Calibration graphs for steels by IR laser ablation inductively
coupled plasma atomic emission spectrometry

J 2001

Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry

KANICKÝ, Viktor, Vítězslav OTRUBA, Karel NOVOTNÝ, Petr MUSIL, Jean-Michel MERMET et. al.

Základní údaje

Originální název

Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry

Autoři

KANICKÝ, Viktor (203 Česká republika, garant), Vítězslav OTRUBA (203 Česká republika), Karel NOVOTNÝ (203 Česká republika), Petr MUSIL (203 Česká republika) a Jean-Michel MERMET

Vydání

Fresenius Journal of Analytical Chemistry, Berlin, Springer-Verlag, 2001, 0937-0633

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.649

Kód RIV

RIV/00216224:14310/01:00004314

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000170115100012

Klíčová slova anglicky

Laser ablation; Infrared laser; Inductively coupled plasma; Atomic emission spectrometry; Steel; LINA

Štítky

atomic emission spectrometry, inductively coupled plasma, Infrared Laser, laser ablation, LinA, steel

Změněno: 28. 6. 2007 16:41, prof. RNDr. Viktor Kanický, DrSc.

Anotace

V originále

Infrared laser ablation (IR-LA) was studied as a sample introduction technique for the analysis of steels by inductively coupled plasma atomic emission spectrometry (ICP-AES).A comparison of two IR-LA-ICP-AES systems based on Q-switched nanosecond Nd:YAG lasers was performed. The beam of the Lina-SPARK Atomizer (LSA Sarl, Cully, Switzerland) based on the Surelite I-20 laser (Continuum, USA) was moved along a circle. A Perkin-Elmer Optima 3000 DV ICP system was used for emission measurement both with lateral and axial viewing modes. A laboratory-made ablation system based on the Brilliant laser (Quantel) was coupled to a Jobin-Yvon 170 Ultrace ICP (lateral viewing, polychromator part employed). A sample was rotated along a circle during ablation. Linearity of calibration plots was verified at least up to 19 % Cr and 12 % Ni without internal standardization for both LA-ICP-AES systems. Other elements were examined up to 3 % Mo, 1.5 % Mn, 1.7 % Si and 0.15 % Cu. The reproducibility was in the range 5 - 1 %RSD for a mass percentage 0.5 - 20 % of steel constituents. The relative uncertainty on centroid of a calibration line was in the range from ą 4% to ą 12% for Cr, Ni, Mn, Mo, Si, and from ą 8 % to ą 19 % for Cu. The lowest determinable quantities were calculated based on calibrated ranges. Performances of both the IR-LA-ICP-AES were comparable.

Návaznosti

MSM 143100003, záměr

Název: Studium plazmochemických reakcí v neizotermickém nízkoteplotním plazmatu a jeho interakcí s povrchem pevných látek

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Studium plazmochemických reakcí v neizotermickém nízkoteplotním plazmatu a jeho interakcí s povrchem pevných látek

Citovat

KANICKÝ, Viktor, Vítězslav OTRUBA, Karel NOVOTNÝ, Petr MUSIL a Jean-Michel MERMET. Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry. Fresenius Journal of Analytical Chemistry. Berlin: Springer-Verlag, 2001, roč. 370, č. 4, s. 387-392. ISSN 0937-0633.

@article{366111,
   author = {Kanický, Viktor and Otruba, Vítězslav and Novotný, Karel and Musil, Petr and Mermet, JeanandMichel},
   article_location = {Berlin},
   article_number = {4},
   keywords = {Laser ablation; Infrared laser; Inductively coupled plasma; Atomic emission spectrometry; Steel; LINA},
   language = {eng},
   issn = {0937-0633},
   journal = {Fresenius Journal of Analytical Chemistry},
   title = {Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry},
   volume = {370},
   year = {2001}
}

TY  - JOUR
ID  - 366111
AU  - Kanický, Viktor - Otruba, Vítězslav - Novotný, Karel - Musil, Petr - Mermet, Jean-Michel
PY  - 2001
TI  - Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry
JF  - Fresenius Journal of Analytical Chemistry
VL  - 370
IS  - 4
SP  - 387
EP  - 387
PB  - Springer-Verlag
SN  - 09370633
KW  - Laser ablation
KW  - Infrared laser
KW  - Inductively coupled plasma
KW  - Atomic emission spectrometry
KW  - Steel
KW  - LINA
N2  - Infrared laser ablation (IR-LA) was studied as a sample introduction technique for the analysis of steels by inductively coupled plasma atomic emission spectrometry (ICP-AES).A comparison of two IR-LA-ICP-AES systems based on Q-switched nanosecond Nd:YAG lasers was performed. The beam of the Lina-SPARK Atomizer (LSA Sarl, Cully, Switzerland) based on the Surelite I-20 laser (Continuum, USA) was moved along a circle. A Perkin-Elmer Optima 3000 DV ICP system was used for emission measurement both with lateral and axial viewing modes. A laboratory-made ablation system based on the Brilliant laser (Quantel) was coupled to a Jobin-Yvon 170 Ultrace ICP (lateral viewing, polychromator part employed). A sample was rotated along a circle during ablation. Linearity of calibration plots was verified at least up to 19 % Cr and 12 % Ni without internal standardization for both LA-ICP-AES systems. Other elements were examined up to 3 % Mo, 1.5 % Mn, 1.7 % Si and 0.15 % Cu. The reproducibility was in the range 5 - 1 %RSD for a mass percentage 0.5 - 20 % of steel constituents. The relative uncertainty on centroid of a calibration line was in the range from ą 4% to ą 12% for Cr, Ni, Mn, Mo, Si, and from ą 8 % to ą 19 % for Cu. The lowest determinable quantities were calculated based on calibrated ranges. Performances of both the IR-LA-ICP-AES were comparable.
ER  -

KANICKÝ, Viktor, Vítězslav OTRUBA, Karel NOVOTNÝ, Petr MUSIL a Jean-Michel MERMET. Calibration graphs for steels by IR laser ablation inductively coupled plasma atomic emission spectrometry. \textit{Fresenius Journal of Analytical Chemistry}. Berlin: Springer-Verlag, 2001, roč.~370, č.~4, s.~387-392. ISSN~0937-0633.

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