Original name Coordination compounds of nickel with trithiocyanuric acid. Part IV. Structure of [Ni(pmdien)(ttcH)] (pmdien = N,N,N ',N ',N''-pentamethyldiethylenetriamine, ttcH(3) = trithiocyanuric acid)
Authors KOPEL, P., Z. TRÁVNÍČEK, L. KVÍTEK, M. BILER, M. PAVLÍČEK, Z. ŠINDELÁŘ and Jaromír MAREK.
Edition Transition Metal Chemistry, Dordrecht, Kluwer Academic Publishers, 2001, 0340-4285.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher Netherlands
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 0.779
Organization unit Faculty of Science
Keywords in English MOLECULAR-STRUCTURE; COMPLEXES; CRYSTAL
Tags Complexes, CRYSTAL, MOLECULAR-STRUCTURE
Changed by Changed by: doc. RNDr. Jaromír Marek, Ph.D., učo 1989. Changed: 3/5/2001 10:59.
Abstract
Ni-II mixed-ligand complexes of compositions [Ni(pmdien)(ttcH)] (1), [Ni(baphen)(2)(ttcH)] . 4H(2)O (2), [Ni-(dpa)(ttcH)(H2O)] (3), [Ni(cyclam)(ttcH)] . 2H(2)O (4), [Ni(hexaa)](ttcH) (5) and [Ni(hexab)(ttcH)] . 2H(2)O (6), (baphen = 4,7-diphenyl-1,10-phenanthroline, dpa = 2,2'-dipyridylamine, cyclam = 1,4,8,11-tetraazacyclotetradecane, hexaa = 1,3,6,9,11,14-hexaazatricyclo[12.2.1.1(6),9]-octadecane, hexab = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane) have been prepared and characterized by means of i.r., u.v.-vis. spectroscopies and magnetochemical measurements. The redox properties of the complexes were studied by cyclic voltammetry. The crystal and molecular structure of [Ni(pmdien)(ttcH)] was determined. The nickel atom is penta-coordinated by three N atoms of pmdien, and by S and N atoms of trithiocyanurate(2-) anion.
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