Novel Aluminum and Gallium Atrane Structures and Reactivities

PINKAS, Jiří a J. G. VERKADE. Novel Aluminum and Gallium Atrane Structures and Reactivities. In PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. Reading, UK: GORDON BREACH SCI PUBL LTD, READING, 1994, s. 333-337. 93, 1-4. ISBN 0308-664X.

Základní údaje

Originální název

Novel Aluminum and Gallium Atrane Structures and Reactivities

Autoři

PINKAS, Jiří a J. G. VERKADE

Vydání

Reading, UK, PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, s. 333-337, 93, 1-4, 1994

Nakladatel

GORDON BREACH SCI PUBL LTD, READING

---

Další údaje

Jazyk

angličtina

Typ výsledku

Stať ve sborníku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Organizační jednotka

Přírodovědecká fakulta

ISBN

0308-664X

Klíčová slova anglicky

CRYSTAL-STRUCTURE; ORGANOMETALLIC PRECURSORS; THERMAL-DECOMPOSITION; GALLIUM;COMPLEXES; NITRIDE; ADDUCTS

Štítky

ADDUCTS, Complexes, CRYSTAL-STRUCTURE, gallium, NITRIDE, ORGANOMETALLIC PRECURSORS, THERMAL-DECOMPOSITION

---

Anotace

V originále

New monomeric azaaluminatranes and gallatranes of the type M(RNCH(2)CH(2))(3)N (M = Al, R = Me(3)Si (8) or tert-BuMe(2)Si (9); M = Ga, R = Me(3)Si (10) or tert-BuMe(2)Si (11)) have been prepared, with characterization including a molecular structure determination in the case of 8. Three dimeric azaalumatranes, namely, [Al(MeNCH(2)CH(2))(3)N](2) (12) and [Al(Me(3)SiNCH(2)CH(2))(2)(HNCH2CH2)N](2) (13) and [Ga(MeNCH(2)CH(2))(3)N](2) (14) have also been structurally characterized and all three compounds feature a central (M-N)(2) four-membered ring with a cis configuration of the nitrogen substituents. Some of the reaction chemistry of these systems is outlined and Al-27 NMR trends as a function of coordination number and geometry are discussed.