D 2001

Free Bases of Benzophenanthridine Alkaloids - a Combined NMR, X-Ray and Theoretical Study

SEČKÁŘOVÁ, Pavlína, Jaromír TOUŠEK, Roger DOMMISSE, Jiří DOSTÁL, Radek MAREK et. al.

Basic information

Original name

Free Bases of Benzophenanthridine Alkaloids - a Combined NMR, X-Ray and Theoretical Study

Name in Czech

Free Bases of Benzophenanthridine Alkaloids - a Combined NMR, X-Ray and Theoretical Study

Authors

SEČKÁŘOVÁ, Pavlína (203 Czech Republic), Jaromír TOUŠEK (203 Czech Republic), Roger DOMMISSE, Jiří DOSTÁL (203 Czech Republic) and Radek MAREK (203 Czech Republic, guarantor)

Edition

Orlando (USA), 42nd Experimental NMR conference, p. 235-235, 2001

Publisher

Inmerge

Other information

Language

English

Type of outcome

Stať ve sborníku

Field of Study

10403 Physical chemistry

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

RIV identification code

RIV/00216224:14310/01:00004185

Organization unit

Faculty of Science

Keywords in English

Benzophenanthridine Alkaloids; NMR; X-Ray
Změněno: 22/6/2009 08:51, doc. RNDr. Jiří Dostál, CSc.

Abstract

V originále

We were able now to demonstrate that the pseudobases (6-hydroxyderivatives) are the only products of alkalization of the QBA in DMSO-d6 solution using sodium carbonate. In less-polar environment the pseudobases are further converted into bimolecular aminoacetals, which exist in two diastereomeric forms. The detailed configurational and conformational analysis of bimolecular aminoacetals, based on NMR measurements, quantum chemical calculations, and X-ray analysis was presented.

In Czech

Free Bases of Benzophenanthridine Alkaloids - a Combined NMR, X-Ray and Theoretical Study

Links

LN00A016, research and development project
Name: BIOMOLEKULÁRNÍ CENTRUM
Investor: Ministry of Education, Youth and Sports of the CR, Biomolecular Center