GRAMLICH, Volker, Přemysl LUBAL, Stefano MUSSO and Giorgio ANDEREGG. The Stability of Metal N,N,N',N'-Tetrakis(2-aminoethyl)ethane-1,2-diamine (=penten) Complexes and the X-Ray Crystal Structure of [Tl(NO3)(penten)](NO3)2. Helvetica chimica acta. Basileae: Aedibus Georg, 2001, vol. 84, No 3, p. 623-631.
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Basic information
Original name The Stability of Metal N,N,N',N'-Tetrakis(2-aminoethyl)ethane-1,2-diamine (=penten) Complexes and the X-Ray Crystal Structure of [Tl(NO3)(penten)](NO3)2
Authors GRAMLICH, Volker, Přemysl LUBAL (203 Czech Republic), Stefano MUSSO and Giorgio ANDEREGG.
Edition Helvetica chimica acta, Basileae, Aedibus Georg, 2001.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher Switzerland
Confidentiality degree is not subject to a state or trade secret
RIV identification code RIV/00216224:14310/01:00004478
Organization unit Faculty of Science
Changed by Changed by: prof. RNDr. Přemysl Lubal, Ph.D., učo 1271. Changed: 31/5/2004 17:22.
Abstract
Complex formation between N,N,N',N'-tetrakis(2-aminoethyl)ethane-1,2-diamine (penten) and the metal ions Mn(II), Co(II), Cu(II), Zn(II), Cd(II), Hg(II), Ag(I), Pb(II) and Tl(III) (in 1.00 M NaNO3 and 25 degrees of Celsius) was investigated by potentiometry and spectrophotometry. These are the first reported values of the stability constants for this ligand with Ag(I), Pb(II) and Tl(III). The X-ray crystal structure of [Tl(NO3}(penten}](NO3)2 was determined. In this structure, Tl(III) shows a coordination number of seven made up of the six N-donors and one O-atom of NO3-.
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MSM 143100011, plan (intention)Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles
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