| CHAKRABORTY, Debashis, Sabine HORCHLER, Ralph KRÄTZNER, Saji P. VARKEY, Jiří PINKAS, Herbert W. ROESKY, Isabel USÓN, Mathias NOLTEMEYER a Hans-Georg SCHMIDT. Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion. Inorg. Chem. Spojené státy americké: American Chemical Society, Washington DC, 2001, roč. 40, č. 11, s. 2620-2624. ISSN 0020-1669. |
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@article{362632,
author = {Chakraborty, Debashis and Horchler, Sabine and Krätzner, Ralph and Varkey, Saji P. and Pinkas, Jiří and Roesky, Herbert W. and Usón, Isabel and Noltemeyer, Mathias and Schmidt, HansandGeorg},
article_location = {Spojené státy americké},
article_number = {11},
keywords = {CRYSTAL-STRUCTURE; MOLECULAR-SIEVES; MODEL-COMPOUND; ZEOLITE-Y; GALLIUM; CATALYST;},
language = {eng},
issn = {0020-1669},
journal = {Inorg. Chem.},
title = {Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion},
volume = {40},
year = {2001}
}
TY - JOUR
ID - 362632
AU - Chakraborty, Debashis - Horchler, Sabine - Krätzner, Ralph - Varkey, Saji P. - Pinkas, Jiří - Roesky, Herbert W. - Usón, Isabel - Noltemeyer, Mathias - Schmidt, Hans-Georg
PY - 2001
TI - Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion
JF - Inorg. Chem.
VL - 40
IS - 11
SP - 2620
EP - 2620
PB - American Chemical Society, Washington DC
SN - 00201669
KW - CRYSTAL-STRUCTURE
KW - MOLECULAR-SIEVES
KW - MODEL-COMPOUND
KW - ZEOLITE-Y
KW - GALLIUM
KW - CATALYST;
N2 - Reaction of t-BuP(O)(OSiMe3)(OH) with Me3Al leads to the formation of [Me2Al(mu -O)(2)P(OSiMe3)(t-Bu)](2) (1) whereas Me2AlCl reacts with Ph2P(O)(OH) to yield [(Cl)(Me)Al(mu -O)(2)PPh2](2) (2). These compounds represent the first examples of functionalized dimeric four-ring type aluminophosphonate systems. The double four-ring type gallophosphonate, namely, [t-BuPO3GaMe](4), reacts with n-Bu4NHF2 under ambient conditions, resulting in the formation of a monomeric gallophosphonate [n-Bu4N][MeGa(t-BuPO2(OH))(3)] (3) These derivatives have been adequately characterized using various spectroscopic techniques and X-ray diffraction studies.
ER -
CHAKRABORTY, Debashis, Sabine HORCHLER, Ralph KRÄTZNER, Saji P. VARKEY, Jiří PINKAS, Herbert W. ROESKY, Isabel USÓN, Mathias NOLTEMEYER a Hans-Georg SCHMIDT. Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion. \textit{Inorg. Chem.}. Spojené státy americké: American Chemical Society, Washington DC, 2001, roč.~40, č.~11, s.~2620-2624. ISSN~0020-1669.
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