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@article{377651,
author = {Kanický, Viktor and Otruba, Vítězslav and Mermet, JeanandMichel},
article_location = {Berlin},
article_number = {7},
keywords = {Laser ablation; LINA spark; Infrared laser; Inuctively coupled plasma; Atomic emission spectrometry},
language = {eng},
issn = {0937-0633},
journal = {Fresenius Journal of Analytical Chemistry},
title = {Calibration graphs for Ti, Ta and Nb in sintered tungsten carbide by infrared laser ablation inductively coupled plasma atomic emission spectrometry},
volume = {371},
year = {2001}
}
TY - JOUR
ID - 377651
AU - Kanický, Viktor - Otruba, Vítězslav - Mermet, Jean-Michel
PY - 2001
TI - Calibration graphs for Ti, Ta and Nb in sintered tungsten carbide by infrared laser ablation inductively coupled plasma atomic emission spectrometry
JF - Fresenius Journal of Analytical Chemistry
VL - 371
IS - 7
SP - 934
EP - 934
PB - Springer-Verlag
SN - 09370633
KW - Laser ablation
KW - LINA spark
KW - Infrared laser
KW - Inuctively coupled plasma
KW - Atomic emission spectrometry
N2 - Infrared laser ablation (IR-LA) was studied as a sample introduction technique for the analysis of sintered cobalt-cemented tungsten carbide materials by inductively coupled plasma atomic emission spectrometry (ICP-AES). A Q-switched nanosecond Nd:YAG laser (LINA-Spark Atomizer, LSA Sarl, Cully, Switzerland) based on the Surelite I-20 laser (Continuum, USA) and a Perkin-Elmer Optima 3000 DV ICP system (lateral viewing) were used. The fractionation of cobalt was observed. Linearity of calibration plots was verified at least up to 15 % Ti, 8 % Ta and 3 % Nb. Above 1% (mass %) Ti, Ta and Nb, the repeatability of results was better than 3 % R.S.D. The relative uncertainty at the centroid of the calibration line was in the range from ą 3% to ą 4% for Ti, Ta and Nb with internal standardization by tungsten and up to ą 5% without internal standardization. The limits of detection were 0.004 % Ti, 0.001 % Ta and 0.004 % Nb. The elimination of the cemented hardmetal dissolution procedure is the main advantage of this method.
ER -
KANICKÝ, Viktor, Vítězslav OTRUBA and Jean-Michel MERMET. Calibration graphs for Ti, Ta and Nb in sintered tungsten carbide by infrared laser ablation inductively coupled plasma atomic emission spectrometry. \textit{Fresenius Journal of Analytical Chemistry}. Berlin: Springer-Verlag, 2001, vol.~371, No~7, p.~934-938. ISSN~0937-0633.
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