J 1995

Low-temperature Structures and Raman Spectra of Crystalline Modifications of Selenium Difluoride Dioxide.

BLAKE, A. J; D. BEVILACQUA; Miloš ČERNÍK and Zdirad ŽÁK

Basic information

Original name

Low-temperature Structures and Raman Spectra of Crystalline Modifications of Selenium Difluoride Dioxide.

Authors

BLAKE, A. J (826 United Kingdom of Great Britain and Northern Ireland); D. BEVILACQUA (380 Italy); Miloš ČERNÍK (203 Czech Republic, guarantor) and Zdirad ŽÁK (203 Czech Republic)

Edition

J. Chem. Soc. Dalton Trans. Anglie, 1995, 0300-9246

Other information

Language

English

Type of outcome

Article in a journal

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

is not subject to a state or trade secret

RIV identification code

RIV/00216224:14310/95:00006036

Organization unit

Faculty of Science

Keywords in English

Selenium difluoride dioxide; Low-temperature Structures; Raman spectra; Factor-group analysis
Changed: 27/5/2004 17:11, RNDr. Miloš Černík, CSc.

Abstract

In the original language

The existence of two crystalline modifications of selenium difluoride dioxide between 174 and 100 K,indicated by low-temperature Raman spectra of solid SeO2F2, has been revealed by single-crystal X-ray diffraction techniques at 150 and 120 K. Raman spectra of both modifications are consistent with their crystal structures and a factor-group correlation analysis confirmed the observed splittings of the Se-F stretching modes.

Links

MSM 143100011, plan (intention)
Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles